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219 个结果
  • 简介:Magnetoplasmonicsensorsareattractivecandidatesforultrasensitivechemicalandbiomedicalsensorapplications.Avarietyofferromagneticmetalthinfilmshavebeenusedformagnetoplasmonicdeviceapplications,yetthedependenceofsensorperformanceontheopticalandmagneto-opticalpropertiesofferromagneticmetalmaterialshasbeenrarelystudied.Inthiswork,wereportthestudyofenhancedmagneto-opticalKerreffect(MOKE)andsensingperformanceinAu∕FexCo1-xbilayermagneto-opticalsurfaceplasmonresonance(MOSPR)transducers.TheopticalconstantsofFexCo1-x(x=0,0.29,0.47,0.65,and1)inasputter-depositedAu∕FexCo1-xdevicearecharacterizedbytheattenuatedtotalinternalreflection(ATR)method.FexCo1-xthinfilmsshowdifferentMOKEsasafunctionofthechemicalconcentration,withthehighesttransverseMOKEsignalobservedinFe0.7Co0.3.Indexsensingperformanceiscloselyrelatedtothematerial’sopticalandmagneto-opticalconstants.BystudyingthesensingperformanceintheparameterspaceoftheAu∕FexCo1-xbilayerthicknesses,thehighestsensitivityisfoundtobe0.385(theoretical)and0.306RIU-1(experimental)intheAu∕Fe0.7Co0.3MOSPRdevices.OurresearchhighlightstheinfluenceoftheopticalpropertiesofferromagneticmaterialtodevicesensitivityinMOSPRtransducers.ThehighsensitivityinAu∕FexCo1-xMOSPRdevicesmakethesestructuresattractivecandidatesforchemicalandbiomedicalsensingapplications.

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  • 简介:AseriesofRbxCs1-xAg4I5(x=0-1)thinfilmsweregrownbyvacuumevaporationonNaCIcrystalsubstratesat350K.Theabsorptionspectraofthesefilmsweremeasuredat80Kinthewavelengthrangefrom240nmto400nm.ItisshownthatsuperionicconductorthinfilmsofquaternarycompoundRb0.5Cs0.5Ag4I5andternarycompoundRbAg415canbeobtainedatx=0.5-0.6andx=0.7-1,respectively.Atx=0.65,thecombinedcompoundfilmofthemixtureof30mol%RbAg4I5and70mol%Rb0.5Cs0.5Ag4I5ispresented.Then,basedonthespectralpositionsoftheA1andA2peaks,wedeterminedthattheRb0.5Cs0.5Ag4I5excitoncouplingenergyRexis0.21eV,theforbiddenzonewidthEgis3.82eVandtheexcitonradiusaexis0.70hm.Furthermore,theionicconductivitiesofsuperionicconductorthinfilmsofRbAg4I5andRb0.5Cs0.5Ag4I5andtheirmixturefilmareinvestigated,respectively,inthetemperaturerange303K-393K.

  • 标签: 吸收光谱 离子传导性 超离子导体薄膜 真空演化
  • 简介:Inthispaper,adetailedLiesymmetryanalysisofthe(2+1)-dimensionalcouplednonlinearextensionofthereaction-diffusionequationispresented.Thegeneralfinitetransformationgroupisderivedviaasimpledirectmethod,whichisequivalenttoLiepointsymmetrygroupactually.Similarityreductionandsomeexactsolutionsoftheoriginalequationareobtainedbasedontheoptimalsystemofone-dimensionalsubalgebras.Inaddition,conservationlawsareconstructedbyemployingthenewconservationtheorem.

  • 标签: (2+1)-dimensional COUPLED nonlinear REACTION-DIFFUSION equation Lie
  • 简介:Ceria-zirconiasolidsolutionhasbeenpreparedbytheureagrindcombustionandcitricacidsol-gelmethodsforcatalyticapplicationsasoxygenstorage/releasematerialsinthisstudy.Thepropertiesandoxygenstorage/releasecapacitiesofsampleswithdifferentZrcontentswerecharacterizedandevaluatedbyX-raydiffraction(XRD),N2adsorption,scanningelectronmicroscopy(SEM),Ramanspectroscopy,andinsituCO–CO2loopingtest.Theresultsdemonstratethatthesamplespreparedbytwomethodsareallofexcellentlattice[O]release/storagepropertiesandmaintaingoodlong-termcyclestability.ButthepreparationmethodsignificantlyimpactsthehomogeneityofsamplesrelatedtotheirredoxpropertiesandthecontentofZrover20%,whichgreatlychangedthepropertiesofceria-zirconiasolidsolutionsandcausedtheirchangingofcrystallinesymmetryfromcubictotetragonal.Thesamplespreparedbycitricacidsolgelmethodareofmorehomogeneousparticlesizesandhigherspecificsurfaceareasthanthatbyureagrindcombustionmethod,whichisbenefittotheoxygenreleaseratherthanoxygenstorage.ThebulkoxygenamountmigratedtosurfaceincreaseswiththeincreasingZrcontent,however,theamountoflatticeoxygenmigrationdecreaseswhenZrcontentisover20%.WhenZrcontentis20%,thedifferencesofstorage/releasecapacitiesfromtwodifferentpreparationmethodsarereducedathightemperatureinthelong-termloopreaction.

