简介:Magnetoplasmonicsensorsareattractivecandidatesforultrasensitivechemicalandbiomedicalsensorapplications.Avarietyofferromagneticmetalthinfilmshavebeenusedformagnetoplasmonicdeviceapplications,yetthedependenceofsensorperformanceontheopticalandmagneto-opticalpropertiesofferromagneticmetalmaterialshasbeenrarelystudied.Inthiswork,wereportthestudyofenhancedmagneto-opticalKerreffect(MOKE)andsensingperformanceinAu∕FexCo1-xbilayermagneto-opticalsurfaceplasmonresonance(MOSPR)transducers.TheopticalconstantsofFexCo1-x(x=0,0.29,0.47,0.65,and1)inasputter-depositedAu∕FexCo1-xdevicearecharacterizedbytheattenuatedtotalinternalreflection(ATR)method.FexCo1-xthinfilmsshowdifferentMOKEsasafunctionofthechemicalconcentration,withthehighesttransverseMOKEsignalobservedinFe0.7Co0.3.Indexsensingperformanceiscloselyrelatedtothematerial’sopticalandmagneto-opticalconstants.BystudyingthesensingperformanceintheparameterspaceoftheAu∕FexCo1-xbilayerthicknesses,thehighestsensitivityisfoundtobe0.385(theoretical)and0.306RIU-1(experimental)intheAu∕Fe0.7Co0.3MOSPRdevices.OurresearchhighlightstheinfluenceoftheopticalpropertiesofferromagneticmaterialtodevicesensitivityinMOSPRtransducers.ThehighsensitivityinAu∕FexCo1-xMOSPRdevicesmakethesestructuresattractivecandidatesforchemicalandbiomedicalsensingapplications.
简介:AseriesofRbxCs1-xAg4I5(x=0-1)thinfilmsweregrownbyvacuumevaporationonNaCIcrystalsubstratesat350K.Theabsorptionspectraofthesefilmsweremeasuredat80Kinthewavelengthrangefrom240nmto400nm.ItisshownthatsuperionicconductorthinfilmsofquaternarycompoundRb0.5Cs0.5Ag4I5andternarycompoundRbAg415canbeobtainedatx=0.5-0.6andx=0.7-1,respectively.Atx=0.65,thecombinedcompoundfilmofthemixtureof30mol%RbAg4I5and70mol%Rb0.5Cs0.5Ag4I5ispresented.Then,basedonthespectralpositionsoftheA1andA2peaks,wedeterminedthattheRb0.5Cs0.5Ag4I5excitoncouplingenergyRexis0.21eV,theforbiddenzonewidthEgis3.82eVandtheexcitonradiusaexis0.70hm.Furthermore,theionicconductivitiesofsuperionicconductorthinfilmsofRbAg4I5andRb0.5Cs0.5Ag4I5andtheirmixturefilmareinvestigated,respectively,inthetemperaturerange303K-393K.
简介:Inthispaper,adetailedLiesymmetryanalysisofthe(2+1)-dimensionalcouplednonlinearextensionofthereaction-diffusionequationispresented.Thegeneralfinitetransformationgroupisderivedviaasimpledirectmethod,whichisequivalenttoLiepointsymmetrygroupactually.Similarityreductionandsomeexactsolutionsoftheoriginalequationareobtainedbasedontheoptimalsystemofone-dimensionalsubalgebras.Inaddition,conservationlawsareconstructedbyemployingthenewconservationtheorem.
简介:Ceria-zirconiasolidsolutionhasbeenpreparedbytheureagrindcombustionandcitricacidsol-gelmethodsforcatalyticapplicationsasoxygenstorage/releasematerialsinthisstudy.Thepropertiesandoxygenstorage/releasecapacitiesofsampleswithdifferentZrcontentswerecharacterizedandevaluatedbyX-raydiffraction(XRD),N2adsorption,scanningelectronmicroscopy(SEM),Ramanspectroscopy,andinsituCO–CO2loopingtest.Theresultsdemonstratethatthesamplespreparedbytwomethodsareallofexcellentlattice[O]release/storagepropertiesandmaintaingoodlong-termcyclestability.ButthepreparationmethodsignificantlyimpactsthehomogeneityofsamplesrelatedtotheirredoxpropertiesandthecontentofZrover20%,whichgreatlychangedthepropertiesofceria-zirconiasolidsolutionsandcausedtheirchangingofcrystallinesymmetryfromcubictotetragonal.Thesamplespreparedbycitricacidsolgelmethodareofmorehomogeneousparticlesizesandhigherspecificsurfaceareasthanthatbyureagrindcombustionmethod,whichisbenefittotheoxygenreleaseratherthanoxygenstorage.ThebulkoxygenamountmigratedtosurfaceincreaseswiththeincreasingZrcontent,however,theamountoflatticeoxygenmigrationdecreaseswhenZrcontentisover20%.WhenZrcontentis20%,thedifferencesofstorage/releasecapacitiesfromtwodifferentpreparationmethodsarereducedathightemperatureinthelong-termloopreaction.
