简介:Effectsofspacevelocity,reactiontemperatureandsupportacidityonproductdistributionandinductionperiodin1-buteneisomerizationandmetathesisoverMo/mordenite-aluminawereinvestigated.Asrevealedbythecatalyticperformanceresults,inductionperiodandobjectiveproductwerecloselyrelatedtothereactionconditions.Lowerspacevelocityledtolongerinductionperiodandhigherpropeneyield.Theoptimalreactiontemperatureforpropeneproductionisaround150Canditshiftedto100Cforetheneproduction.1-Buteneauto-metathesispredominatedinthereactionnetworkifthesupportwithlowerdegreeofsodiumexchanged.Andpropenegraduallybecamethedominantproductuponincreasingthesupportsodiumexchangedegree.6Mo/H100Na0M-30Alcatalystwithasupportoffullsodiumexchangedegreeexhibitedthehighestpropeneyield.
简介:Takingthe(2+1)-dimensionalBroer-Kaup-Kupershmidtsystemasasimpleexample,somefamiliesofrationalformsolitarywavesolutions,triangularperiodicwavesolutions,andrationalwavesolutionsareconstructedbyusingtheRiccatiequationrationalexpansionmethodpresentedbyus.Themethodcanalsobeappliedtosolvemorenonlinearpartialdifferentialequationorequations.
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简介:Inthispaper,first,weemployclassicLiesymmetrygroupsapproachtoobtaintheLiesymmetrygroupsofthewell-known(2+1)-dimensionalGeneralizedSasa-Satsuma(GSS)equation.Second,basedonamodifieddirectmethodproposedbyLou[J.Phys.A:Math.Gen.38(2005)L129],moregeneralsymmetrygroupsareobtainedandtherelationshipbetweenthenewsolutionandknownsolutionissetup.Atthesametime,theLiesymmetrygroupsobtainedareonlyspecialcasesofthemoregeneralsymmetrygroups.Atlast,someexactsolutionsofGSSequationsareconstructedbytherelationshipobtainedinthepaperbetweenthenewsolutionandknownsolution.
简介:Zr1-xTixCo(x=0,0.1,0.2,0.3)alloyswerepreparedbyarc-meltingmethodandtheeffectofTisubstitutiononhydrogenstoragepropertieswasstudiedsystematically.Hydrogendesorptionpressure-composition-temperature(PCT)measurementswerecarriedoutusingSievert’stypevolumetricapparatusforZrCo(at473K,573Kand673K)andZr1-xTixCoalloys(at673K),respectively.ProductsafterdehydrogenationwerecharacterizedbyX-raydiffraction(XRD).Inaddition,thekineticsofZr1-xTixCohydridewasinvestigatedat473Kand673K,respectively,underhydrogenpressureof5MPa.ResultsshowedthatTisubstitutionforZrdidnotchangethecrystalstructureofZrCophase.Withtheincreaseoftemperaturefrom473Kto673K,theextentofdisproportionationforZrCoalloyincreased.WithTicontentincreasingat673K,thedesorptionequilibriumpressureofZr1-xTixCo-H2systemselevatedandthedisproportionationreactionofZr1-xTixCoalloyswasinhibitedeffectively.TisubstitutiondecreasedthekineticsrateandtheeffectivehydrogenstoragecapacityofZr1-xTixCoalloysslightly.Generallyspeaking,itwasfoundthatZr0.8Ti0.2Coalloyhadbetteranti-disproportionationpropertywithlessdecreaseofeffectivehydrogenstoragecapacitywhichwasbeneficialtotritiumapplicationintheInternationalThermonuclearExperimentalReactor(ITER).
简介:Inthiswork,MoOxpromotedIr/SiO2catalystswerepreparedandusedfortheselectivehydrogenolysisoftetrahydrofurfurylalcohol(THFA)to1,5-pentanediolinacontinuousflowreactor.Theeffectsofdifferentnoblemetals(Ir,Pt,Pd,Ru,Rh),supportsandIrcontentswerescreened.Amongtheinvestigatedcatalysts,4wt%Ir-MoOx/SiO2withaMo/Iratomicratioof0.13exhibitedthebestcatalyticperformance.ThesynergybetweenIrparticlesandthepartiallyreducedisolatedMoOxspeciesattachedonthemisessentialfortheexcellentcatalyticperformanceofIr-MoOx/SiO2.ThecatalystexhibitedabetterhydrogenolysisefficiencyofTHFAwiththeselectivityof1,5-pentanediolof65%–74%ataconversionofTHFAof70%–75%whentheinitialTHFAconcentrationisrangingfrom20wt%and40wt%.AndhighersystempressurewasalsoinfavoroftheconversionofTHFA.Duringastabilitytest,theconversionofTHFAand1,5-pentanediolyieldoverIr-MoOx/SiO2decreasedwithreactiontime,whichcanbeexplainedbytheleachingofMospeciesduringthereaction.
简介:Underinvestigationinthispaperisa(3+1)-dimensionalvariable-coefficientKadomtsev–Petviashviliequation,whichdescribesthepropagationofsurfaceandinternalwaterwaves.ByvirtueofthebinaryBellpolynomials,symboliccomputationandauxiliaryindependentvariable,thebilinearforms,solitonsolutions,B¨acklundtransformationsandLaxpairareobtained.Variablecoefficientsoftheequationcanaffectthesolitonicstructure,whentheyarespeciallychosen,whilecurvedandlinearsolitonsareillustrated.Elasticcollisionsbetween/amongtwoandthreesolitonsarediscussed,throughwhichthesolitonskeeptheiroriginalshapesinvariantexceptforsomephaseshifts.
简介:对将运行于日-地L1点的太阳观测器进行了热设计,重点论述了日-地L1点的轨道外热流计算和Lymanα日冕仪(LACI)反射镜M2光阱、Lymanα日冕成像仪(LADI)滤光片组件、CCD组件、电箱、观测器主体等部分的热设计方案。通过在探测器对日面设置集热板,将观测器的主动加热功耗降低了73%;选用预埋热管的设计方案解决了对日定向观测导致的框架温差问题。仿真分析结果表明,在对日高温工作、对日低温工作、低温存储、轨道转移等4个极端工况下,观测器各组件温度均满足指标要求。该热设计方案以较低的加热功耗,解决了太阳观测器在轨工作阶段的散热、轨道转移阶段的保温等问题,满足CCD焦面工作温度<-50℃的要求。