简介:Si3N4/TiCnanocompositeceramicshavebeenfabricatedbyhotpressingtechniquewithAl2O3andY2O3asadditives.TheresultsshowedthatwelldispersedcompositepowderwascarriedoutbyaddingdispersantandadjustingpHvaluesofsuspensions.RemarkableincreaseinflexuralstrengthatroomtemperatureswasobtainedbyaddingnanoparticlesinSi3N4matrixwith10%(wtpct)ofnano-Si3N4and15%ofnano-TiC.Theflexuralstrength,fracturetoughnessandhardnesswere1025MPa,7.5MPa·1/2and15.6GPa,respectively.Themicrostructuresofmaterialswereanalyzedbyscanningelectronmicroscopy(SEM)andtransmissionelectronmicroscopy(TEM),whichindicatedthatTiCnanoparticlesdistributeinthematrixandatthegrainboundaries.Accordingtothefractureform,lowcontentsofnanoparticlescouldrefinematrixgrainsandleadtothecrackdeflectionaswellascrackpinning.Themultiplexmicrostructurewasformedbymixingnano-Si3N4particles.Thecracktrajectoriesexhibitedcrackdeflection,rod-likegrainbridgingandpull-out.
简介:环氧树脂可作为复合材料的基体树脂或作为粘合剂而广泛地应用于诸如航空和汽车等许多行业。这类聚合物最令人关心的一点就是它们的长期表现。对这类材料的湿气老化研究已有许多相关报道,能在高温下使用的新型改性环氧树脂也是研究热点之一。一般来说,除了在非常苛刻的使用条件下,在100℃以上,环境水对材料的影响可大大忽略,但是材料的气体环境影响,尤其是氧气,通常总是存在,并可能导致其他形式的强度损失。目前已有数篇文章试图解释材料的热降解机理和失重过程,以及强度下降现象。而最为普遍报道的环氧树脂化学降解方式为分子内的失水。vanKrevelen报道称交联点可能是聚合物网络中最脆弱的部分,因此可能导致在热降解过程发生链的解聚而变回到(部分)不交联的原料。为了能更深入的了解此类热降解现象,最近我们着力研究了一种经改性的环氧粘合剂在高温下的行为。
简介:Theinterfacialbindingcovalentbonddensity(CBD)andthelocalenvironmentaltotalbondorder(LTBO)oftheNi/Ni3Alinterfacewithdifferentlatticemisfits(δ)werecalculatedbyusingfirst-principlesdiscretevariationXαmethod.ItwasfoundthattheeffectsoflatticemisfitsontheelectronicstructuresofincoherentNi/Ni3Alinterfacewereveryobvious.Ononehand,lessthan-0.6%negativelatticemisfitcanpromotethebindingstrengthofγ/γ′interface.Ontheotherhand,thetotalbondingstrengthofγ/γ′interfacedecreaseswithincreasingδ.Therefore,themagnitudeandsignoflatticemisfitmustbecarefullycontrolledforbalancingthehightemperaturecreepstrengthofNi-basesinglecrystalsuperalloyandthestructuralstabilityofγ/γ′interfacewhenonedesignsanewNi-basesinglecrystalsuperalloy.
简介:Thenanocompositefilmswerepreparedbydirectintercalationofpoly(ethyleneoxide)andPEOintoMoO3xerogelviasol-gelroute,TheelectrochromicbehaviorandthechemicalconditionwsofLi^+ionswereinvestigatedbycyclicvoltammograms,UV-visiblespectraltransmittanceandXPS,Thetesultsshowthatthecyclingefficiencyandthereversibilityofinsertion/extracitonofLi^+ionsin(PEO)1MoO3.nH2Onanocompositefilmwereimproved.TheintercalationofPEOintoMoO3xerogelmodulatedthewavelengthrangeofelectrochromismandenhancedtheelectrochromicefficiney,TwodifferentchemicalconditionsofLi^+ionsexistingintheinterlayerandinterstitialpositionsofMoO3latticewereobservedinMoO3XEROGELAND(PEO)1MoO3.nH2Onaocompositefilms.
