简介:Twooxo-vanadium(IV)complexes,[VO(C2O4)(2,2′-bipy)(H2O)]·C2H5OH(1)andVO(C2O4)(phen)(H2O)(2),where2,2′-bipy=2,2′-bipyridyl,phen=1,10-phenanthroline,weresynthesizedaspotentialfunctionalmodelsofvanadiumhaloperoxidases(VHPOs)inmixedsolventofethanolandwateratroomtemperature.Thecomplexeswerecharacterizedbyelementalanalysis,infrared(IR),UV-VisandX-raycrystallography.Structuralanalysesshowedthatvanadiumatomwascoordinatedbyaterminaloxygen,oneoxygenatomfromcoordinatedwater,twooxygenatomsfromthecarboxylategroupofoxalicacid,andtwonitrogenatoms(N1andN2)from2,2′-bipy/phen.Centralvanadiumatomsincomplexes1and2werebothinadistorted-octahedralenvironment,andsomeintermolecularhydrogenbondinglinkageswerealsoobservedineachcomplex.BrominationreactionactivityofthetwocomplexeswasevaluatedwithphenolredasorganicsubstrateinthepresenceofH2O2,Br-andphosphatebuffer,indicatingthattheycanbeconsideredasapotentialfunctionalmodelofVHPO.Inaddition,thermalanalysiswasalsoperformedanddiscussedindetail.
简介:Thecombinationofboth4,4′-bipyridine(4,4′-bipy)anddihydrogenphosphateanionligandswithcopper(Ⅱ)resultsintheformationofanovellayeredcompoundCu(4,4′-bipy)2(H2PO4)2(H2O)2.ThecrystalstructurecomprisesdiscreteneutralCu(4,4′-bipy)2(H2PO4)2(H2O)2units.Thecopperatom,locatedonthecrystallographictwofoldaxis,iscoordinatedwithtwonitrogenatomsofterminal4,4′-bipyligandsandtwowatermoleculesattheequatorialpositions,andtwodihydrogenphosphateoxygenatomsattheaxialpositions,forminganelongatedoctahedron.Thecomplexisatwo-dimensionaldistortedrhomboidalnetworkpossessingtwokindsofrhomboidswithdimensionsofca.1.6792nm×0.3203nmand1.2778nm×0.3198nm,respectively.Thetwo-dimensionalnetworksarestackedparallellyoneachotheralongc-axistogiveanextendedthree-dimensionalchannelnetworkwithaninterlayerdistanceofca.0.5030nm.Crystaldata:triclinic,spacegroupP-1,a=1.0253(2)nm,b=1.4501(3)nm,c=0.79715(16)nm,α=97.91(3)°,β=90.99(3)°,γ=85.54(3)°,V=1.1703(4)nm3,Z=2,R=0.0892,wR=0.2451.
