简介:ElectrocrystallizationMechanismofTungsteninMoltenKF-B_2O_3-K_2WO_4WenZhenhuanandLiGuoxun文振环,李国勋(GeneralResearchInstiiuteforNo...
简介:polyacrylonitrile(平底锅)上的electrodepositingFe-Cr2O3合成涂层的过程基于碳纤维,它的催化graphitization被学习。有或没有electrodepositedFe-Cr2O3合成涂层的碳纤维是在不同温度对待的热,结构的变化被XRD,拉曼光谱学和SEM描绘。结果显示那Fe-Cr2O3合成涂层在低温度在碳纤维的graphitization上展出重要催化效果。当Fe-Cr2O3-coated碳纤维是时,热对待在1300?慢敳?慣'R湯映扩牥映汥?獡琠敨瀠敲畣獲牯映汯潬敷?祢椠灭敲湧瑡潩?楷桴爠獥湩?潭摬湩?湡?敨瑡琭敲瑡敭瑮楴?楴吗??
简介:Thecorrosionfatiguebehaviorofepoxy-coatedMg–3Al–1Znalloywasinvestigatedinairand3.5wt%NaClsolution.Epoxycoatingasanewmethodwasusedtoimprovethecorrosionfatiguepropertyofthematerial.Resultsshowthatthefatiguelimit(FL)ofthecoatedspecimensishigherthanthatoftheuncoatedspecimensin3.5wt%NaClsolutionbecauseofthestrengtheningandblockingfunctionsoftheepoxycoating.TheFLofthecoatedspecimensin3.5wt%NaClsolutionisashighasthatinair.Itimpliesthatthecoatedspecimensarenotassensitivetotheenvironmentasthemagnesiumalloy.Thelowtensilestrengthandtheshortelongationofthepureepoxycoatingleadtothatthefatiguecrackofthecoatedspecimenisalwaysinitiatedfromtheepoxy-coatingfilmPoresandpinholesacceleratethefatiguecrackinitiationprocess.PinholesarecausedbythecorrosionreactionsbetweentheepoxycoatingandtheNaClsolution.
简介:Solventextractionofpalladium(Ⅱ)fromhydrochloricacidsolutionwith2-n-octyl-4-isothiazolin-3-one(OIT)/cyclohexanewasstudied.Effectsofdifferentparametersonextractionefficiencywereevaluated.99.96%and98.26%palladium(Ⅱ)couldbeeffectivelyextractedwith0.018mol·L-1OIT/cyclohexaneof0.1and4.0mol·L-1HClmedium,respectively.Nonpolarsolventandlowaciditycouldimprovetheextractingefficiency,andsuccessfullystrippalladium(Ⅱ)fromtheloadedorganicphasewasachievedwith0.5mol·L-1(NH2)2CSsolution.ItwasproposedthattheextractionofPdcomplexesfromHClmediumproceededthroughtheionassociationmechanismbyslopemethod,NMRandFT-IRspectra.
简介:Fe(OH)3precursorsolwaspreparedbyasol-gelmethod.Theprecursorsolwasdippedontotheabsorbentcotton,andgelwasformedontheabsorbentcottontemplateafterthevolatilizationofmoisture.Fe2O3microtubulesweresynthesizedaftertheprocessofself-propagationorcalcination.Thephase,morphology,andparticlediameterofthesampleswereexaminedbyX-raydiffraction(XRD)andscanningelectronmicroscopy(SEM),andthemagneticpropertiesofthesamplesweremeasuredusingavibratingsamplemagnetometer(VSM).TheexternaldiametersofFe2O3microtubulesrangedbetween8and13μm,andthewallthicknessesrangedbetween0.5and2μm.ThetypeofthecalcinationmethodplaysasignificantroleindevelopingtheFe2O3phaseandthevariationinthemagneticpropertiesinthesol-geltemplatecomplexingmethod.γ-Fe2O3wassynthesizedbyaself-propagationmethod.However,α-Fe2O3wassynthesizedaftercalcinationat400°Cfor2h.Thecoercivityofthesamplessynthesizedbycalcinationat400°Cfor2hafterself-propagationwasfoundtoincreasesignificantly,therebypresentinghardmagneticproperties.
