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  • 简介:Inthispaper,wegetW1,p(Rn)-boundednessfortangentialmaximalfunc-tionandnontangentialmaximalfunction,whichimprovesJ.Kinnunen,P.LindqvistandTananka’sresults.

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  • 简介:AseriesofnovelN-(3-furan-2-yl-1-phenyl-1H-pyrazol-5-yl)amidesderivativesweredesignedandsynthesized.Theirstructureswereconfirmedby1HNMR,13CNMRandHRMS.Alltitlecompoundswereevaluatedfortheirherbicidalandantifungalactivities.Preliminarybioassayresultsindicatedthatthetitlecompoundsshowedgoodtomoderateherbicidalactivityat1000mg/L.Compound6qpresentedthebestactivityagainstDigitariasanguinalis(L)Scop.,AmaranthusretroflexusL.andArabidopsisthalianawithaninhibitiondegreeoffive.Compound6dalsoshowedaninhibitiondegreeoffiveagainstD.sanguinalis.Inaddition,at50mg/L,mostcompoundsexhibitedgoodinvitroantifungalactivityagainstSclerotiniasclerotiorum,withcompound6cshowingover90%antifungalactivityagainstS.sclerotiorumandPelliculariasasakii.

  • 标签: 酰胺衍生物 生物活性 设计合成 除草活性化合物 抗真菌活性 油菜菌核病
  • 简介:WehavecomprehensivelyinvestigatedthefrustratedJ1-J2-J3Heisenbergmodelonasimplecubiclattice.Thismodelallowsthreeregimesofmagneticorder,viz.,(π;π;π),(0;π;π)and(0;0;π),denotedasAF1,AF2,andAF3,respectively.Theeffectsoftheinterplayofneighboringcouplingsonthemodelarestudiedintheentiretemperaturerange.Thezerotemperaturemagneticpropertiesofthismodelarediscussedutilizingthelinearspinwave(LSW)theory,nonlinearspinwave(NLSW)theory,andGreen’sfunction(GF)method.ThezerotemperaturephasediagramsevaluatedbytheLSWandNLSWmethodsareillustrated,andareobservedtoexhibitdifferentparameterboundaries.Incertainregionsandalongtheparameterboundaries,thepossiblephasetransformationsdrivenbytheparametersarediscussed.TheresultsobtainedusingtheLSW,NLSW,andGFmethodsarecomparedwiththoseobtainedusingtheseriesexpansion(SE)method,andareobservedtobeingoodagreementwhenthevalueofJ2isnotclosetotheparameterboundaries.ThegroundstateenergiesobtainedusingtheLSWandNLSWmethodsareclosetothatobtainedusingtheSEmethod.Atfinitetemperatures,onlytheGFmethodisemployedtoevaluatethemagneticproperties,andthecalculatedphasediagramisobservedtobeidenticaltotheclassicalphasediagram.Theresultsindicatethatattheparameterboundaries,atemperature-drivenfirst-orderphasetransitionbetweenAF1andAF2mayoccuralongtheboundaryline.AlongtheAF1-AF3andAF2-AF3boundarylines,AF3islessstablethanAF1andAF2.OurcalculatedcriticaltemperatureagreeswiththatobtainedusingMonteCarlosimulationsandpseudofermionfunctionalrenormalizationgroupscheme.

  • 标签: QUANTIZED SPIN models quantum phase TRANSITIONS
  • 简介:存取2-substituted-N1-carbethoxy-2,3-dihydro-4(1H)的一条灵巧、有效、新奇的途径-quinazolinones是被代替的N-carbethoxyanthranilamide的冷凝作用用p-toluenesulfonic酸在refluxing2,2,2-trifluoroethanol或hexafluoroisopropanol与烷基,aromatic或异种aromatic醛开发催化剂。

  • 标签: 三氟乙醇 六氟异丙醇 氟溶剂 溶剂效应 喹啉氮杂化合物
  • 简介:最值问题是一种常见题型,解法灵活,综合性强.其中不等式法不失为一种好而有效的方法,经常使用,但务必注意相应的等号成立的条件,也就是能否取得最大值或最小值.以下仅就一个最值题的解法及其“更正”谈一点浅见.一、数学通报97.2《数学问题解答》栏中所刊10...

