学科分类
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126 个结果
  • 简介:PolycrystallinesamplesofLa12x(Sr12yAgy)xMnO3(y=0.0,0.2,0.4,0.6,1.0)werepreparedbythesolid-statereactionmethod.ThetemperaturestabilityofmagnetoresistanceandmagnetoresistanceenhancementinLa1-x(Sr1-yAgy)xMnO3systemwithbothunivalentandbivalentelementsdopedatAsiteandwithunchangedvalueofMn3+/Mn4+ratiowereexploredthroughthemeasurementsofX-raydiffractionpatterns,magnetiza-tion-temperature(M-T)curves,resistivity-temperature(q-T)curvesandmagnetoresistance-temperature(MR-T)curves.Theresultsareasfollows:therearetwopeaksintheq-TcurvesofthesampleswithAgdoping,oneiscausedbyresistancechangeduringtheparamagnetism-ferromagnetismtransition,andtheotherisfromboundary-dependentscatteringofconductionelectronsontheboundariesofgrains.ThepeakvalueofMRincreaseswithincreasingAgdopingcontent,anditincreasesfrom8.2%fory=0.2to29.6%fory=1.0underthemagneticfieldofB=0.8T;MRremainsaconstantof12%inthetemperaturerangeof218-168Kforthesamplewithy=1.0,andthetemperaturestabilityofMRisinfavorofthepracticalapplicationofMR.

  • 标签: 温度稳定性 MR 系统 温度曲线 磁阻 AG掺杂
  • 简介:ThestructureandelectrochemicalpropertiesofanewlowcobalthydrogenstorageelectrodealloysLa1-xLixNi3.2Co0.3Al0.3(0≤x≤0.2)wereinvestigatedwithadifferentadditionsofLiinreplacementofLa.WiththeincreaseofLicontentsthemaximumdischargecapacityincreasesfrom240mAh·g-1(x=0)to328.4mAh·g-1(x=0.1)andthecyclestabilityisimprovedcorrespondingly.ThecapacitydecaycanremaiN28.6%(x=0.2)after230charge/dischargecycles.Thehighratedischarge(HRD)abilityofthealloys(x≤0.1)isimprovedandthebestHRDis34.1%(x=0.1)underthedischargecurrentdensity1200mA·g-1.ItisfoundthatthepreparedalloysarebasicallycomposedofLaNi5asmatrixphaseandLaNi3assecondphase(x≤0.1).ButtheabundanceofLaNi3phasedramaticallydecreaseswithincreasingx.Whenx=0.2,anewphaseAl(NiCo)3isformed.

  • 标签: HYDROGEN storage alloy microstructure high rate
  • 简介:BasedontheMiedemamodelandExtendedMiedematheory,theformationenergiesofdifferentsolutecomponentsinEr-XbinarysystemandAl-Er-Xternarysystemswerecalculated.TheresultsshowthatthevariationoferbiumcontenthaslittleinfluenceonthechancerateoftheformationAl-ErcompoundintheAl-Mg-Mn-Zr-Ersystem.ThecalculatedformationenergiesintheEr-XbinarysystemandAl-Er-XternarysystemsindicatethatAl3Erphasecantakepriorityofdepositing,Al-Er-Zrternarycompoundsmayalsofoundwhichagreeswiththeexperimentalresultsinreferences.TheconsistencyofcalculationandexperimentprovesthattheintermetalliccompoundsintheAl-Mg-Mn-Zr-ErsystemcanbepredicteddirectlybycalculatingtheformationenergiesofthereactionsinEr-XbinarysystemandAl-Er-XternarysystemswiththeMiedemamodelandExtendedMiedematheory.

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  • 简介:GaxIn1-xAs1-ySbyalloyshavebeengrownbyatmosphericpressureMOCVDonn-GaSb(Te-doped)substrate.Thesohdcompositionwasdeterminedbyusingelectronmicroprobe.ThealloysofGalnAsSbwithcompositioninmiscibilitygapweresuccessfullygrown.TheopticalpropertiesofGaxIn1-xAs1-ySbylaverswerecharacterizedbythephotoluminescenceandtheinfraredabsorption.Thespectralresponsesofp+-GaInAsSb/p-GaxIn1-xAs1-ySby/n-GaSbdetectorsshowedwavelengthcutoffat2.4μmanddetectivity-D*=5×108cmHz1/2/Watroomtemperature.

