简介:WithTi(OBu)4asprecursor,andHAcascomplexingagent,pureandW-dopedTiO2gelatinswerepreparedbyasol-gelmethod.Duringtheprocessofgelformation,metalionsweredispersedintheporousTiO2matrix.Then,powdersofnano-TiO2andW-dopednano-TiO2werepreparedbydrying,grindingandheattreatmentatdifferenttemperatures.Thegrainsizeandstructureofthesamples,pureTiO2andW-doped,andtreatedatdifferenttemperatures,werestudiedbyX-raydiffraction(XRD),BeckmanCoulterSorptionAnalysisandTEM.Resultsshowedthat,withincreasingtemperature,theTiO2transformedfromanatasetorutileandthegrainsizeincreased.ThistransformationandgraingrowthofTiO2couldberetardedbydopingwithW.
简介:部分地,聪明切割的过程,缺陷由尺寸描绘了的结合的效果和在切开前后的内部压力上的2纸被使用破裂力学模型学习。有大尺寸的结合的缺陷是容易的引起缺点生长的严重偏差,这被发现,当切开时,导致薄层的一个非转移的区域。在结合的缺陷的内部压力是很小的一个实际聪明切割的过程,大界面的缺点总是在切开的过程支持缺点生长。同时,增加结合的缺陷的内部压力减少在切开前的缺点生长和它的偏差。stiffener限制的松驰的机制被建议澄清结合的缺陷的效果。而且,当结合的缺陷是在场的时,切开的过程的进步被分析。在切开以后,有大尺寸和高内部的压力的那些结合的缺陷在高温度的退火期间为薄电影的blistering是脆弱的。
简介:Inthisstudy,factorsaffectingthecrystalstructureofflame-synthesizedY2O3:Euparticleswereinves-tigated,especiallytheparticlesizeeffectanditsinteractionwithEudopingconcentration.PolydisperseY2O3:Eu(sizerange200nmto3m)powdersampleswithEudopingconcentrationsfrom2.5mol%to25mol%weregeneratedineitherH2/airorH2/O2substrate-freeflames.ThecrystalstructureofthepowdersampleswasdeterminedbypowderX-raydiffraction(XRD),whichwascomplementedbypho-toluminescence(PL)measurements.Singleparticlecrystalstructurewasdeterminedbysingleparticleselectedareaelectrondiffraction(SAED),andforthefirsttime,byelectronbackscatterdiffraction(EBSD).H2/airflamesresultedincubicphaseY2O3:Euparticleswithhollowmorphologyandirregularshapes.ParticlesfromH2/O2flameshaddenseandsphericalmorphology;sampleswithlowerEudopingconcen-trationshadmixedcubic/monoclinicphases;sampleswiththehighestEudopingconcentrationswerephase-puremonoclinic.ForsamplesgeneratedfromH2/O2flames,aparticlesizeeffectanditsinteractionwithEudopingconcentrationwerefound:particlessmallerthanacriticaldiameterhadthemonoclinicphase,andthiscriticaldiameterincreasedwithincreasingEudopingconcentration.Thesefindingssug-gestthattheformationofmonoclinicY2O3:Euisinevitablewhenextremelyhotsubstrate-freeflamesareused,becausetypicalflame-synthesizedY2O3:Euparticlesizesarewellbelowthecriticaldiameter.However,itmaybepossibletogenerateparticleswithdense,sphericalmorphologyandthedesiredcubicstructurebyusingamoderatelyhighflametemperaturethatenablesfastsinteringwithoutmeltingtheparticles.
