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500 个结果
  • 简介:本文用少体方法对A≤的S壳超核动力学结构进行系统研究,同时研究A≤3的普通原子核的结构,通过比较,看到了超子进入核内使结构产生变化,超子的加入,造成壳心核的缩聚,核子间均方根距离缩短,超子在核内起胶粘凝聚作用。对这些核体系内部结构的研究表明.粒子间相对运动主要处于Os轨道。

  • 标签: 均方根距离 相对运动 动力学结构 Λ超核 基态能量 互作用
  • 简介:Highlyselectivedimerizationofα-methylstyrene(AMS)waseffectedusingaBroenstedacidicionicliquid,[Hmim]^+BF4^-,assolventaswellascatalyst,providingtheindustrialhigh-valueolefin,2,4-diphenyl-4-methyl-1-pentene(1-PT).Thedesireddimer1-PTcouldbeobtainedin90%yieldat96%conversioninthedimerizationofAMSunderoptimizedconditions.Featuresoftheprocedureincludeuseofreadilyavailableionicliquid-catalyst,exclusionofvolatileorganicsolvents,higherselectivityandefficiencyfor1-PT.

  • 标签: 2 4-联苯-4-甲基-l-戊烯 ^+BF4^- 离子性液体 化学结构 催化剂
  • 简介:采用水热法合成了诺氟沙星金属配合物[Cu(C16H18N3FO3)2(C14H8O5)(H2O)3],并应用X-射线单晶衍射技术对其结构进行测定,确定了其几何构型,探讨了金属离子与药物分子的配位方式.采用琼脂扩散法对比4种常见细菌对药物的敏感性,结果表明合成的金属配合物具有一定的抑菌作用.

  • 标签: 诺氟沙星 金属配合物 合成 晶体结构 抑菌作用
  • 简介:采用2步水热法合成了LaPO4∶Eu3+-Fe3O4复合材料.在LaPO4∶Eu3+-Fe3O4复合材料中,LaPO4∶Eu3+为单斜晶相,呈纳米棒状,纳米棒的直径和长度分别为20-100nm和0.2-1μm;Fe3O4为正交晶相、呈20-30nm的颗粒状,Fe3O4粒子紧紧附着在LaPO4∶Eu3+纳米棒的表面;样品的磁性和发光性质研究表明所合成的LaPO4∶Eu3+—Fe3O4复合材料既具有发光性质又具有磁性.

  • 标签: LaPO4∶Eu3+-Fe3O4 水热 发光 磁性
  • 简介:Li4Ti5O12(LTO)/carbonnanotubes(CNTs)compositematerialissynthesizedbasedonasolid-statemethodbysand-milling,spray-dryingandcalciningat8508CunderN2flow.TheLTO/CNTssampleswith1wt%and3wt%weightratioofCNTsadditionandthepristineLTOsampleareprepared.TherateperformanceandthethermalstabilityofthesesamplesareinvestigatedbasedonLiMn2O4(LMO)/LTOfull-cell.TheresultsshowthattheweightratioofCNTsadditionhasdistincteffectonLTOperformances.ThecompositematerialsofLTOcompositedCNTshavebetterperformanceathigh-rateduetotheintercalationenhancementbyconductivenetworkofCNTs.Atsecond,theoverchargingtemperatureresponseofthecell’ssurfacewith1wt%CNTsadditionisthelowest.Theparticlesizedistributionismeasuredandthemostuniformparticlesareobtainedwith1wt%CNTsaddition.ThistrendcouldexplainthatthemediumquantityofCNTsisoptimaltoimprovetheheatandmasstransferandpreventtheproblemsofcrystallitegrowinginterferenceandaggregationduringthecalcinationprocess.

  • 标签: 下线 服务 迁移
  • 简介:1问题背景A题是希望同学们通过搜集相关数据,尝试构建深圳治水提质工程数学建模,量化分析雨、污'分流'与'混流'收集机制对污水处理系统以及海绵城市建设的影响,在既能达到治污要求,又能尽量节省开支的原则下,给出区域治污时实施'清源'、'截排'措施的判定条件,并特意指出了光明新区毛洲河上游的治理情况。当前,深圳市水环境质量差、内涝积水多发、频发,影响和损害群众健康,不利于城市正常运行和经济

  • 标签: 工程数学 收集机 判定条件 水环境质量 混流 问题背景
  • 简介:Three-dimensional(3D)flowerlikehierarchicalZn2GeO4andMn2+-dopedZn2GeO4microstructureshavebeenpreparedbyafacilehydrothermalapproach.X-Raydiffraction(XRD),fieldemissionscanningelectronmicro-scopy(FESEM),transmissionelectronmicroscopy(TEM)andphotoluminescence(PL)spectrometrywereemployedtocharacterizethesamples.SuchflowerlikehierarchicalZn2GeO4microstructureswithanaveragediameterof3―4μmwerefoundtobeconstructedbyabundantsinglecrystallinenanorodsofabout90nmindiameter.TheluminescentpropertiesofZn2GeO4:xMnphosphorswithdifferentcontentsofMn2+asanactivatorwereinvestigated.TheMn2+-dopedsamplesshowedgreenluminescencecorrespondingtothed-dtransitionofMn2+undertheirradiationofUVlight.Theredshift(from531nmto538nm)inλemwithincreasingMn2+contentwasobservedintheluminescentspectra,whichshouldbeattributedtoaweakcrystalfieldbecauseofthesubstitutionofZn2+byMn2+atadistortedtetrahedrallatticesite.

