学科分类
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173 个结果
  • 简介:WesummarisetheHEPVis'01workshopheldinMay2001atNortheasternUniversity,Boston.Generalissuessuchasarchitectureanddesignoftheframeworksandtoolkitsaredescribedaswellasthestatusofawiderangeofgenericanalysisandvisualisationtoolsandexperiment-specificsystems.

  • 标签: 高能物理实验 数据分析 交互图形
  • 简介:[1]BASFUSP4479906[2]BASFBP1443541[3]BASFDE3618265[4]WangL.,WuZ.,ChinaLeather,26(8),11,(1997)[5]YuanL.,DinY.,ChineseChemistryBulletin,(2),19(1988)[6]KurokiH.,ChemistryofDyeingTheory(ChineseTranslation),TextileIndustryPress,Beijing,89(1982)[7]WangS.,LiP.,WuZ.DyestuffIndustry(Chinese),34(4),1,(1997)[8]Tian,Y.,Wu,Z.,Wang,G.,Zhang,S.J.ChineseChem.Eng.,46,156(1995)[9]Tian,Y.,Wang,G.,Wu,Z.,J.ChineseChem.Eng.,47,75(1996)[10]Lycka,A.,DyesandPigment,32,11(1996)[11]Griffith,J.,ColourandConstitutionofOrganicMolecules,AcademicPress,London,191(1976)

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  • 简介:Dibromobiphenylreactedwithcynomethylanioninammoniaunderirradiationtoformnucleophilicbis-substitutedproductinhighyieldwithoutsubstantialmonosubstitutedproduct.Quantumyieldsfortheformationsofbis-andmonosubstitutedproductswerefoundtobe85.6and2.3×10-6respectively,whilethecorrespondingpseudo-first-orderrateswere6.9×10-3and5.2×10-10mol.L-1.S-1.Blockupthepossibleelectrontransferof4-brome-4’-cyanomethylbiphenylylradicalanionto4-cyanometbyl-biphenylylradicalandbromineion.

  • 标签: PHOTOCHEMISTRY SRN1 REACTION electron TRANSFER dibromobiphenyl.
  • 简介:Ahomologousseriesof4’-methylphenyl4"-[(4-alkoxy-2,3,5,6-tetrafluorophenyl)ethynyl]-benzoateshavebeensynthesized.Polarizingmicroscopictexturalobservationshowsthatsuchcompoundsexhibitenantiotropicnematicphase.

  • 标签: Liquid crystal 1 4-tetrafluorophenylene SYNTHESIS NEMATIC
  • 简介:Thesynthesisofopen-fiameworkmetalphosphateshasbeenasubjectofintenseresearchowingtotheirinterestingstructuralchemistryandpotentialapplicationsasionexchangers,catalystsandadsorbents.Alargenumberofthesematerialsaresynthesizedinthepresenceoforganicaminesasstructure-directingagents.Recently,manyresearchactivitieshavefocusedonthesynthesisofinorganic-organichybridframeworks.Ascomparedwithinorganicligands,theadvantageofusingorganicmultidentateligandsistheefficacyofrationaldesignofcrystallinesolidsthroughtheircoordinatingpropensitiesandgeometries.

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  • 简介:Thesynthesisandphasebehaviorofaseriesof4’-alkyloxy-4-hydroxybiphenylswerediscribed.Theeffectsofreactionconditionsontheyieldsofproductswereinvestigated.Thecharacterizationsofthermotropicliquidcrystallineproductsforthetypeandthermalpropertiesarediscussedthroughtheuseofdifferentialscanningcalorimetry,polarizingmicroscopy.

  • 标签: crystalline ATTRACTIVE spectrometer PHOTOGRAPH CALORIMETRY melting
  • 简介:Thestructureofpolyimidefrom1,4-bis(3’,4’-dicarboxyphenoxy)benzeneand4,4’-oxydianilinefilmspecimensbeforeandafterhotstretchinghasbeeninvestigatedbyWAXD,DSCandFTIR.AsevidencedbyboththeWAXDandDSCresults,itcouldbebelievedthatstraininducedcrystallizationdidtakeplaceafterhotstretching.Meanwhile,shiftingpositionandsplittingofsomebandpeaksexistedontheFTIRspectrogramswereexplainedintermsoftheclosepackingofchainsandthechangesofinter-molecularcharge-transferinteractionbetweenimidegroupsandaromaticgroupsuponcrystallization.

  • 标签: POLYIMIDE ORIENTATION CRYSTALLIZATION FTIR
  • 简介:On △I= Bifurcation PhenomenaOn△I=BifurcationPhenomena¥ZhangJingye;YangSunandMikeGuidryTheexperiments-bythenew7--raydetector...

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  • 简介:Emissionquenchingof[Ru(bpy)2(4,4’-dcbpy)](PF6)2(1)bybenzenamine,4-[2-[5-[4-[4-dimethylamino]phenyl]-4,5-di-hydro-1-phenyl-1H-pyrazol-3-yl]-ethenyl]-N,N-dimetyl(2)or1,5-diphenyl-3-(2-phenothiazine)-2-pyrazoline(3)wasobserved.Measurementsoftheemissiondecayof1beforeandafteradditionof2or3bysinglephotoncountingtechniquecon-finnedtheobservations.Theemissionquenchingof1by2or3wassubmittedtoStern-Volmerequation.Itwascalculatedthatthequenchingrateconstants(kq)are5.5×109(mol/L)-1s-1for2and4.0×109(mol/L)-1s-1for3,respectively.Theseresultsindicatedacharacterofdynamicquenchingprocess.Thesinglet-stateof2or3wasalsoquenchedby1.ThequenchingbehaviorsdidnotconformtotheStern-Volmerequationandinvolvedbothstaticanddynamicquenchingprocesses.Theapparentquenchingrateconstant(kapp)wascalculatedtobe3×109(mol/L)-1fortheinteractionofexcited2with1,and1.2×109(mol/L)-1forthatofexcited3wit

