简介:ThetitlecomplexEu(Ⅲ)(TTA)3(phen)(whereTTA=thenoyltrifluoroacetonemonoanion;phen=1,10-phenanthroline)hasbeensynthesizedinmixedsolventsofacetoneandethanol(1:1volumeratio)anditscrystalstructurehasbeendeterminedbyX-raydiffraction.Thecomplexcrystalsaretriclinic,spacegroupP1(#2)withcelldimensionsofa=1.3241(2)nm,6=1.5278(4)nm,c=0.9755(3)nm,α=92.49(2)°,β=102.57(2)°,γ=91.62(2)°,V=1.9268(8)nm3,Z=2,μ(MoKα)=18.77cm-1,Dx=1.720g/cm3.ThecoordinationgeometryofEuatomisadistortedsquareantiprism,andtheencapsulatedstructurethatcanmeetthestructuralrequirementofthetypicaleuropiumluminescentsensor.Thefluorescencespectrumsuggeststhatthecomplexisastrongphotoluminescentmaterial.
简介:Grapheneanditsderivativeshaveattractedtremendousresearchinterestbecauseoftheiruniquecompositionandphysicochemicalproperties[1??3].However,thepotentialbiologicaltoxicityofGQDshasbecomeahealthriskbecauseoftheirinherentchemicalcompositionandnanoscaleproperties[4].Zebrafish(Daniorerio)isoneofthemostpromisinginvivomodelsystemsfortoxicitystudies[5].
简介:TheprogressofresearchgoingoninGroupofEnergyMaterials(GEM),MaterialResearchCenter,in2014isinthefollowingthreeaspects.1.FacilitydevelopmentInordertopushforwardourstudyonfusionreactormaterials,weupgradedtheirradiationterminal(128#)ofthesectorfocusedcyclotron(SFC)atHIRFL,bydevelopinganewspecimenstagespecificforirradiationwithlow-fluencescatteredions.Sofartheterminaliscapableofirradiationtobothverylowfluences(106ions/cm2)andveryhighfluences(typically1016ions/cm2)forvariousmaterials.SpecimentemperaturecanbereadilycontrolledusingtheL-N2coolingstageorthethehigh-Tstage(upto600oC).Ourrecentinvestigationwithtransmissionelectronmicroscopy(TEM)ofthedefectsproducedbyhigh-energyNeionsinsteelspecimensprovidesaclearevidencethatdefectswereproduceduniformlyalongthedepthinthespecimen,indicatingthattheenergydegraderoftheterminalworkseffectivelytodispersetheionenergyinawiderange.AphotooftheterminaltogetherwithaSRIMestimateofdepthprofilesofdamageinan8%Crreducedactivationferritic/martensiticsteel(RAFMS)isshowninFig.1.
简介:HighactiveandstablegoldcatalystssupportedoncrystallineFe2O3andCeO2/Fe2O3werepreparedviathedeposition-precipitationmethod.ThecatalystwithaAuloadof1.0%calcinedat180°CshowedaCOconversionof100%at-8.9°C,whileAu/CeO2/Fe2O3convertedCOcompletelyat-16.1°C.Evenhavingbeencalcinedat500°C,Au/Fe2O3stillexhibitedsignificantcatalyticactivity,achievingfullconversionofCOat61.6°C.ThecatalystwithalowAuloadof0.5%couldconvertCOcompletelyatroomtemperatureandkepttheactivityunchangedforatleast150h.N2adsorption-desorptionmeasurementsshowthatthecrystallinesupportspossessedahighspecificsurfaceareaofabout200m2/g.CharacterizationsofX-raydiffractionandtransmissionelectronmicroscopyindicatethatgoldspecieswerehighlydispersedasnanoorsub-nanoparticlesonthesupports.Evenafterthecatalystwascalcinedat500°C,theAuparticlesremainedinanano-sizeofabout6―10nm.X-rayphotoelectronspectrarevealthatthesupportedAuexistedinmetallicstateAu0.ThemodificationofAu/Fe2O3byCeO2provedtobebeneficialtotheinhibitionofcrystallizationofFe2O3andthestabilizationofgoldparticlesindispersedstate,consequentlypromotingcatalyticactivity.