简介:针对亚轨道可重复使用运载器(SRLV)的应用需求,在将卫星投送到预定轨道同时确保SRLV安全返回的前提下,对基于记忆原理的轨迹/总体参数一体化优化方法进行了研究。记忆优化算法是一种具有全局收敛性的随机搜索方法,每次搜索的试探解优劣状态由记忆元来存储。利用记忆原理的记忆增强和遗忘规律来衡量优化搜索过程中试探解的状态,并以燃料最省作为优化指标。同时采用三种不同的搜索策略,实现对试探解的随机搜索,避免陷入局部极小问题,并以此来提高搜索速度。仿真表明:卫星入轨速度偏差小于2m/s,高度偏差小于10m,轨道倾角偏差小于0.0001°。SRLV最终与着陆场的位置偏差小于100m,速度偏差小于5m/s。相较于传统的轨迹优化方法,新方法适用于复杂的轨迹/参数一体化优化问题,搜索速度快,求解精度高,有利于算法在工程实际中的应用与推广。
简介:3-DevolutionofKarmanvortexfilamentsandvortexfilamentsinbraidregionsintheturbulentwakeofa2-Dcirculaxcylinderisinvestigatednumeri-callybasedoninviscidvortexdynamicsbyanalyzingtheresponseoftheinitially2-Dspanwisevortexfilamentstoperiodicspanwisedisturbanceofvaryingmagnitude,wavelengthandinitialphaseangles.Ourresultsrevealakindof3-Dvortexsysteminthewakewhichconsistsoflargescalehorseshoe-shapedvorticesandsmallscaleλ-shapedvortexfilamentsaswellasvortexloops.Themechanismandthedynamicprocessaboutthegenerationofstreamwisevorticalstructureandthe3-Dcoherentstructurearereported.
简介:Nanostructuredtransitionmetaloxidesarepromisingalternativeanodesforlithiumionbatteries.Li-ionstorageperformanceisexpectedtoimproveifhighpackingdensityenergyparticlesareavailable.Herein,Mn2O3microsphereswithaca.18μmdiameterandatappeddensityof1.33g/cm3weresynthesizedbyafacilesolvothermal-thermalcoversionroute.SphericalMnCO3precursorswereobtainedthroughsolvothermaltreatmentandtheydecomposedandconvertedintoMn2O3microspheresatanannealingtemperatureof700C.TheMn2O3microspheresconsistedofMn2O3nanoparticleswithanaverage40nmdiameter.TheseporousMn2O3microspheresallowgoodelectrolytepenetrationandprovideanionbufferreservoirtoensureaconstantelectrolytesupply.TheMn2O3microsphereshavereversiblecapacitiesof590and320mAh/gat50and400mA/g,respectively.Wethusreportanefficientrouteforthefabricationofenergyparticlesforadvancedenergystorage.
简介:TiO2-loadedactivatedcarbonfibers(ACF)werepreparedbyahydrothermalmethod.Thesampleswerecharacterizedbyscanningelectronmicroscopy(SEM),X-raydiffraction(XRD),Fouriertransforminfrared(FT1R)spectrometryandUV-visdiffusereflectancespectra(DRS).SEMimagesshowedthattheTiO2nanoparticlesweredepositedonthesurfaceofACF,andtheparticlesizeandloadingamountofTiO2werevariedbychangingtheinitialconcentrationoftetrabutyltitanate(TBOT).TheresultsofanashexperimentshowedthattheloadingamountsofTiO2were18.4%,43.3%,52.5%,75.1%,and91.1%forinitialconcentrationsofTBOTof0.07,014,0.21,0.28,and0.35mol/L,respectively.PhysicalinteractionsplayedanimportantroleintheformationofTiO2/ACFcompositefibersthatabsorbUVandvisiblelight.ComparedwiththoseofACF,improvedadsorptionandphotocatalyticactivitytowardRhodamineB(RhB)wereobservedforTiO2/ACFcompositefiber.TheRhodamineBcouldberemovedefficientlybyTiO2/ACFcompositefibers,andtheTiO2loadingamounthadasignificanteffectonthephotocatalyticactivityofTiO2/ACFcompositefibers.