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简介:由di-(2,4,4-trimethylpentyl)的L本氨基丙酸的抽取行为phosphinic酸,di-(2,4,4-trimethylpentyl)-monothiophosphinic酸和di-(2-ethylhexyl)磷的酸分别地在二阶段、三阶段的系统被学习。为这些抽取反应的平衡常数是计算的。
简介:稀土元素aryloxides由各种各样的烷基组代替了[行(浆)3]例如甲基,isopropyl和tertbutyl,被用作单个部件催化剂影响L减水乳酸(LLA)的戒指洞聚合。催化活动,聚合特征,聚合动力学和机制被学习。稀土元素aryloxides的催化活动被结构和烷基组的数字在苯基戒指上影响,这被发现。越强壮烷基组的电子捐赠能力,催化活动将是越多higher。代用品组的数字的增加将导致一项更高催化的活动。镧tris(2,4,6-tri-tert-butylphenolate)[La(OTTBP)3]在所有镧aryloxides之中展出最高的活动。根据1H-NMR数据,LLA聚合经由包含减水乳酸的酰氧债券的劈开的协作插入机制继续了,这被建议。关键词戒指洞聚合-L减水乳酸-稀土元素aryloxides这个工作被山西省(号码2006011069)的自然科学基础和山西省(号码2009011059-7)的关键实验室的开的基础支持。
简介:GinsenosidesRg1,Re,Rb1,Rc,Rb2,Rb3,andRdindifferentpartsoftheAmericanginsengplantwereinvestigated.Theextractionprocesswasapressurizedmicrowave-assistedextraction(PMAE).Thesevenginsenosideswereseparatedanddeterminedbyhigh-performanceliquidchromatography(HPLC)withaultraviolet(UV)detector,at203nm.TheexperimentresultsshowedsignificantvariationsintheindividualginsenosidecontentsoftheAmericanginsengindifferentpartsandagesoftheplant.Theresultsdemonstratedthattheleaves,roothairs,andrhizomesofPanaxquinquefoliusL.containedhigherginsenosidecontents,followedbythemainrootsandstems.TheleavescontaineddramaticallyhigherlevelsofginsenosideRg1,Rb3,andRdthantheotherfourparts.HighercontentsofRb1andRewerepresentinthemainroots,roothairs,andrhizomes.Theamountofginsenosidecontentinthestemswasthelowest.Thetotalcontentofthesevenginsenosidesinmainroots,roothairsandrhizomesincreasedwiththeageoftheplant.Incontrast,theginsenosidecontentsintheleavesandstemsdecreasedwithayearofgrowth.
简介:Arareearthcoordinationsystemwasfirstinvestigatedasanewtypeofcatalystforthering-openingpolymerizationofα-aminoacidN-carboxyanhydrides(NCAs).Theresultsforthepolymerizationofγ-stearyl-α,L-glutamate(SLG)NCAusingneodymiumacetylacetonate(Nd(acac)3)-orneodymiumtris(2-ethylhexylphosphonate)(Nd(P204)3)-triethylaluminum-waterascatalystswerecomparedwiththoseusingconventionalcatalysts.Itwasfoundthatthehelicalpoly(γ-stearyl-L-glutamate)withhighmolecularweightaswellasnarrowmolecularweightdistributioncanbeobtainedinthepresenceofNd(acac)3/AlEt3-1/2H2O.ThepolymerobtainedwascharacterizedbyIRandNMRspectroscopy.
简介:Thestructureandkineticsofthecomplexformedbyhyaluronicacid(HA)andpoly(L-lysine)(PLL)werestudiedbytimeresolvedlaserlightscattering,TEM,andAFM.BecauseHAhasahydrophilicbackbone,thecomplexesformedbyHAandPLLaredifferentfromthoseformedbyoppositelychargedpolyelectrolytesbothhavinghydrophobicbackbones.Insteadofformingstrongaggregatesandevenprecipitates,thecomplexinthepresenceofexcessHAisstableinthestudiedtimeperiod.Moreimportantly,thecomplexspontaneouslyformscore-coronastructurebytherearrangementofHAchains.ThecoreiscomposedofcomplexrichofPLLandthecoronaismainlyHA.FurtheranalysisshowsthatthehydrogenbondformedbyHAcreatesabarrierhinderingthefurtherrelaxationofHAchains.Theautomaticformationofcore-coronastructurebyPLL/HAishelpfulnotonlytounderstandtherelaxationofpolyelectrolyteincomplex,butalsotodevelopdrugcarrierswithdesirableproperties.
简介:Anewcerebroside,1-O-(β-D-glucopyranosyloxy)-(2S,3R,4E,8Z)-2-[(2′R)-2’-hydroxylignoceranoylamino]-4,8-tetradecene-3-diolwasisolatedfromthe60%EtOHextractoftraditionalChinesemedicalplantCyperusrotundusL.Itsstructurewasdeterminedonthebasisofspectroscopicdata.Thisnewcompoundshowedanti-proliferationeffectonvascularsmoothmusclecells(VSMCs).