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172 个结果
  • 简介:Withcoalgasasareducingagent,thecatalyticreductionofSO2tosulfurinthefluegasproducedinmetallurgicalprocesseswasstudiedovercatalystsofrareearth-Fe/Al2O3(REFe/Al2O3).ThecatalyticactivityoftheREFe/Al2O3catalystonthereductionofSO2tosul-furwasinvestigatedbasedonkindsandthecontentsofrareearthsanddifferentpreparationmethodofthecatalyst.Additionally,themecha-nismofthiscatalyticreductionreactionwasalsoexplored.ResultsshowedthatdifferentrareearthimposeddifferenteffectontheactivityoftheFe/Al2O3catalyst.Especially,theadditionofSmandDygreatlyimprovedthecatalyticactivityofFe/Al2O3.TheyieldofsulfuroverSmFe/Al2O3wasincreasedto86.62%at360℃,whichwas40.5%higherthanthatoverFe/Al2O3atthesametemperature;andthesulfuryieldoverDyFe/Al2O3wasincreasedto91.62%at400℃,26.4%higherthanthatoverFe/Al2O3.ThecatalyticactivityofREFe/Al2O3wassomehowdependentonthecontentofrareearth.ForSmFe/Al2O3,thecontentofSmwasoptimizedtobeabout1.0wt.%.Therareearthcatalystpreparedwithdifferentmethodsalsoshowedvariedactivity.Thesulfuryieldoverrare-earthtransitionmetalcatalystsfollowstheorder:SmandironsolutionmixingimpregnationSmfirst,thenironsolutionimpregnationironfirst,thenSmsolutionimpregnation.ThereactionmechanismofSO2reductiontosulfurwithcoalgaswasproposedtobeanintermediatemechanism.

  • 标签: SULFUR dioxide CATALYTIC REDUCTION SULFUR FLUE
  • 简介:介绍了利用可编程控制器和计算机技术对大功率SO2风机控制系统的改造,内容包括控制方案、系统软件方案、系统功能以及问题和对策.

  • 标签: SO2风机 PLC 工控机 触摸屏 PROFIBUS-DP MPI
  • 简介:针对方大特钢公司60Si2Mn弹簧扁钢产品出现剪切端面裂纹问题,进行裂纹检测、剪切温度试验和不同温度下力学性能检测;分析发现剪切时的温度对裂纹产生的影响,发现剪切裂纹是剪切应力作用于偏析较严重部位形成的裂纹源在残余应力释放过程中扩展形成的横向裂纹.根据分析结果,在生产实践中分别对炼钢、轧制工序采取相应措施,有效控制了弹簧扁钢的剪切端面裂纹.

  • 标签: 弹簧扁钢 裂纹 剪切温度 偏析 原因分析
  • 简介:TheNd3+3.2%(atomfraction):KGd(WO4)2crystalwasgrownbyKyropoulosmethod.TheabsorptionspectrumandfluorescencespectrumofNd3+:KGWcrystalweremeasured.Theabsorptioncrosssectionsat808nm(0.6799×10-20cm2)werecalculated,andtheoutputwavelengthoffluorescenceis1064and1351nm.Thediode-pumpedlaserwasoperatedbothinthefree-runningandpassivelyQ-switchedoperatingmodes.Themaximumlaseroutput(1064nm)is326mWwith62.7%slopeefficiencywheninputenergyis900mW.ThebeamqualityfactorM2≈1.1.Thegreenlightof532nmisobtainedinfrequencydoublingoperation.ThelaserispassivelyQ-switchedbyusingCr4+:LuAGassaturableabsorber.Thepulsewidthis170nsatrepetitivefrequencyof15kHZ.