简介:Effectsofspacevelocity,reactiontemperatureandsupportacidityonproductdistributionandinductionperiodin1-buteneisomerizationandmetathesisoverMo/mordenite-aluminawereinvestigated.Asrevealedbythecatalyticperformanceresults,inductionperiodandobjectiveproductwerecloselyrelatedtothereactionconditions.Lowerspacevelocityledtolongerinductionperiodandhigherpropeneyield.Theoptimalreactiontemperatureforpropeneproductionisaround150Canditshiftedto100Cforetheneproduction.1-Buteneauto-metathesispredominatedinthereactionnetworkifthesupportwithlowerdegreeofsodiumexchanged.Andpropenegraduallybecamethedominantproductuponincreasingthesupportsodiumexchangedegree.6Mo/H100Na0M-30Alcatalystwithasupportoffullsodiumexchangedegreeexhibitedthehighestpropeneyield.
简介:Takingthe(2+1)-dimensionalBroer-Kaup-Kupershmidtsystemasasimpleexample,somefamiliesofrationalformsolitarywavesolutions,triangularperiodicwavesolutions,andrationalwavesolutionsareconstructedbyusingtheRiccatiequationrationalexpansionmethodpresentedbyus.Themethodcanalsobeappliedtosolvemorenonlinearpartialdifferentialequationorequations.
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简介:Inthispaper,first,weemployclassicLiesymmetrygroupsapproachtoobtaintheLiesymmetrygroupsofthewell-known(2+1)-dimensionalGeneralizedSasa-Satsuma(GSS)equation.Second,basedonamodifieddirectmethodproposedbyLou[J.Phys.A:Math.Gen.38(2005)L129],moregeneralsymmetrygroupsareobtainedandtherelationshipbetweenthenewsolutionandknownsolutionissetup.Atthesametime,theLiesymmetrygroupsobtainedareonlyspecialcasesofthemoregeneralsymmetrygroups.Atlast,someexactsolutionsofGSSequationsareconstructedbytherelationshipobtainedinthepaperbetweenthenewsolutionandknownsolution.
简介:Zr1-xTixCo(x=0,0.1,0.2,0.3)alloyswerepreparedbyarc-meltingmethodandtheeffectofTisubstitutiononhydrogenstoragepropertieswasstudiedsystematically.Hydrogendesorptionpressure-composition-temperature(PCT)measurementswerecarriedoutusingSievert’stypevolumetricapparatusforZrCo(at473K,573Kand673K)andZr1-xTixCoalloys(at673K),respectively.ProductsafterdehydrogenationwerecharacterizedbyX-raydiffraction(XRD).Inaddition,thekineticsofZr1-xTixCohydridewasinvestigatedat473Kand673K,respectively,underhydrogenpressureof5MPa.ResultsshowedthatTisubstitutionforZrdidnotchangethecrystalstructureofZrCophase.Withtheincreaseoftemperaturefrom473Kto673K,theextentofdisproportionationforZrCoalloyincreased.WithTicontentincreasingat673K,thedesorptionequilibriumpressureofZr1-xTixCo-H2systemselevatedandthedisproportionationreactionofZr1-xTixCoalloyswasinhibitedeffectively.TisubstitutiondecreasedthekineticsrateandtheeffectivehydrogenstoragecapacityofZr1-xTixCoalloysslightly.Generallyspeaking,itwasfoundthatZr0.8Ti0.2Coalloyhadbetteranti-disproportionationpropertywithlessdecreaseofeffectivehydrogenstoragecapacitywhichwasbeneficialtotritiumapplicationintheInternationalThermonuclearExperimentalReactor(ITER).