  • 标签: MOCVD GaxIn+(1-x)As1-ySby Photoluminescence INFRARED absorption INFRARED
  • 简介:Inthisinvestigation,themechanicalpropertiesandlow-temperaturefracturetoughnessofAPI5LX65offshorepipelineweldedjointswerestudied.StructureIntegrityAssessmentProcedure(SINTAP)-FailureAssessmentDiagram(FAD)methodwasappliedtothepipestructurewithsurfaceflawattheweldtoe.AccordingtotheISOstandardBS7448,theCTODfracturetoughnessoftheweldedjointswasdeterminedatthetemperatureof0℃.Fortheheat-affectedzone(HAZ)specimens,post-testmetallographicanalysiswasperformedtoverifythatthetipofthecrackwaslocatedinthecoarsecrystalzoneinordertoconfirmthevalidityoftheaboveresults.Thefailurelinesofanalysislevel1and3ofweldmetalwerederivedfromtheresultsofthemechanicalpropertytest.Theassessmentwasperformed,consideringthemaximumlaystress,residualstressconservativelyassumedtobeuniformtensilestress,andminimumCTODvalue.Theresultsoftheassessmentshowedthatpipelinestructurewithasurfaceflaw(theheightandlengtharerespectively2.2mmand5mm)attheweldtoeissafe.ThisstudylaysthefoundationofapplicationofSINTAPtopipelinestructureassessment.

  • 标签: 低温破裂韧性 SINTAP 安全处理 管道焊接 结构检测
  • 简介:X-rayDouble-crystalDiffractometerwithHorizontalSlitsandItsApplicationsXuJingyangandZhuNanchang徐景阳,朱南昌(ShanghaiInstituleofMeta...

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  • 简介:涡轮叶片在X射线无损检测时,X射线底片上存在黑白线显示。运用视频显微镜、光学显微镜对叶片黑白线显示部位的表面形貌和显微组织进行了观察分析。结果表明,黑白线显示是由于陶瓷型芯表面错位或微裂纹,使得叶片内腔表面存在具有一定高差的台阶。而陶瓷型芯表面形成错位或微裂纹主要与型芯表面质量和材料高温强度有关。通过控制陶瓷型芯材料纯度和粒度,选择合适的工业氧化铝填料以及加强压芯工艺参数和修芯工艺过程控制,提高型芯表面质量和高温强度,可明显减少甚至消除X射线黑白线显示。

  • 标签: 涡轮叶片 X射线 陶瓷型芯
  • 简介:LayeredcathodematerialLiCo1/3Ni1/3Mn1/3O2wassynthesizedbyPechiniprocess,andinvestigatedusingX-raydiffraction(XRD),scanningelectronmicroscopy(SEM)andgalvanostaticcharge/dischargecycling.Thesampleiswell-crystallizedandhasaphase-purea-NaFeO2structure.Theparticlesizesareuniform,anddistributedintherangeof20-200nm.TheinitialdischargecapacityoftheLi/LiCo1/3Ni1/3Mn1/3O2cellwasabout149mAh·g-1whenitwascycledatavoltagerangeof4.5-2.3Vwithaspecificcurrentof0.25mA.Theresultisbetterincomparisonwithsolid-statesolutionmethod.Thesyntheticprocedurewasdiscussed.Threemajorreactions:chelation,esterification,andpolymerizationsuccessivelyoccurred.

  • 标签: LAYERED CATHODE material LiCo1/3Ni1/3Mn1/3O2 PECHINI method
  • 简介:MgTixNi(x=0,0.1,and0.2)alloysweresuccessfullypreparedbymechanicalalloying(MA),andtheinfluenceofmillingtimeontheelectrochemicalcharacteristicsoftheelectrodeswasdiscussed.MgTixNialloysafter90hmillingdisplayedthebestelectrochemicalperformance.TheX-raydiffractionpatternsshowedthatthealloyball-milledfor90hwasamorphouswithawideneddiffractionpeak.Thecharge-dischargetestsindicatedthatthesealloyshadgoodelectrochemicalactivationproperties,andtheMgTi0.2Nialloyelectrodeexhibitedthebestcycleperformance.TheinitialdischargecapacityoftheMgTi0.2Nialloyreachedupto401.1mAh·g-1,andtheretentionrateofcapacitywas31.0%after30cycles,muchhigherthanthatofMgNi(17.3%).TheTafelpolarizationcurvesrevealedthatTiadditioncouldenhancetheanticorrosionperformanceofthesealloysinalkalisolution,whichwasresponsiblefortheamelioratedcyclicstabilityofthesealloyelectrodes.