简介:TiO2nanometerthinfilmswithphotocatalyticantibacterialactivitywerepreparedbythesol-gelmethodonfusedquartzandsodalimeglassprecoatedwithaSiO2layer.ThethinfilmswerecharacterizedbyX-rayphotoelectronspectroscopy(XPS),scanningelectronmicroscopy(SEM),andX-raydiffraction(XRD).TheresultsshowthatsodiumandcalciumdiffusionintonascentTiO2filmiseffectivelyretardedbytheSiO2layerpre-coatedonthesodalimeglass.Theantibacterialactivityofthefilmswasdetermined.ThecrystallineofTiO2nano-meterthinfilmhasimportanteffectsontheantibacterialactivityofthefilm.
简介:Thesynthesisofultrafineceriumdioxideprecursorviahomogeneousprecipitationwasstudied.Mixedaqueoussolutionofanhydrousceriumnitrateandureawasfirstheatedto85℃for2h,andthepreparedsuspensionwasthenagedatroomtemperatureforvariousperiodsoftime.Whiteprecipitatewasfinallycollectedbycentrifugingandwashedwithdistilledwaterandanhydrousethanol.Theobtainedceriumdioxide(CeO2)precursorwasobservedwithSEM.Itwasfoundthatthemorphologyandsizeoftheprecursorwerestronglyaffectedbyagingtimeandstirringconditions(withorwithoutstirring).Theprecipitatedfinesphericalparticlesoftheprecursorchangedtheirshapefromellipsetosliceordirectlytoslice.Finesphericalmonodispersed(300nm)precursorpowderscouldbeobtainedbycontrollingtheagingtime.Stirringthesolutionalsocouldchangethereactionprocessandthusthemorphologyandsizeoftheprecursorwerechanged.
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简介:TherepresentativesampleLa0.58Dy0.09Ca0.33MnO3ofDydopedLa0.67Ca0.33MnO3rare-earthmanganiteswasinvestigated.ThemostimportanteffectofDydopingistointroducethemagnetoimpurityandformthespinclusterswhichinducedramaticallylargeCMRinLa0.58Dy0.09Ca0.33MnO3.Thefittingresultsoffield-inducedresistivitydecreasetotheBrillouinfunctionindicatethattheCMRiscausedbythespindependenthoppingbetweenspinclusters.Itisthemagneticfieldthatreducesthesizeofspinclustersandinducesafield-inducedirreversibleCMRbehaviour.
简介:PositronannihilationbehaviorshavebeenstudiedinthesinglephaseNd2Fe14BmagnetandthenanocompositeNd2Fe14B/α-Femagnet,preparedbymeltspinning.Theresultsshowedthatthenumberofvacancy-clusteratgrainboundariesincreaseswithincreasingannealingtemperatureforthebothtypesofmagnets.Theincreaseofthiskindofdefectcanimprovethecoercivityof
简介:不饱和聚酯(UP)通过正确选择原材料和固化条件可获得更广泛的应用。然而由于其抗冲击性能较低,使其一些应用受到限制。掺混能够增加网络结构柔性的改性剂可提高抗冲击性能。在UP网络结构中引入柔性的聚硅氧烷链段,象形成接枝共聚物一样,作为树脂和改性剂之间的低粘附性降至最低的一种方法,以便增加改性物的柔性。由于聚酯和聚硅氧烷是不互溶的混合物体系,在固化时,接枝共聚作用能够促进两聚合物问的相容性。所以,将甲基丙烯酸缩水甘油酯(GMA)通过自由基反应引入到树脂网络结构中,以及1,3-氨丙基三乙氧基硅烷(APTS)中的氨基与GMA反应。硅氧烷(1,1,3,3-四甲基-1,3-二乙氧二硅氧烷)的加入可使聚有机硅氧烷网络增长,而加水可以保证固化期间水解和缩聚反应进行。使用此方法可改善改性物的柔性。采用动态机械分析方法评价了接枝共聚,并且通过悬臂梁式试验评价了纯UP和改性UP抗冲击性能。在较低的改性剂含量范围内,在不饱和聚酯链段内接枝柔性链段可有效地提高聚酯树脂的冲击性能。
简介:ItwasshownbyTEMandX-rayanalysisthatNi3AlisthemainphaseoftheintermetallicsynthesizedundercompressionfromthepowdermixtureofNiwithAlalloyedbyB.TheNi3Bisasecondaryphase.ThevalueofthelatticeparameteroftheintermetallicNi3AlwithandwithoutBincreaseswhentheconcentrationofAlincreases.TheincreaseinAlconcentrationfrom23.5to25.0intheinitialpowdermixtureleadstodecreasingthesolubilityofBintheNi3Alphase.