  • 标签: RUTHENIUM COMPLEXES PYRAZOLINE compounds electrontransfer dynamic
  • 简介:Therearemoreandmorecountriestoakeanefforttothestudiesofvanadiumalloyforfusionapplication.NIFSinJapanhasrecentlydevelopedan80kgheatV4Cr4Tialloy(NIFS-heat2)aftertheproductionofa500kgscaleV4Cr4TiinU.S.severalyearsago.PropertyevaluationofthealloyhasbeenputintoaninternationalcollaborationprogramunderthecoordinationofIEA(InternationalEnergyAgency).SWIPhasjoinedthecollabrationonthehydrogenembrittlementresistanceevaluationofthealloyt.

  • 标签: 钒合金 氢脆变 阻抗 NIFS
  • 简介:ThedevelopmentoftheGEANT4applicationforALICEsimulationwithinthealiRootframeworkisdescribed.TheG3toG4approachadoptedbyALICEcollaborationisexplained.Theoverviewofthedesign,presentimplementationandfunctionalityispresentedandtheremainingproblemsarediscussed.

  • 标签: ALICE实验 软件开发 GEANT4
  • 简介:SinceitserliestyearsofR&D[1],theGEANT4simulationtoolkithasbeendevelopedfollowingsoftwareprocessstandardswhichdictatedtheoverallevolutionoftheproject.Thecomplexityofthesoftwareinvolved,thewideareasofapplicationofthesoftwareproduct,thehugeamountofcodeandCategorycomplexity,thesizeanddistributednatureoftheCollaborationitselfareallingredientswhichinvolveandcorrelatetogetherawidevarietyofsoftwareprocesses.Althoughin"production"andavailabletothepublicsinceDecember1998,theGEANT4softwareproduct[1]includesCategoryDomainswhicharestillunderactivedevelopment.Thereforetheyrequiredifferenttreatmentalsointermsofimprovementofthedevelopmentcycle,system,testingandusersupport,ThisarticleismeanttodescribesomeofthesoftwareprocessesastheyareappliedinGEANT4forbothdevelopment,testingandmaintenanceofthesoftware.

  • 标签: GEANT4 软件处理 软件开发
  • 简介:Treatmentof4-amino-3-(1-aryl-5-methyl-1,2,3-triazol-4-yl)-5-mercapto-1,2,4-triazoles/2-amino-5-(1-aryl-5-methyl-1,2,3-triazole-4-yl)-1,3,4-thiadiazoleswithbenzaldehyde,acetoneandω-bromoacetophenonewastestedandcompared.ThetitlecompoundsSchiffbases,amides,imidazolo[2,1-b]-1,3,4-thiadiazolesand7H-s-triazolo[3,4-b]-1,3,4-thiadiazineshavebeenconfirmedbyelementalanalyses,^1HNMR,IRandMSspectra.AllthecompoundshavealsobeenscreenedfortheirantibacterialactivitiesagainstB.subtilis,S.aureusandE.coli.

  • 标签: 合成 抗菌活性 4-氨基-3-(1-芳基-5-甲基-1 2 3-三唑-4-基)-1 3 4-噻重氮 衍生物
  • 简介:TheGAUDIsoftwareframeworkistobeusedforallevent-processingapplicationsintheLHCbexperiment.TheGEANT4toolkithasbeenintegratedintoGAUDItoformthebasisoftheLHCbsimulationprogramGAUSS.Thebenefitsofthisapproacharethatitpermitsre-useofbasicservices,suchaspersistency,interactivityanddatavisualization,aswellasphysicsalgorithmsthatwereoriginallydevelopedinthecontextofthereconstructionandanalysisprograms.FollowingtheGAUDIphilosophy,theintegrationhasbeenachievedbydevelopinganumberofserviceswithabstractinterfacesthatcanbepluggedinatrun-time.Wedescribetheoveralldesignanddetailsofthecomponentsforinterfacingthedetectorgeometry,theprimaryinteractionandtheoutputfromtrackingparticlesthroughthedetector.

  • 标签: GAUDI软件 数据处理 事件模拟
  • 简介:IntroductionAconsiderableinteresthasbeenshownintheinvestigationofmixed-donormacromolec-ularligandscomplexingtransitionions[1]...

  • 标签: CRYSTAL STRUCTURE Free LIGAND Mixed donor
  • 简介:ThespinelLiMn2O4-x(SO4)xcompoundcathodematerialsweresynthesizedbysolid-statereactionofthecalculatedamountsofLiOH·H2O,MnO2andMnSO4.Theresultsoftheelectrochemicaltestdemonstratedthatthesematerialsexhbitedexcellentelectrochemicalproperties.Thehighestreversiblecapacityoftheseseriesofcathodematerialswas-120mAh/g,andafter50cycles,thisreversiblecapacitywasstillaround116mAh/gwithnearly100%reversibleefficiency,whichrevealedthatdopedsulfateioncouldimprovethestructuralstabilityofspinel.

  • 标签: 合成 电化学性 负极材料 尖晶石型硫酸锰酸锂 LiMn2O4-x(SO4)x 锂离子二次电池