简介:Polyparaphenylene(PPP)ispreparedbyAlCl3-CuCl2catalystswithbenzeneasthemonomerandisdopedbychemicalmethodandN^+ionimplantation.Theinfluencesoftheconcentration,temperatureandtimeofchemicaldopingandthedose,energyandtemperatureofionimplantation,onPPPconductivityareinvestigated.TheresultsshowedthattheconductivityofPPPcanbeimproved4-5ordersofmagnitudebyionimplantationandtheconductivityofPPPcanreachabout0.11S·cm^-1bychemicaldoping.Thecomparisonofstabilityofthematerialconductivebehaviorbyusingthetwodopingmethodsispresented.Itshowsthationimplantationisbetterthanchemicaldopinginstabilizingtheelectricconductivebehaviorforthematerial.
简介:Amorphoussiliconfilmsarepreparedatlowertemperatureof350℃bynewcatalyticchemicalvapordepositionmethod.Inthemethod,materialgases(SiH4andH2)aredecomposedbycatalyticreactionatgiventemperature,soa-Sifilmsaredepositedonsubstrates.Itisfoundthata-Sifilmswithhighqualitycanbeobtain,suchashighphotosensitivityof10^6,lowspindensityof2.5×10^16cm^-3.
简介:Chalcopyrite-typeCuInSe2nanoparticlesaresuccessfullypreparedbyusingIn2Se3nanoparticlesasaprecursorreactedwithcopperchloride(CuCl)solutionviaaphasetransformationprocessinlowtemperature.Thereactiontimeisakeyparameter.Afterthereactiontimeincreasingfrom0.5hto8h,In2Se3andCuClreactwitheachothergraduallyviaphasetransformationintoCuInSe2withoutanyintermediatephase.ThecrystallinestructureandmorphologyoftheCuInSe2nanoparticlesarecharacterizedbyX-raydiffraction(XRD)andfieldemissionscanningelectronmicroscopy(FESEM).ThediameterofCuInSe2nanoparticleswithgooddispersibilityrangesfrom10nmto20nm.ThebandgapoftheCuInSe2nanoparticlesis1.04eVcalculatedfromtheultraviolet-visible(UV-VIS)spectrum.