  • 标签: 锰掺杂 体系结构 场发射扫描电子显微镜 水热法 透射电子显微镜 X-射线衍射
  • 简介:Pureandneodymium-dopedgadoliniumcalciumoxoboratecrystalsofhighqualityweregrownbytheCzochralskimethod.Theorientationofcrystalwaspreciselydetermined,andthesamplesformeasurementswereprepared.Throughsynchrotronx-raytopographyandhigh-resolutionx-raydiffractometry,thetwinstructurewasdiscovered.Somepropertiessuchasthefigureofmeritvalue,anddielectric,piezoelectric,andelasticconstantsweremeausuredalongwithadiscussionoftheanisotropyofthelaserproperties.

  • 标签: GdCa4O(BO3)3晶体 钕掺杂 硼酸盐晶体 Nd:GdCa4O(BO3)3晶体 晶体生长 形貌学
  • 简介:Highlyefficientsheet-likeBiPO4/zeoliteandball-flower-likeBiPO4/zeolitehadbeensuccessfullysynthesizedbyastandardhydrothermalmethod.Theadditionofassistantreagentinthehydrothermalsystemispromisingtoobtainspecialmorphology.Theassistantreagent(EDTA)actsasagrowthmodifierofcrystal.Thepossibleformationmechanismsofsheet-likeBiPO4/zeoliteandball-flower-likeBiPO4/zeolitewereschematicallydiscussed.Adetailedstudyofsheet-likeBiPO4/zeoliteandball-flower-likeBiPO4/zeoliteimpactedonthephotodecolorationmethyleneblue(MB)solutionshowedthatthecompositehadahighlyreusableandstablepropertyforlong-runphotocatalyticapplication.

  • 标签:
  • 简介:Poly(β-carboxyethylmethylsiloxane)-LiClO4andpoly(β-alkoxylethylmethylsiloxane)-LiClO4crosslinkedfllmshavebeenprepared.Theionicconductivityofthefilmsdependsonthepolymerspecies,concentrationoflithiumperchlorate,temperatureandcontentofcrosslinkingagent.Theeffectofhighpolarorganicsolvent1,4-butyrolactoneontheionicconductivityandmechanicalpropertiesofpoly(β-carhoxyethylmethylsiloxane)-LiClO4systemwasalsoinvestignied.

  • 标签: IONIC conductivity: Poly(β-alkoxycarbonylethylmethylsiloxane)- LITHIUM Complex 1
  • 简介:Ionicconductivityvaluesforsegmentedpolyetherpolyurethaneurea(PEUU)complexeswithLiClO4weredeterminedandvaluesashighas~1.1×10-4S·cm-1at353Kand~1.0×10-5S·cm-1at306Kwereachieved.TheionicconductivitydatawereanalyzedusingtheVTF(Vogel-Tamman-Fulcher)equationandWLF(Williams-Landel-Ferry)typeequation.Valueshavebeenestimatedforthe"apparent"activationenergiesofiontransportfromVTFequationandtheylieintherange2.70—5.53kJ·mol-1.

  • 标签: Segemented POLYETHER polyurethaneureas Complex: Solid IONIC
  • 简介:Anovelseriesofcalix[4]azacrownderivativeswiththereactionbetweencalix[4]azacrownandthedifferentfluorophorederivatives,whichmaybeusefulfluorescentreceptors,havebeensynthesizedandstructurallycharacterizedbyIR,~1HNMR,~(13)CNMRandMS.Fromtheiranalysisdata,itwasfoundthosecompoundsadoptedaconeconformation.

  • 标签: 荧光衍生物 氮杂冠 合成 核磁共振氢谱 衍生产品 分析数据
  • 简介:LetMbeapositivequaternionicKhlermanifoldofdimension4m.Wealreadyshowedthatifthesymmetryrankisgreaterthanorequalto[m/2]+2andthefourthBettinumberb_4isequaltoone,thenMisisometrictoHP~(m).Thegoalofthispaperistoreportthatwecanimprovethelowerboundofthesymmetryrankbyoneforhighereven-dimensionalpositivequaternionicKahlermanifolds.Namely,itisshowninthispaperthatifthesymmetryrankofMwithb_4(M)=1isgreaterthanorequaltom/2+1form≥10,thenMisisometrictoHP~m.OneofthemainstrategiesofthispaperistoapplyamoredelicateargumentofFrankeltypetopositivequaternionicKhlermanifoldswithcertainsymmetryrank.

  • 标签: 四元数 流形 高功率微波 对称约束 分类 高等级