  • 标签: Nd : KGW晶体 晶体生长 LD泵浦 激光材料
  • 简介:本文主要进行了二价铜在溶液中用亚硫酸根将其还原成一价铜,并用氯离子作为沉淀剂制取氯化亚铜的研究。氯化亚铜生成过程中会产生H+,反应体系pH对氯化亚铜产品收率影响最大,所以过程中可通过滴加碳酸钠来控制体系酸度,并根据还原反应发生的速度控制碳酸钠的滴加速度来中和体系中的生成的酸,保持体系pH在2.0~3.0,使氯化亚铜产率达到92%以上。

  • 标签: 亚硫酸钠 硫酸铜 氯化亚铜 还原法
  • 简介:Inaflowinjectionseparationandpreconcentrationsystemincorporatingamicrocolumn,theadsorptionbehavior(effectofpH,kineticadsorptioncapacity)ofmetalionsCu^2+,Cr^3+,Mn^2+,Ni^2+,La^3+,Eu^3+,Ga^3+,Mo(Ⅵ)andW(Ⅵ)onTiO2owderwithdifferentcrystalstructureandparticlediameterwasstudiedandcompared.Inaddition,theechanismoftheadsorptionofmetalionsonTiO2owderwasexplored.TheresultsshowthatcrystaltructureandparticlediameteroftheTi02powderwillefinitelyaffecttheadsorptioncapacityofmetalsont.

  • 标签: 二氧化钛粉末 吸收性质 金属离子 晶体结构 颗粒直径 稀土元素
  • 简介:TheNaGd(WO_4)_2:Eu~(3+)phosphorswerepreparedbythemicroemulsionmediatedhydrothermalmethod.ThemorphologyandsizeofthesamplescouldbedependentonthepHintheinitialsolution.Thesephosphorsobtainedhadastrongabsorptionat395nmmatchingwiththepopularemissionofnear-UVLEDchips,andcouldemitintenseredlightat616nm.Thesmallellipsoid-likeparticlesorshortrodswereprovidedwithlargeparametersofoscillatorstrength?_2andasymmetryratio.Comparedtotheellipsoid-likephosphors,therod-likephosphorstookonstrongeremission,longerlifetimeandlargerquantumefficiency.Thisworkdemonstratedthattheone-dimensionNaGd(WO_4)_2:Eu~(3+)phosphorsmightbeamorefavorabledevicethanzero-dimensiononesforphotoluminescence.

  • 标签: MICROEMULSION hydrothermal oscillator matching LIFETIME sizes
  • 简介:StudyontheEasyDirectionofMagnetizationofSm0.88Dy0.12FeAlloyZhuMingyuan(朱明源),ZhangHuiyou(张慧友),ZhuYuliang(诸于良)JinHongmin?..

  • 标签: Sm0. 88Dy0. 12Fe2 ALLOY EASY direction
  • 简介:ThispaperistodiscussthesensingcharacteristicsofSnO2semiconductorcomponentsinwhichPr6O11isadded.Whenexperimentingunder11gasesofCH3COCH3,C2H5OH.C6H5CH3,H2,NH3,CO,CO2CH4,C4H10,n—C6H14andn—C7H16,wefindthatthecomponentshaveselectivitytoCH3COCH3,C2H5OHandthattheidealamountofPr6O11inthecomponentsisaboutI.Owt%.TheexperimentsalsoshowthatwiththeincreaseoftheamountofPr6O11,theidealworkingtemperature,theresponseandrestorationtimedecrease.

  • 标签: gases SELECTIVITY restoration MONOXIDE methane AMMONIA
  • 简介:主要采用金相及SEM分析方法,对20Cr2Ni4A锻圆表面裂纹性质及产生原因进行了分析,结果表明锻圆表面裂纹是由于原材料存在表面夹杂/渣引起的。

  • 标签: 钢锭 锻造 纵向裂纹
  • 简介:钕铁硼系磁体的推出,使Sm_2Co_(17)磁体的市场规模大大减少。最近日本信越化学工业公司的研究表明,该磁体可以暴露于200℃以上的高温下,还可在氢气等特殊环境下使用。钕系列磁体用于大功率马达的情况下,由于周围环境及焦耳热使温度升高,产生的

  • 标签: 快淬 日本快 法生产
  • 简介:通过研究烧结过程中发生的传质传热反应,对烧结过程进行了合理的假设,建立了主要反应动力学模型。应用Fluent流体计算软件,将动力学模型与Fluent计算软件通过UDF系统结合,建立了烧结反应模型。在不同气氛的条件下进行了烧结模拟实验,即,对二氧化硫的排放规律进行了研究,得到了入口空气中H2O与O2的含量与烟气中SO2含量分布之间的关系。

  • 标签: 烧结 SO2 烟气排放 烧结过程 模拟