简介：hePhotocatalyticcharacterizationofTiO2supportedonactivecarbonwasinvestigatedforphotocatalyticdecompositionofdichloroaceticacid.ItwasfoundthatTiO2/ACexhibitedahigherphotocatalyticactivitythanpureTiO2.ThereasonisthatactivecarbonactingaspowerfuladsorbentsupportsmakeshighconcentrationenvironmentsoforganicpollutantmoleculesaroundTiO2particles.

简介：N酰--hydroxy-4-phenyl-oxazolidinethiones能被处理很快在高收益变换成他们的乙醇thiol酉旨与在0è的EtSH

简介：在这研究，一新(乙烯基氯化物)(PVC)poly，为Ho3+离子的膜传感器作为ionophore基于N-phenyl-2-(thiophen-2-ylmethylene)hydrazinecarbothioamide(PHC)被准备。这个传感器与阳离子的变化比较向钬离子表明了好选择和敏感，包括碱，碱的地球，转变和重金属离子。电极的反应性质上的膜作文和pH的效果被调查。详细，建议传感器展出了Nernstian行为(与20.4的一个斜坡??洀????x

简介：Inthiswork,acidfunctionalizedmulti-wallcarbonnanotubes(MWCNTs)weremodifiedwithimidazolium-basedionicliquids.Theselectiveoxidationofvariousalcoholswithhydrogenperoxidecatalyzedby[PZnMo_2W_9O_(39)]~(5-),ZnPOM,supportedonionicliquids-modifiedwithMWCNTs,MWCNTAPIB,isreported.Thiscatalyst[ZnPOM@APIB-MWCNT],wascharacterizedbyX-raydiffraction,scanningelectronmicroscopy(SEM)andFT-IRspectroscopicmethods.Thisheterogeneouscatalystexhibitedhighstabilityandreusabilityintheoxidationreactionwithoutlossofitscatalyticperformance.

简介：TwonewintercalationcompoundsFe0.90PS3(phen)0.41(1)(phenstandsfor1,10-phenanthrolineincludingapartof1,10-phenanthrolineH+)andFe0.83PS3(bipy)0.34(2)(bipystandsfor2,2’-bipyridineH+)weresynthesizedbythereactionofthelayeredFePS,with1,10-phenanthrolineor2,2’-bipyridineinthepresenceofaniliniumchloride.Theywerecharacterizedbyelementalanalyses,powderX-raydiffraction(XRD),infraredspectroscopy.Thelatticespacingoftheintercalatewasexpandedby0.90nmforFe0.90PS3(phen)0.41and0.57nmforFe0.83PS3(bipy)0.34withrespecttothepristineFePS3,indicatingthattheringplaneoftheguestsisperpendiculartothelayerofthehost.TheUV-visabsorptionspectraofthefiltrateinpreparationoftheintercalatesindicatethat1,10-phenanthrolineor2,2’-bipyridinealsoactsasacomplexingagenttoremoveintralamellarFe2+ionsintothesolutionduringintercalation.Themagneticpropertiesof1and2werestudied.

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简介：存取2-substituted-N1-carbethoxy-2,3-dihydro-4(1H)的一条灵巧、有效、新奇的途径-quinazolinones是被代替的N-carbethoxyanthranilamide的冷凝作用用p-toluenesulfonic酸在refluxing2,2,2-trifluoroethanol或hexafluoroisopropanol与烷基，aromatic或异种aromatic醛开发催化剂。

简介：Anumberofnaphthalenedonorcompoundsthatpossessanadamantanaminebindingmoietyandan(OCH2CH2)n(nn1,2,3,4,6,8)spacerweresynthesized.Thefluorescencequenchingbetweenthesedonorsubstratesandmono-6-O-p-nitrobenzoyl-β-cyclodextrin(pNBCD)andmono-6-O-m-nitrobenzoyl-β-cyclodextrin(mNBCD)wasstudiedindetail.Itwasfoundthatveryefficientfluorescencequenchingcouldoccurinthesesupramolecularsystems.Thisquenchingwasattributedtothephotoinducedelectrontransferinsidethesupramolecularassemblybetweenthenaphthalenedonorsandcyclodextrinacceptors.DetailedStern-VolmerconstantsweremeasuredandtheywerepartitionedintodynamicStern-Volmerquenchingconstantsandstaticbindingconstants.Itwasdemonstratedthatthebindingconstantsbetweenallthenaphthalenecompoundsandcyclodextrinsarethesameastheypossessthesamebindingsite,i.e.,adamantanamine.

简介：本文通过电化学测量（循环伏安法）和量子化学计算（CNDO/2法）对几种原子簇化合物[（MoS4）2FeL]3-（其中配位体L为O2CH3CN,O2,O）的氧化还原活性进行了研究.实验测量与理论计算所得结果相符.研究结果表明这几种阴离子的还原皆为不可逆的单电子转移过程.它们接受电子的能力按如下次序递增:[（MoS4）2FeO2CH3CN]3-<[（MoS4）2FeO2]3-<[（MoS4）2FeO]3-

简介：利用2,3-二甲基吡嗪与硝酸铜及氯化铜合成了铜配位聚合物[Cu（Mepz）]2n＋（Mepz=2,3-二甲基吡嗪）,并通过单晶X射线衍射方法进行了表征.该晶体属于正交晶系,空间群为：Cmca,相关晶胞参数为：a=0.68617（11）nm,b=1.3652（2）nm,c=1.9533（3）nm,V=1.8297（5）nm3.该配位聚合物中的Cu原子与2个N原子、2个O原子和2个Cl原子配位,形成了一个稍微畸变的配位八面体,每相邻的2个配体之间通过Cu离子与吡嗪环上的2个N原子配位连接成无限延伸的一维链状结构,并通过分子间的氢键作用进一步将其连接成为二维的超分子网络结构.