  • 标签: 等号成立条件 最小值 不等式法 当且仅当 最大值 数形结合思想
  • 简介:过量臼齿的卷VmEand运动学的粘性为丙烯乙二醇monomethyl醚(1-methoxy-2-propanol)的二进制混合物作为作文的一个函数被测量了,MeOCH2CH(哦)我,丙烯乙二醇monoethyl醚(1-ethoxy-2-propanol),EtOCH2CH(哦)我,丙烯乙二醇monopropyl醚(1-propoxy-2-propanol),PrOCH2CH(哦)我,丙烯乙二醇monobutyl醚(1-butoxy-2-propanol),BuOCH2CH(哦)我,和丙烯乙二醇tert丁基醚(1-tert-butoxy-2-propanol),t-BuOCH2CH(哦)我与1-butanol臼齿的体积是的过量为系统2-butanol+1-methoxy-2-propanol,和+1-propoxy-2-propanol越过为有1-butanol的所有系统的全部范围ofcomposition否定、积极,为为系统2-butanol+1-ethoxy-2-propanol,和+1-tert-butoxy-2-propanol的系统2-butanol+1-butoxy-2-propanol,和变化符号否定。从试验性的数据,在从xii的动态粘性的偏差被计算了。两过量臼齿的卷和粘性偏差被方法用一个Redlich-Kister类型多项式方程相关为二进制系数和标准错误的评价最少平方。

  • 标签: 过剩摩尔量 混合物 烷氧基 化学反应
  • 简介:有代替的吲哚的o-alkynylbenzaldehydes或o-alkynylbenzaldimines的催化双人脚踏车反应由羰基或imine组的吲哚的分子间的增加开始了的Pd(II)由intramolecular炔属羟的nucleopalladation列在后面,由protonolysis熄灭碳钯契约改革Pd(II)种类被开发。没有一个氧化还原作用系统的必要性,反应能在温和条件下面被执行。

  • 标签: 串联反应 催化合成 吲哚 OAC 氧化还原系统
  • 简介:设P为素数,利用同余及高次丢番图方程的一些结果证明了不定方程组x-1=3py^2,x^2+x+1=3z^2仅有正整数解(p,x,y,z)=(7,22,1,13)。

  • 标签: 不定方程 同余 正整数解
  • 简介:AgraphissaidtobeK1,4-freeifitdoesnotcontainaninducedsubgraphisomorphictoK1,4.Letkbeanintegerwithk≥2.WeprovethatifGisaK1,4-freegraphoforderatleast11k-10withminimumdegreeatleastfour,thenGcontainskvertex-disjointcopiesofK1+(K1∪K2).

  • 标签: 不相交 最小度 FREE图 顶点 吉隆坡 曲线图
  • 简介:作者在C上给围住的双线性的表格的Fourier变换的描述*(S1)×C*(二基础半的S2)以乔丹组织S1和S2*-representations,hemimogeneous随机域,并且象一样微弱地,harmonizable随机S回答1和S2直到Hilbert空格。

  • 标签: 双线性 半群 数学理论 计算方法
  • 简介:一系列1-[2-(2-methoxyphenylthio)本甲基]-4-arylpiperazines衍生物基于5-HT1A/SSRI药设计策略被设计并且综合。综合混合物为他们的双5-HT1A/5-HTT活动被评估。

  • 标签: 抗抑郁药 药物合成 芳基哌嗪 杀螨好
  • 简介:Lithium-aluminum-cobalt-nickeloxideLiAlxCoyNi1xyO2particles,generallyusedascathodeoflithiumbattery,werepreparedbychemicalcoprecipitationfromanaqueoussolutionofLiOH,Al(NO3)3,Co(NO3)2andNi(NO3)2withNH4OH.XRD,SEMandFTIRwereusedtoexaminetheeffectofnickelcontentontheproduct.FTIRpatternsshowedthatincreaseinnickelcontentdecreasedtheabsorptionstrengthofthepeakofspinelstructureoftheproduct,attributedtotheoccupationbynickelinthealuminumsites.Particlesizeandelectricalpropertiesofthelithium-aluminum-cobalt-nickeloxide(abbreviatedasLACNO)particleswerealsodetermined.