简介:Fortwo-dimensionnonlinearconvectiondiffusionequation,atwo-gridmethodofcharacteristicsfinite-elementsolutionwasconstructed.Inthismethodthenonlineariterationsisonlytoexecuteonthecoarsegridandthefine-gridsolutioncanbeobtainedinasinglelinearstep.Forthenonlinearconvection-dominateddiffusionequation,thismethodcannotonlystabilizethenumericaloscillationbutalsoacceleratetheconvergenceandimprovethecomputationalefficiency.Theerroranalysisdemonstratesifthemeshsizesbetweencoarse-gridandfine-gridsatisfythecertainrelationship,thetwo-gridsolutionandthecharacteristicsfinite-elementsolutionhavethesameorderofaccuracy.Thenumericalexampleconfirmsthatthetwo-gridmethodismoreefficientthanthatofcharacteristicsfinite-elementmethod.
简介:Aself-adaptiveprecisealgorithminthetimedomainwasemployedtosolve2-Dnonlinearcoupledheatandmoisturetransferproblems.Byexpandingvariablesatadiscretizedtimeinterval,thevariationsofvariablescanbedescribedmoreprecisely,andanonlinearcoupledinitialandboundaryvalueproblemwasconvertedintoaseriesofrecurrentlinearboundaryvalueproblemswhicharesolvedbyFEtechnique.Inthecomputation,noadditionalassumptionandthenonlineariterationarerequired,andacriterionforself-adaptivecomputationisproposedtomaintainsufficientcomputingaccuracyforthechangesizesoftimesteps.Inthenumericalcomparison,thevariationsofmaterialpropertieswithtemperature,moisturecontent,andbothtemperatureandmoisturecontentaretakenintoaccount,respectively.Satisfactoryresultshavebeenobtained,indicatingthattheproposedapproachiscapableofdealingwithcomplexnonlinearproblems.
简介:Carbonnanotube(CNTs)/Fe-Ni/TiO2nanocompositephotocatalystshavebeensynthesizedbyaninsitufluidizedbedchemicalvapordeposition(FBCVD)method.ThecompositephotocatalystswerecharacterizedbyXRD,Ramanspectroscopy,BET,FESEM,TEM,UV-visspectroscopy,andXPS.TheresultsshowedthattheCNTsweregrowninsituonthesurfaceofTiO2.Fe(lll)inTiO2showednochemicalchangesinthegrowthofCNTs.Ni(Ⅱ)waspartlyreducedtometalNiintheFBCVDprocess,andthemetalNiactedasacatalystforthegrowthofCNTs.ThephotocatalyticactivitiesofCNTs/Fe-Ni/TiO2decreasedwiththeriseoftheFBCVDreactiontemperature.ForthesamplesynthesizedatlowFBCVDtemperature(500℃),morethan90%andnearly50%ofmethylenebluewereremovedunderUVirradiationin180minandundervisiblelightirradiationin300min,respectively.TheprobablemechanismofsynergisticenhancementofphotocatalysisontheCNTs/Fe-Ni/TiO2nanocompositeisproposed.
简介:AlaminarpremixedPropane/Airflamewithafuelequivalenceratioof2.1wasemployedforanalysisofsootparticles.Zeroth-orderIognormaldistributions(ZOLD)wereusedintheanalysisofexperimentaldistributionphenomenaatdifferentresidencetimesduringsootformationintheflame.Rayleigh'stheoryandMie'sscatteringtheorywerecombinedwithagglomerateanalysisusingscatteringandextinctiondatatodeterminethefollowingsootcharacteristics:agglomerateparameters,volumetricfractions,massflowratesandsurfacegrowthrate.Sootdensitymeasurementswerecarriedouttodeterminedensityvariationsatdifferentstagesofgrowth.Themeasuredresultsshowthatmetricfractionandmassflowrateindicatethatthesurfacegrowthrateofsootparticlesexceedstheoxidationratesintheflamestudied.Thedataobtainedinthisworkwouldbeusedtostudysootoxidationrateunderflamingcondition.