简介:Calciumtitanatedopedwithpraseodymiumwaspreparedthroughsolidstatereactionanditexhibitedintenseredemissionat612nm.Phosphorswerecharacterizedforphotoluminescence,thermo-luminescenceandafterglowemissions.Studyofeffectsofrareearthsonphotoluminescenceaswellasafterglowintensitywasreported.Presenceofgadoliniumenhancedluminescence.Presenceofsomemonovalentionsenhancedbothafterglowandphotoluminescenceemission.Thermo-luminescenceglowcurveswereanalyzedand...
简介:Er~(3+)andLa~(3+)codopedY_2O_3nanocrystallinepowdersweresynthesizedbygelcombustionmethodandcharacterizedwiththermalanalysis,X-raydiffraction(XRD),transmissionelectronmicroscopy(TEM),high-resolutionTEM(HRTEM)techniquesandfluorescencespectroscopy.Afterbeingcalcinedat1200oC,the(Y_(1–x)La_x)_2O_3:Er~(3+)powderswereconfirmedtobecubicY_2O_3phasewiththecrystallinegrainsizeintherangeof20–40nm.TheEr~(3+)emissionat1.53μmfromthe~4I_(13/2)→~4I_(15/2)transitionwasobserved,whichwasfoundtobeenhancedbyintroducingLa~(3+)ions.SuchenhancementcouldbeattributedtotheadjustmentofEr~(3+)ions'localenvironmentbythecodopingofLa~(3+)ions,leadingtotheincreasedgroundstateabsorptioncrosssectionofEr~(3+)ions.
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简介:利用扫描电子显微镜、能谱仪、光学显微镜及电子探针等对比分析了Q235B钢板拉伸试验后出现分层和不分层的两组试样,研究引起钢板拉伸分层的原因。试验结果表明:分层试样中心含有大量的MnS、Si02等夹杂,心部存在宽大的铁素体条带,是导致Q235B铜板出现拉伸分层现象的主要原因。根据分析结果提出改进措施以减少和消除此种缺陷。