简介:QuantumdynamicscalculationsforthetitlereactionH(2S)+S2(X3-Σg)→SH(X2Π)+S(3P)areperformedbyusingagloballyaccuratedoublemany-bodyexpansionpotentialenergysurface[J.Phys.Chem.A1155274(2011)].TheChebyshevrealwavepacketpropagationmethodisemployedtoobtainthedynamicalinformation,suchasreactionprobability,initialstate-specifiedintegralcrosssection,andthermalrateconstant.Itisfoundnotonlythatthereisareactionthresholdnear0.7eVinbothreactionprobabilitiesandintegralcrosssectioncurves,butalsothatboththeprobabilityandcrosssectionincreasefirstlyandthendecreaseasthecollisionenergyincreases.Theexistenceoftheresonancestructureinboththeprobabilityandcrosssectioncurvesisascribedtothedeeppotentialwell.Thecalculationoftherateconstantrevealsthatthereactionoccurringonthepotentialenergysurfaceoftheground-stateHS2isslowtotakeplace.
简介:ThesplittingofpotentialenergylevelsforgroundstateX2ΠgofOx2(x=+1,1)underspin–orbitcoupling(SOC)hasbeencalculatedbyusingthespin–orbit(SO)multi-configurationquasi-degenerateperturbationtheory(SO-MCQDPT).TheirMurrell–Sorbie(M–S)potentialfunctionsaregained,andthenthespectroscopicconstantsforelectronicstates2Π1/2and2Π3/2arederivedfromtheM–Sfunction.TheverticalexcitationenergiesforOx2(x=+1,1)areν[O+12(2Π3/2→X2Π1/2)]=195.652cm1,andν[O12(2Π1/2→X2Π3/2)]=182.568cm1,respectively.Allthespectroscopicdataforelectronicstates2Π1/2and2Π3/2aregivenforthefirsttime.
简介:YBa2Cu3Ox(YBCO)thinfilmsgrownondifferentsubstrateswithand/orwithoutEu2CuO4(ECO)bufferlayerwereinvestigatedbyX-raywideanglediffraction,reflection,diffusescatteringandtopography.TheresultsshowthatfortheyttriastabilizedZrO2(YSZ)substrate,thepresenceofanECObufferlayerimprovesthecrystallinequalityoftheYBCOfilm,whileanegativeeffectisobservedfortheSrTiO3(STO)substrate.ThelateralcorrelationlengthforasamplegrownonaYSZsubstratewithECObufferLayerismuchgreaterthangrownonanSTOsubetrate.TheSTOsubstrateusedhasmosaicstructure.2001ElsevierScienceB.V.Allrightsreserved.
简介:Inthefarfieldoftheintensitydistributionofthebeamdeliveredbyatwo-stagetransient–collisionalexcitationX-raylaser(XRL),anon-expectedinterferencepatternthatisstablefromshottoshothasbeendiscovered.Itisdemonstratedthattheinterferenceiscausedbytheemergenceofanimaginarysourceintheamplifyingplasma,whichisphasematchedtotheradiationofthegenerator.TheobservedphenomenoniscalledanX-raycoherentmirage.Toexplaintheobtainedresults,anewtheoreticalapproachisdeveloped.ThebasicessentialconditionsforformationoftheX-raymirageareformulated,andpossibleapplicationsarediscussed.Thispaperdetailstheexperiments,includingtheformulationofthenecessaryandsufficientconditionsforformationoftheX-raymirage,andpossibleapplicationsarediscussed.
简介:ThestatusoftheEuropeanX-rayFree-ElectronLaser(EuropeanXFEL),underconstructionnearHamburg,Germany,isdescribed.ThestartofoperationsoftheLCLSatSLACandofSACLAinJapanhasalreadyproducedimpressivescientificresults.TheEuropeanXFELfacilityispoweredbya17.5GeVsuperconductinglinearacceleratorthat,comparedtothesetwooperatingfacilities,willgeneratetwoordersofmagnitudemorepulsespersecond,upto27000.Itcanthereforesupportmodesofoperationswitchingthebeamupto30timespersecondamongthreedifferentexperiments,providingeachofthemwiththousandsofpulsespersecond.Thescientificpossibilitiesopenedupbythesecapabilitiesarebrieflydescribed,togetherwiththecurrentinstrumentaldevelopments(inoptics,detectors,lasers,etc.)thatarenecessarytoimplementthisprogram.
简介:Inthiswork,webrieflydiscussanovelclassofmodifiedgravitylikef(T,TG)gravity.Inthisbackground,weassumethenewagegraphicversionofpilgrimdarkenergyandreconstructf(T,TG)modelsfortwospecificvaluesofs.Wealsodiscusstheequationofstateparameter,squaredspeedofsoundandwDE-wDEplaneforthesereconstructedf(T,TG)models.Theequationofstateparameterprovidesphantom-likebehavioroftheuniverse.ThewDE-wDEplanealsocorrespondstoΛCDMlimit,thawingandfreezingregionsforbothmodels.
简介:X-γradiationbelongtotheionizingradiation.Ionizingradiationsinkstoenergyinorganismbutproduceadisservicetotheorganism.Justasmedicine,thedisserviceoftheradiationtowardsOrganismisdecidedbytoacceptradiationquantify,theradiationquantifywasnameddose.Radiationprotection'sbasicmissionsistowanttoresultthedosetofixquantify.InthissurveythedoseatworkplaceanditssurroundingsenvironmentsofHL-2Adevicewasmeasuredandtheassessmentwasgivenout.
简介:SmallangleX-rayscatteringexperimentshavebeenperformedtostudythemicrostructureofmessoporoussilicameterialspreparedbycondensationoftetraethylorthosilicateusingnonionicalkylpolyethyleneoxide(AEO9)andioniccetyltrimethylammoniumbromide(CTAB)surfactantastemplates.Itistheporeswithinthenanometrerangethatproducethemaincattering.ThescatteringofthepuresilicasystemsobeyPorod’slaw.Thismaybebecausethetemplatesproducesomeadditionalscatteringbackgroundandthenmakethescatteringofporesdistorted.TheresultsshowthatthefullremovaloftemplatesfromtheporesofthematerialsbySoxhletextractionisveryeasyforAEO9,butitisdifficultforCTAB.Thepositivedeviationcorrectionisalsoperfromed.
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