简介:Theroleofpulseparametersonnanoparticlepropertyisinvestigatedself-consistentlybasedonacoupleoffluidmodelandaerosoldynamicsmodelinacapacitivelycoupledparallel-plateacetylene(C2H2)discharge.Inthismodel,themasscontinuityequation,momentumbalanceequation,andenergybalanceequationforneutralgasaretakenintoaccount.Thus,thethermophoreticforceariseswhenagastemperaturegradientexists.Thetypicalresultsofthismodelarepositiveandnegativeiondensities,electronimpactcollisionsrates,nanoparticledensity,andchargedistributions.Thesimulationisperformedfordutyratio0.4/0.7/1.0,aswellaspulsemodulationfrequencyfrom40kHzto2.7MHzforpureC2H2dischargesatapressureof500mTorr.Wefindthatthepulseparameters,especiallythedutyratio,haveagreataffectonthedissociativeattachmentcoefficientandthenegativedensity.Moreimportantly,bydecreasingthedutyratio,nanoparticlesstarttodiffusetothewall.Undertheactionofgasflow,nanoparticledensitypeakiscreatedinfrontofthepulseelectrode,wherethegastemperatureissmaller.
简介:Thelackofefficientandnon-toxicgenedelivery,preferablywithnon-viralDNAvectors,isgenerallyregardedasamajorlimitationforgenetherapy.Inthisstudy,awheathistoneH4genewasclonedfromTriticumaestivum,sequenced,modifiedandexpressedinE.coli.ThewheathistoneH4geneandreconstructedH4TLgeneencodedwheathistoneH4andarecombinantproteinof141aminoacidswithanapproximatemolecularweightof15500.GelelectrophoresismobilityshiftassaysdemonstratedthatthepurifiedproteinhadhighaffinityforDNA.Mostsignificantly,thecomplexofplasmidpEGFP/C1withH4TLwastransfectedwithincreasedefficiencyintoMCF-7,HO8910,LNCap,A549andHeLacellsinvitro.Theseresultsdemonstratethatthetargetingofnon-viralvectorstotumor-specificreceptorsprovidesacheap,simpleandhighlyefficienttoolforgenedelivery.
简介:Theα-decayofneutron-deficientheavynucleifarfromstabilityisanindispensablespectroscopictooltostudytheirlow-energystructure.220Pa,atrans-leadisotopeneartheshellclosureN=126,itsdecaypropertiesarestillnotwellestablished,thoughitwasstudiedintwoα-decayexperiments30yearsago[1,2].Recently,weappliedsuccessfullythemoderndigitalpulseprocessing(DPP)technique[3,4]tothedecayspectroscopyintheZ≥91andN=128~131region[5]andthedecaychainof220Pawasestablishedatthefirsttime.
简介:TargetResiduesfromInteractionofUraniumwith20MeV/u40ArIons¥QinZhi;LiWenxin;SunTongyu;ZhaoLin;ZhangXiang;YinXinming;?..
简介:Multi-nucleontransferreactionplaysanimportantroleinthesynthesisofnewnuclides[1].Inthereactionsof20Ne+209Bi,someshort-livednucleiproducedbytransferring26nucleonswerediscovered.Theexperimentof20Ne+209Biwasperformedatgas-filledrecoilseparatorinLanzhou[2].A400g/cm2thick209Bitargetwasbombardedwith20NebeamdeliveredbyacceleratorHIRFL.
简介:ThreeseriesofCeO2/CuOsampleswerepreparedbyimpregnationmethodandcharacterizedbyXRD,N2adsorption-desorption,temperatureprogrammedreduction(TPR),XPSandTEMtechniques.IncomparisonwiththesamplespreparedwithCuOasinitialsupport,thesampleswithCu(OH)2asinitialsupporthavehigherreducibilitiesandsmallerrelativeTPRpeakareas,andalsolargerspecificsurfaceareasatcalcinationtemperaturesof400℃–600℃.Asaresult,Cu(OH)2isbetterthanCuOasinitialsupportforpreferentialoxidationofCOinexcessH2(CO-PROX).Thebestcatalyticperformancewasachievedonthesamplecalcinedat600℃andwithanatomicratioofCe/Cuat40%.XPSanalysesindicatethatmoreinterfacelinkagesCe-O-Cucouldbeformedwhenitwascalcinedat600℃.AndtheatomicratioofCe/Cuat40%ledtoaproperreducibilityforthesampleasillustratedbytheTPRmeasurements.
简介:Asimpleandefficientmethodhasbeendeveloped;benzil/benzoinundergoessmoothcondensationwithvarioussubstitutedaldehydeandammoniumacetateinthepresenceofpotassiumdihydrogenphosphate(KH_2PO_4)undermildreactionconditionstoaffordthecorrespondingtrisubstitutedimidazoleinexcellentyields.Themethodforsynthesisofproduct,thereactionmixturewasrefluxinethanolfor40-90min.Thepresentmethodissimple,efficient,andcost-effective.
简介:Gasphasereductionofcarbonmonoxidetoformaldehydeandethylenewasfoundinelectrochemicalcellwithaninorganicionexchangerα-Zr(HPO4)2·H2Ousedassolidproton-conductingelectrolyteatroomtemperatureandatmosphericpressure.ThetypeandamountoftheelectroreductionofCOdependonthedifferentmetalelectrodesandcurrentdensities,whichgivesalankbetweenheterogeneouscatalysisandelectrochemistry.
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简介:为在的盒子象差错为高级放射性的原子废物在一个仓库的近的域里在包围岩石团以内存在一样的大地质的结构,浸透不饱和的无所不在关节的岩石质量的双孔的媒介的一个种联合thermo-hydro-mechanical-migratory模型被建立。在现在的模型,渗出物域和集中域是双的,但是压力域和温度域是集合的单身者,和影响,空格,角度,连续性比率,媒介的组成的关系上的破裂的僵硬能被考虑。同时,有限元素方法的一个二维的节目被开发。拿在是不饱和的一个岩石团定位的一个假想原子浪费仓库是的双孔的媒介一个计算例子,为联合的thermo-hydro-mechanical-migratory的女性的分析在有或没有一个差错,和温度为盒子漏的放射性的核种的条件下面被执行,毛孔压力,流动速度,在岩石团中的核种集中和主要压力被调查。在差错的破裂水流动的结果表演是基本上沿着差错方向,和它的流动速度比在岩石质量中的破裂水的高几乎三个数量级;没有差错,在差错的核种集中也比那高得多,并且核种更快沿着差错移动;而且,差错在岩石团中在毛孔压力和主要压力上有明显的影响。