简介:AsimpleandefficientcascadeMichael/cyclizationreactionof3-aminoindolin-2-oneswithenones/enalswasidentifiedforthesynthesisofpotentiallybiologicallyactive3’,4’-dihydrospiro[pyrrol-3,2’-oxindoles],usingDBUasanefficientcatalystandethyleneglycolasanenvironmentallybenignsolvent.Morediverse3’,4’-dihydrospiro[pyrrol-3,2’-oxindoles]analoglibrarieswerepreparedingoodyields(upto97%).Thestructureof3’,4’-dihydrospiro[pyrrol-3,2’-oxindoles]wasconfirmedbymassspectrometryanalysis,NMRanalysisandsinglecrystalX-raydiffraction.Themainadvantagesofthismethodincludetheavailabilityofstartingmaterials,simpleexperimentaloperation,shortreactiontime,aswellashighyieldsobserved.
简介:ThecomplexK3H4GeW9V3O40·8H2OcrystallizedinamonocliiniesystemwithspacegroupP2,Mr=2784.67,a=11.099(3),b=16.452(4),c=13.534(4),β=108.14°,Z=2,V=2348.493,F(000):2456,μ=239.7cm-1,De=3.932g/cm3.ThefinalR=0.083for4528non-zeroreflexions.ThestructureofanionsGeW9V3O40andGeW9O34belongstoA--type.
简介:AnaffordablesolutiontoTier-3RegionalCenter(RC)ispresentedinthistalk,asimpleprototypehasbeensetupforevaluationofthesystemperformance,thisprototypecanbeeasilyscaledtobiggerone.Asetofmeasurementshavebeenconductedinbothcomputerandnetworksystembehavioursinmultipleconcurrentlyrunningjobscontexts.Inthetalkthesemeasuredresultsaretalkedanddiscussed,includingsystemandnetworkeffectiveutilizationsandlimitations,andtheidentifiedbottlenecksindifferentnetworklayouts,andthecomparisonswithsimulation.
简介:Heavyionbeamsaregenerallyrecognizedasoneofpowerfulmutagensinplantbreedingtogeneratenewmutantswithidealorusefulagronomiccharacters[1].12C6+ionbeams(80MeV/u)acceleratedbyHeavyIonResearchFacilityinLanzhou(HIRFL)wereusedtoirradiatewheatsamples,oneofthemajorwheatvarietiesinQinghaiprovince,namedGaoyuan448.Theradiationdosesrangedfrom10to200Gy.Theirradiatedsamples,controls,andanothermajorwheatvarietynamedAbowereplantedinfarmlocatinginLeducountyofQinghaiprovincein2014.
简介:Soilconsolidationwouldinducevariationsofitstransportcoefficientssuchashydraulicconductivityanddiffusioncoefficient.Thispaperpresentsastudyoftheinfluenceofbarrierconsolidationontransportcoefficients,anda3Dtransportmodelbasedonmixturetheoryisproposedfordescribingthelinersthatinvolvecirculardefectsinthegeomembrane.TheelastoplasticALPHAmodelisrevisedbyusingthespatiallymobilizedplane(SMP)criterionforsimulatingthedeformationofthesoils.Then,the3Dmodelcouplingthenonlinearconsolidationandcontaminantadvection-diffusionissolvedusingthefiniteelementsoftwareABAQUS.Theresultsshowthattheimportanceofreducingthedefectsizeinthegeomembraneandthelinerporositytocontrolthecontaminantconcentrationincrease.
简介:Theauthorsproposeanovelmethodfortransportingmulti-viewvideosthataimstokeepthebandwidthrequirementsonbothend-usersandserversaslowaspossible.Themethodisbasedonapplicationlayermulticast,whereeachendpointreceivesonlyaselectednumberofviewsrequiredforrenderingvideofromitscurrentviewpointatanygiventime.Thesetofselectedvideoschangesinrealtimeastheuser'sviewpointchangesbecauseofheadoreyemovements.Techniquesforreducingtheblack-outsduringfastviewpointchangeswereinvestigated.Theperformanceoftheapproachwasstudiedthroughnetworkexperiments.
简介:Anewkindofmonomerswassuccessfullysynthesizedbythereactionbetween2-chloromethylcycloketalandtrimethylsilylcyanide,followedbyringclosureanddehaiogenation.Polymerizationsofthemonomerswerecarriedoutinbenzenesolutionat80℃withbenzoylperoxideasinitiator.BoththestructuresofmonomersandpolymerswerecharacterizedbyIR,1HNMR,13CNMRandelementalanalysis.