简介：过量臼齿的卷VmEand运动学的粘性为丙烯乙二醇monomethyl醚(1-methoxy-2-propanol)的二进制混合物作为作文的一个函数被测量了，MeOCH2CH(哦)我，丙烯乙二醇monoethyl醚(1-ethoxy-2-propanol)，EtOCH2CH(哦)我，丙烯乙二醇monopropyl醚(1-propoxy-2-propanol)，PrOCH2CH(哦)我，丙烯乙二醇monobutyl醚(1-butoxy-2-propanol)，BuOCH2CH(哦)我，和丙烯乙二醇tert丁基醚(1-tert-butoxy-2-propanol)，t-BuOCH2CH(哦)我与1-butanol臼齿的体积是的过量为系统2-butanol+1-methoxy-2-propanol，和+1-propoxy-2-propanol越过为有1-butanol的所有系统的全部范围ofcomposition否定、积极，为为系统2-butanol+1-ethoxy-2-propanol，和+1-tert-butoxy-2-propanol的系统2-butanol+1-butoxy-2-propanol，和变化符号否定。从试验性的数据，在从xii的动态粘性的偏差被计算了。两过量臼齿的卷和粘性偏差被方法用一个Redlich-Kister类型多项式方程相关为二进制系数和标准错误的评价最少平方。

简介：The1.3-dipolarcycloadditionreactionof2-trifluoromethyl-oxazoloneandtheactivatedcarbon-carbonmultiplebondwasstudiedandgaveaconvenientwaytosynthesize2-trifluoromethylpyrrolederivatives.

简介：热行为，机制和在一个规划温度的模式的标题混合物的发热的第一阶段的分解反应的运动参数借助于DSC，TG-DTG和红外被调查了。反应机制被建议。在微分形式，明显的激活精力(Ea)和这反应的pre指数的因素(A)的实验运动模型功能是(1-)?1.119，211.3kj/mol和1020.2s?1分别地。混合物的热爆炸的批评温度是202.2爠慥瑣潩?㈠低??湡敧漠??????????????鈿酌顛鱎?????疞????陴?陴?T

简介：以4-[（8-羟基-5-喹啉）偶氮]-苯磺酸与氯化钴为原料,采用溶剂热法通过原位反应合成{[Co（5-氨基-8-羟基喹啉）_2]·H_2O}_n,并通过X-射线单晶衍射方法确定了该配合物的晶体结构.结构分析表明：标题配合物属于斜方晶系,Pbcn空间群,晶胞参数a=1.321（2）nm,b=0.811（2）nm,c=1.511（2）nm,α=β=γ=90.00°,V=1.619（3）nm~3,Z=4,R_1=0.0516,wR_2=0.1025.配合物中存在ππ堆积相互作用和氢键作用,将配合物连接形成三维超分子网络结构.

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简介：一系列1-[2-(2-methoxyphenylthio)本甲基]-4-arylpiperazines衍生物基于5-HT1A/SSRI药设计策略被设计并且综合。综合混合物为他们的双5-HT1A/5-HTT活动被评估。

简介：Newmethodsfordehydrogenationofsteroidal2,5（10）-dieneswith2,3-dichloro-5,6-dicyano-1,4-benzoquinone（DDQ）orpyridiniumhydrobromideperbromide（PHP,Py·HBr·Br2）toaromaticAringsteroidinquantitativeyieldinshorttimearedescribed.

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简介：ＴＨＥ　ＳＵＰＰＯＲＴＥＤ　ＧＯＬＤ　ＣＡＴＡＬＹＳＴＳ　ＦＯＲ　ＣＬＯＳＥＤ　ＣＹＣＬＥ　ＣＯ２　ＬＡＳＥＲＴＨＥＳＵＰＰＯＲＴＥＤＧＯＬＤＣＡＴＡＬＹＳＴＳＦＯＲＣＬＯＳＥＤＣＹＣＬＥＣＯ２ＬＡＳＥＲ￥ＺｈｅｎｇＰｉｎｇＨＡＯ；ＬｉＤｕｎＡＮ；...

简介：Newphosphorus-andselenium-containingheterocyclyes,1,3,2,6-dioxaphosphaselena-cyclooctanes(la-1h),weresynthesizedbythereactionofbis(2-hydroxyethyl)selenidewithRP(X)Cl2whereR=alkoxyl,aroxyl,arylandX=Oorlonepair.Theirstructuresweredeterminedbyspectro-scopiesandelementalanalysesandfinallyconfirmedbytheX-raycrystallographicanalysisof1c.Themolecularstructuresoftheheterocycleswerediscussedintermofconformationalanalysis.