简介:采用化学平衡模拟软件GEMS预测了锌湿法冶金过程中涉及的锌在Zn(Ⅱ)-NH3-H2O和Zn(Ⅱ)-NH3-Cl--H2O体系中的溶解度,并构建了其含锌物种分布图和优势区图。采用平衡实验方法测定了相同条件下锌的溶解度,其结果与预测结果相吻合。含锌物种的分布图和优势区图表明,在弱碱性条件下,2个体系均为以锌氨和羟基锌氨配合物为溶液的主要物种,其中Zn(NH3)24-为主要优势物种;在Zn(Ⅱ)-NH3-Cl--H2O体系中,锌氨氯三元配合物的形成能有效增大锌在中性条件下的溶解度,在该体系中存在Zn(OH)2、Zn(OH)1.6Cl0.4和Zn(NH3)2Cl23种固相,固相产物的形成取决于体系中总锌、总氨和总氯浓度。这些热力学平衡图表明了体系中各种物种之间的相互影响作用,并预测了总氨和总氯浓度的变化对锌溶解度的影响,为锌湿法冶金提供了热力学数据。
简介:Pt(Ⅱ)andPd(Ⅱ)complexeswith2',3',4',5,7-pentahydroxy-flavoneweresynthesizedandcharacterizedbyelementalanalysis,molarconductance,IR,1HNMR,TG-DTA,UV-Visspectroscopictechniques,andfluorescenceanalysis.Thescavengingeffectonthesuperoxideradical(O-2)andtheinhibitoryeffectonlipidperoxideswerealsoinvestigated.Boththeligandandthecomplexesexhibitscavengingeffectonsuperoxideradicals,andtheeffectofthecomplexesisgreaterthanthatoftheligand.ThePt(Ⅱ)complexexhibitsthestrongestscavengingefficiency.BothPt(Ⅱ)andPd(Ⅱ)complexeshavetheinhibitoryeffectonlipidperoxides,andtheeffectofthecomplexesisgreaterthanthatoftheligand,butthePt(Ⅱ)complexhasahigheffectofpromotinglipidperoxides.
简介:采用BP神经网络对聚酯玻璃钢氙弧灯加速老化的弯曲寿命进行了预测。通过对聚酯及其玻璃钢的人工氙弧灯加速老化,测试其不同老化时间的弯曲强度,对弯曲强度与老化时间进行BP神经网络的建模分析,借助MATLAB软件对聚酯玻璃钢的使用寿命分别进行分析与预测,并采用最小二乘法对所预测的结果进行了对比。结果表明:在以弯曲强度达到初始强度值的一半作为失效条件下,聚酯的氙灯老化寿命为813d,含填料玻璃钢老化寿命为1031d,无填料玻璃钢老化寿命为1065d,说明BP神经网络可以预测玻璃钢的老化寿命,预测结果与最小二乘法预测结果误差不大于8%,而且预测结果与该材料性能的实际情况相符。
简介:Mg–9Li–3Al–1.6Yalloyswerepreparedthroughmixturemethod.Themicrostructure,mechanicalproperties,andcorrosionresistanceoftheas-castandasextrudedalloyswerestudiedbyopticalmicroscopy(OM),scanningelectronicmicroscopy(SEM),X-raydiffraction(XRD),mechanicalpropertiestesting,andelectrochemicalmeasurement.Theas-castMg–9Li–3Al–1.6Yalloywiththeaveragegrainsizeof325lmiscomposedofb-Limatrix,blocka-Mg,andgranuleAl2Yphases.Afterextrusion,thegrainsizeoftheas-castalloyisobviouslyrefinedandreachesto75lm;thestrengthandelongationoftheextrudedalloyareenhancedby17.20%and49.45%,respectively,owingtotheirfinemicrostructureandreductionofcastingdefects.Theas-extrudedalloyshowsbettercorrosionresistancecomparedtotheas-castone,whichmayberelatedtothelowstoredenergyanddislocationdensityintheextrudedalloy,alsothehomogenizationtreatmentbeforeextrusion.
简介:通过一个简单的水热方法成功地合成出由SnO2纳米片作次级结构的新型花状ZnSnO3-SnO2分级纳米结构。ZnSnO3多面体在生长分级SnO2纳米片的过程中主要起模版作用,制备出的SnO2纳米片的厚度约为25nm。还讨论了ZnSnO3-SnO2样品的形貌随反应时间变化的规律,并且进一步讨论了形成这种分级结构的形成机制。此外,由这种新型ZnSnO3-SnO2纳米结构作敏感材料的气体传感器对乙醇气体具有高灵敏和快响应的特点。ZnSnO3-SnO2纳米片在最佳工作温度270°C时,对50×10-6乙醇气体的灵敏度约为27.8,其响应和恢复时间分别在1s和1.8s内。