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  • 简介:Effectsofspacevelocity,reactiontemperatureandsupportacidityonproductdistributionandinductionperiodin1-buteneisomerizationandmetathesisoverMo/mordenite-aluminawereinvestigated.Asrevealedbythecatalyticperformanceresults,inductionperiodandobjectiveproductwerecloselyrelatedtothereactionconditions.Lowerspacevelocityledtolongerinductionperiodandhigherpropeneyield.Theoptimalreactiontemperatureforpropeneproductionisaround150Canditshiftedto100Cforetheneproduction.1-Buteneauto-metathesispredominatedinthereactionnetworkifthesupportwithlowerdegreeofsodiumexchanged.Andpropenegraduallybecamethedominantproductuponincreasingthesupportsodiumexchangedegree.6Mo/H100Na0M-30Alcatalystwithasupportoffullsodiumexchangedegreeexhibitedthehighestpropeneyield.

  • 标签: 氧化铝 产品分布 丝光沸石 诱导期 异构化
  • 简介:详细地研究了LS1垫层在同一应力水平下,不同温度对其加速老化规律的影响。按照永久变形试验标准加工试样,然后对其进行长期加载,大小为对垫层进行45%压缩。加载以后的样品分别放入45,65℃和75℃的烘箱内,进行长时间加速老化;又分别在40,80,120d和160d的不同时间段内取出样品进行测试;分别测试了取出样品的质量、永久变形量、压缩性能、松弛性能、动态力学性能以及红外光谱。

  • 标签: 老化规律 垫层 温度 力作用 动态力学性能 永久变形
  • 简介:Takingthe(2+1)-dimensionalBroer-Kaup-Kupershmidtsystemasasimpleexample,somefamiliesofrationalformsolitarywavesolutions,triangularperiodicwavesolutions,andrationalwavesolutionsareconstructedbyusingtheRiccatiequationrationalexpansionmethodpresentedbyus.Themethodcanalsobeappliedtosolvemorenonlinearpartialdifferentialequationorequations.

  • 标签: 里卡蒂函数有理数展开式法 BKK系统 符号运算 孤立波解
  • 简介:人们一直尝试合成可以替代现今高能炸药的新型炸药,期望新型炸药在相同的感度水平有更高的性能,或者在相同的性能水平下有更低的感度。1,1-二氨基-2,2-二硝基乙烯(简称FOX-7)就是在这种要求下研究较为活跃的一种新型低感炸药。文献报道FOX-7有3种或4种相态,在室温下存在α相,在113℃转变成β相,下一个相变开始于160℃或170℃。文中利用四圆衍射仪测定FOX-7的晶体结构,变温X射线衍射仪(XRD)研究FOX-7在加热时发生的相变。

  • 标签: 硝基乙烯 二氨基 相变 X射线衍射仪 FOX-7 高能炸药
  • 简介:Inthispaper,first,weemployclassicLiesymmetrygroupsapproachtoobtaintheLiesymmetrygroupsofthewell-known(2+1)-dimensionalGeneralizedSasa-Satsuma(GSS)equation.Second,basedonamodifieddirectmethodproposedbyLou[J.Phys.A:Math.Gen.38(2005)L129],moregeneralsymmetrygroupsareobtainedandtherelationshipbetweenthenewsolutionandknownsolutionissetup.Atthesametime,theLiesymmetrygroupsobtainedareonlyspecialcasesofthemoregeneralsymmetrygroups.Atlast,someexactsolutionsofGSSequationsareconstructedbytherelationshipobtainedinthepaperbetweenthenewsolutionandknownsolution.

  • 标签: LIE对称性 解方程 改性方法 广义 精确解 构造体系
  • 简介:随着科学技术的发展,大学基础物理教育的作用和地位引起了科学家的极大关注。当前世界各国组织了一批优秀的物理学家和科学家正在研究和重新制定大学基础物理教育规划,使物理教育与现代科学技术的发展相适应。

  • 标签: 课程改革 大学物理 教育规划 基础物理 物理教育 科学家
  • 简介:Zr1-xTixCo(x=0,0.1,0.2,0.3)alloyswerepreparedbyarc-meltingmethodandtheeffectofTisubstitutiononhydrogenstoragepropertieswasstudiedsystematically.Hydrogendesorptionpressure-composition-temperature(PCT)measurementswerecarriedoutusingSievert’stypevolumetricapparatusforZrCo(at473K,573Kand673K)andZr1-xTixCoalloys(at673K),respectively.ProductsafterdehydrogenationwerecharacterizedbyX-raydiffraction(XRD).Inaddition,thekineticsofZr1-xTixCohydridewasinvestigatedat473Kand673K,respectively,underhydrogenpressureof5MPa.ResultsshowedthatTisubstitutionforZrdidnotchangethecrystalstructureofZrCophase.Withtheincreaseoftemperaturefrom473Kto673K,theextentofdisproportionationforZrCoalloyincreased.WithTicontentincreasingat673K,thedesorptionequilibriumpressureofZr1-xTixCo-H2systemselevatedandthedisproportionationreactionofZr1-xTixCoalloyswasinhibitedeffectively.TisubstitutiondecreasedthekineticsrateandtheeffectivehydrogenstoragecapacityofZr1-xTixCoalloysslightly.Generallyspeaking,itwasfoundthatZr0.8Ti0.2Coalloyhadbetteranti-disproportionationpropertywithlessdecreaseofeffectivehydrogenstoragecapacitywhichwasbeneficialtotritiumapplicationintheInternationalThermonuclearExperimentalReactor(ITER).

  • 标签: ZrCo-based ALLOYS TI substitution hydrogen storage