  • 标签: 贮氢合金 电化学特性 非晶 电化学活化性能 射线衍射分析 合金电极
  • 简介:X-raydiffraction(XRD)anddifferentialscanningcalorimetry(DSC)wereusedtoinvestigatethecrystallizationprocessofamorphousAl90TMxCe10-x(atomfractionin%;TM=FeorNi;x=3,5)alloys.AgingeffectswereexaminedbyX-raydiffraction.ThestructurecorrespondingtotheprepeakfortheamorphousAl90Fe5Ce5alloyismorestablethantheamorphousmatrix,butitisnotstableforamorphousAl90Ni5Ce5alloyduringthefirstcrystallizationstageandevendecomposesatroomtemperature.AlthoughbothAl-NiandAl-Fehavestrongchemicalbonding,thecrystallizationonsettemperatureofamorphousAl-Fe-CealloysismuchhigherthanthatofamorphousAl-Ni-Cealloys,whichislikelycausedbythedifferentstabilityofthestructurecorrespondingtotheprepeak.ThecrystallizationonsettemperatureincreasesasCe/NiratioincreasesinamorphousAl90NixCe10-xalloys,whereasitdecreasesasCe/FeratioincreasesinamorphousAl90FexCe10-xalloys.AbetteratomicpackingproducesasCecontentincreasesbecauseofthesizemismatchinAlNi-CesystemsandasFecontentincreasesbecauseoftheincreasingFecentralstructuralunits.

  • 标签: 非晶形合金 Al90TMxCe10-x合金 稳定性
  • 简介:本文将介绍新研制的一种用于人造金刚石合成的触媒合金JX-1,其合成效果明显优于Ni70Mn25Co5,且金刚石的颜色呈金黄色,金刚石的TI、TTI值较高,磁化率较低。

  • 标签: 触媒合金 组织结构 TI TTI 磁化率 微量元素
  • 简介:转子工作时不仅需要承受高速旋转(3000r/min)所产生的巨大离心力,同时还承受扭转和弯曲的应力.是汽轮机上重要的安全部件。因此,要求其强度高、韧性好、组织性能均匀、残余应力小等,探伤执行标准为JB/T1265-2002。转子的锻造难度大干一般轴类锻件.因此必须要有可靠的工艺、先进的设备和熟练的操作工人才能保证锻出优质的转子。

  • 标签: 汽轮机转子 30Cr1Mo1V 生产工艺 残余应力 高速旋转 安全部件
  • 简介:Whenmeasuringresidualstressofcoarse-grainaluminumalloyusingX-raydiffractionmethod,thediffractionprofileshowstwopeaksandpositionofmeasured2dwillbechanged,whichleadtoaninaccuratemeasurementresult.Hence,inthispaper,somemethodswereemployedtoimprovethemeasurementaccuracy.Duringthemeasuringprocess,differentparameters(diameterofirradiatedarea,Ψ-oscillationrangeandexposuretime)wereselectedandprofilepeakshiftmethodwasutilized.Moreover,whenthe20ofprofileswasdetermined,differentcalculationmethodswereusedtocalculatetheresidualstress.TheresultsshowthatdiameterofirradiatedareaandΨ-oscillationrangehavesignificantinfluenceonthemeasuringresult.Forstressvaluecalculateddirectlyfromthetestequipment,crosscorrelationmethodismoreaccuratethantheabsolutepeak.Furthermore,anothertwocalculationmethodsofslopewith2θ-sin~2Ψande-sin~2Ψwereusedtocalculatethestressbasedonparameters(2θ,ε)obtainedfromcrosscorrelationmethod.Itisconcludedthat20-sin~2Ψmethodcanfurtherimprovethemeasurementaccuracy.

  • 标签: X射线衍射法 残余应力 铝合金 粗晶 测定 测量精度