简介:首次制备出粉末微晶BaCl0.5Br0.5F:Sm2+红色发光材料,并测量了其低温光谱。发现其谱线宽度与BaClF:Sm2+的相比较有了约十倍左右的非均匀增宽,而且相应于5D0,1,2→7F0,1的谱线由两个峰间距分别为15cm-1,65cm-1的谱线构成,峰间距只与基态7F0和7F1有关。W.Lenth&W.E.Morener[1]讨论了光子门光谱烧孔作为频率微区光学记录的理论和应用的可能性。对于长存的光谱烧孔,可以进行二进制的数据存储与改写。该技术为实现大容量、高速度的光学计算机的应用提供了新的前景。在这方面已经有了不少的研究工作[2~6]。为提高存储容量,需使光谱线非均匀增宽,以提供更多的光谱烧孔可能性。为此目的,首次制备出粉末微晶BaCl0.5Br0.5F:Sm2+红色发光材料,并测量了其低温光谱,并将其与BaClF:Sm2+的低温光谱进行了比较分析。
简介:Ultrafastfiberlasersareingreatdemandforvariousapplications,suchasopticalcommunication,spectroscopy,biomedicaldiagnosis,andindustrialfabrication.Here,wereportthehighlystablefemtosecondpulsegenerationfromaMXenemode-lockedfiberlaser.Wehavepreparedthehigh-qualityTi3C2Txnanosheetsviatheetchingmethod,andcharacterizedtheirultrafastdynamicsandbroadbandnonlinearopticalresponses.Theobviousintensity-andwavelength-dependentnonlinearresponseshavebeenobservedandinvestigated.Inaddition,ahighlystablefemtosecondfiberlaserwithsignal-to-noiseratioupto70.7dBandcentralwavelengthof1567.3nmhasbeendelivered.Thestudymayprovidesomevaluabledesignguidelinesforthedevelopmentofultrafast,broadbandnonlinearopticalmodulators,andopennewavenuestowardadvancedphotonicdevicesbasedonMXenes.
简介:Two-dimensional(2D)graphitecarbonnitride(g-C3N4)nanosheetshavebeensuccessfullyusedasasaturableabsorber(SA)inapassivelyQ-switchedNd:LLFlaserat1.3μmforthefirsttime,tothebestofourknowledge.Underanincidentpumppowerof9.97W,theshortestpulsedurationof275nswasacquiredwithoutputpowerof0.96Wandpulserepetitionrateof154kHz,resultinginapulseenergyof6.2μJ.Inaddition,thesaturableabsorptionbehaviorsofzero-dimensional12nmg-C3N4nanoparticles(g-C3N4-NPs)andthree-dimensionalorderedmesoporousg-C3N4(mpg-C3N4)werealsoobserved,althoughtheirmorphologyandstructurewerequitedifferentfrom2Dg-C3N4.Theexperimentalresultsintroducethepotentialapplicationofg-C3N4nanomaterialsasSAsinQ-switchedlasers.
简介:Thesuppressionoftherecombinationofelectronsandholes(e–h)andtheenhancementofthelightabsorptionofsemiconductorsaretwokeypointstowardefficientphotocatalyticdegradation.Here,wereportafew-layerg-C3N4/α-MoO3nanoneedles(flg-C3N4/α-MoO3NNs)all-solid-stateZ-schememechanismphotocatalystsynthesizedviaatypicalhydrothermalmethodinacontrolledmanner.Therecombinationofthephoto-inducede–hpairscouldbeeffectivelyrestrainedbytheZ-schemepassagewaybetweentheflg-C3N4andα-MoO3NNsinthecomposite,whichcouldalsopromiseahighredoxabilitytodegradepollutants.Anditbecamepossibleforthepreparedphotocatalysttoabsorblightinawiderangeofwavelengths.Thedetailedmechanismwasstudiedbyelectronspin-resonancespectroscopy(ESR).Thelow-dimensionalnanostructureofthetwoconstituents(α-MoO3NNswithone-dimensionalstructureandflg-C3N4withtwo-dimensionalstructure)endowedthecompositewithvarietiesofexcellentphysicochemicalproperties,whichfacilitatedthetransferanddiffusionofthephotoelectronsandincreasedthespecificsurfaceareaandtheactivesites.The10wt%flg-C3N4/α-MoO3NNsshowedthebestphotocatalyticperformancetowardRhBdegradation,therateofwhichwas71.86%,~2.6timeshigherthanthatofα-MoO3NNs.