  • 标签: LiAlxCoyNi1-x-yO2 Chemical coprecipitation Particle size Electrical
  • 简介:新carbene钌建筑群,1,3二度(2,6-dimethylphenyl)-4,5-dihydroimidazol-2-ylidene)(PPh3)Cl2-Ru=CHPh,被综合并且为1-hexene的换位用作催化剂。产生建筑群展出了其TOF直到6680h的很高催化的活动?1。然而,同时重要的石蜡异构化被观察并且能是由改变反应条件的surpressed,例如温度,时间,alkene/Ru臼齿的比率和溶剂。

  • 标签: 烯烃易位作用 异构化作用 卡宾钌催化剂 1-己烯
  • 简介:Thesymmetryenergy,whichgovernsmanyphysicalphenomenafromthestructureofexoticnucleitoastrophysicalprocesses,hasmanyramificationsinbothnuclearphysicsandastrophysics.Althoughnuclearsymmetryenergyanditsslopeatthenormaldensityofnuclearmatterhavebeenroughlypinneddown,recentinterpretationsofFOPIandFOPI-LANDdatabydifferenttransportmodelsleadtodivergentconclusionsonthedensity-dependentsymmetryenergyatsupradensities.

  • 标签: Qualitative PROBE NUCLEAR
  • 简介:Anovelpolymercontainingthesucrosegroupwassynthesizedbyradicalpolymerizationfromanenzymaticallypreparedmonomer,1′-O-vinyladipoyl-sucrose(VAS).TransesterificationreactionofsucrosewithdivinyladipateinanhydrouspyridinecatalyzedbyanalkalineproteasefromBacillussubtilisat60℃for7daysgaveVAS(yield55%)withoutanyblocking/deblockingsteps.ThevinylsucroseestercouldbepolymerizedwithpotassiumpersulfateandH2O2asinitiatortogivepoly(1′-O-vinyladipoyl-sucrose)withMn=33,000andMw=53,200,Mw/Mn=1.61.Thepolymerwasbiodegradable.After6daysinaqueousbuffer(pH7),thisalkalineproteasecoulddegradepoly(1′-O-vinyladipoyl-sucrose)toMnofca.1080,Mw/Mn=3.30(37℃),andMnofca.5200,Mw/Mn=2.44(4℃).Thepolymercontainingthesucrosebranchwouldbeafunctionalmaterialinvariousapplicationfields.

  • 标签: Divinyladipate Sucrose Alkaline protease Polymerization Biodegradation
  • 简介:这份报纸关于一个参数依赖者接口地点为敏感的数字近似涉及精确、有效的计算算法的构造。在一根Euler-Bernoulli横梁上关于压电的致动器放置由敏感分析激发了,这个工作为兴趣的参数决定接口的地点的接口问题说明与敏感方程明确的表达有关的关键概念。第四个顺序模型问题被考虑的A,和为敏感计算的一个homogenization过程用标准有限元素方法被构造。数字结果证明敏感接口条件的合适的明确的表达和近似对获得会聚的数字敏感近似批评。第二命令椭圆形的接口模型问题也被提及,并且homogenization过程为这个模型简短被构画出。[从作者抽象]

  • 标签: 敏感性分析 计算问题 接口 二阶椭圆型方程 数值逼近 模型问题
  • 简介:Thecopolymerizationofl-octenewithstyrenecatalyzedbyrareearthcoordinationcatalystshasbeenstudiedforthefirsttime.Somefeaturesandkineticbehavioraredescribed.Theoverallactivationenergyofthecopolymerizationwas22.2KJ/molandthecopolymerizationratecouldbeexpressedasRp=Kp[Nd][M]2.(=1.68×10-3L2/mol2.S,50℃,[Oct]/[St]=1).ThecatalyticactivityofvariousrareearthelementsinLn(naph)3forthecopolymerizationwascomparedandshowsthefollowingsequence:Dy,Y,Yb>Ho>Sm,Gd,Nd>Pr>Ce>La>Tm.Bothmonomersofl-octeneandstyreneinthecopolymerizationbyNd(naph)3-AlEt3havethetendencyofconstantproportioncopolymerization.Thestructureofthecopolymerswasstudiedby1H-NMR.

  • 标签: 1-OCTENE STYRENE COPOLYMERIZATION Rare earth catalyst