简介:本发明涉及一种具有多峰分子量分布的聚乙烯树脂,该树脂进一步的特征在于它具有从约0.925g/ccm到约0.950g/ccm的密度,和从约0.05g/10min到约5g/10min的熔融指数(12),和在于它包括至少一种高分子量(HMW)乙烯共聚体和至少低分子量(LMW)乙烯聚合物,以及包括这样树脂的组合物。也提供包括该树脂或组合物的成形制品,特别是管子。
简介:Nitrobenzene-containingindustrialwastewaterwasdegradedinthepresenceofozonecoupledwithH2O2byhighgravitytechnology.Theeffectofhighgravityfactor,H2O2concentration,pHvalue,liquidflow-rate,andreactiontimeontheefficiencyforremovalofnitrobenzenewasinvestigated.TheexperimentalresultsshowthatthehighgravitytechnologyenhancestheozoneutilizationefficiencywithO3/H2O2showingsynergisticeffect.ThedegradationefficiencyintermsoftheCODremovalrateandnitrobenzeneremovalratereached45.8%and50.4%,respectively,underthefollowingreactionconditions,viz.:ahighgravityfactorof66.54,apHvalueof9,aH2O2/O3molarratioof1:1,aliquidflowrateof140L/h,anozoneconcentrationof40mg/L,aH2O2multipledosingmodeof6mL/h,andareactiontimeof4h.Comparedwiththeperformanceofconventionalstirredaerationmixers,thehighgravitytechnologycouldincreasetheCODandnitrobenzeneremovalraterelatedwiththenitrobenzene-containingwastewaterby22.9%and23.3%,respectively.
简介:Alkylationoftoluenewith2-chloro-2-methylpropane(t-Bu-Cl)tosynthesizepara-tert-butyltoluene(PTBT)wascarriedoutinthepresenceoftriethylaminehydrochloride-aluminumchlorideionicliquidsusedasthecatalyst.TheionicliquidswerepreparedwithdifferentmolarratiosofEt3NHCltoAlCl3,andtheeffectofthemolarratiobetweenAlCl3andEt3NHCl,thereactiontime,thereactiontemperature,theionicliquiddosage,aswellasthemolarratiooftoluenetochloro-2-methylpropaneonthealkylationreactionoftoluenewithchloro-2-methyl-propanewasinvestigated.ThetestresultsshowedthattheacidicionicliquidspreparedwithEt3NHClandAlCl3hadgoodactivityandselectivityforthealkylationreactionoftoluenewithalkylchloridetoproducePTBT.TheoptimalreactionconditionswerespecifiedatanAlCl3toEt3NHClratioof1.6,areactiontemperatureof20℃,amassfractionoftoluenetoionicliquidof10%,andachloro-2-methylpropanetotoluenemolarratioof0.5.Underthesuitablereactionconditions,a98%conversionofchloro-2-methylpropaneandan82.5%selectivityofPTBTwereobtained.Ionicliquidscouldbereused5timeswithitscatalyticactivityunchanged,andtheregeneratedionicliquidscanberecycled.
简介:从保护井壁、提高井壁稳定性等技术要求出发,筛选了高效发泡剂、稳泡剂、泥页岩抑制剂,并确定各组分最佳含量,研制了空气泡沫钻井流体体系,该体系由0.3%TWS+0.15%XC+0.03%YIM+0.5%GXG组成。考察了空气泡沫流体抑制页岩水化膨胀、水化分散能力、岩芯浸泡效果及抗温性能。结果表明,该空气泡沫流体体系页岩24h水化膨胀量2.64mm,页岩滚动回收率91.4%,岩芯在配方体系中浸泡24h完好无损,温度90℃时泡沫体系的半衰期仍保持30min以上,表明该泡沫配方体系具有较强的抑制性和良好的抗温性,能够较好地解决空气泡沫钻井中井壁失稳问题。