简介:Twoseriesofmixedoxides,CoAlMandMgAlM(M=Cr,Mn,Fe,Co,Ni,Cu),werepreparedbycalciningtheircorrespondinghydrotalcite-likecompounds(HTLc).TheratioofMg:Al:M(orCo:Al:M)was3:1:1.ThecatalyticactivityofallsamplesforthereactionofNO+COwasinvestigated.TheresultsshowedthattheactivityofCoAlMwasmuchhigherthanthatofMgAlM.ThestructureandthepropertyofredoxwerecharacterizedbyXRDandH2-TPR.TheresultsindicatedthatonlyMgOphasewasobservedaftercalciningMgAlMhydrotalcites,andthetransitionmetalsbecamemorestable.Thespinel-likephaseappearedinallofCoAlMsamplesafterthecalcination,andthetransitionmetalswerechangedtobemoreactive,andeasilyreduced.TheactivitiesofthreeseriesofmixedoxidesCoAlCuobtainedfromdifferentpreparationmethods,differentratioofCo:Al:Cuandatdifferentcalcinationtemperatures,werestudiedindetailforproposingthemechanismofreaction.TheabilityofadsorptionofNOandCO
简介:TheCurietemperatureof(Nd1-xPrx)2Fe14CoyBcompounds(x=0,0.2,…,1.0andy=O,2,4,6,14)hasbeendeterminedwithACinitialsusceptibilitymeasurement.ItwasfoundthatthevariationsofCurietempera-turewithxisnotlinearfory=0and14,whereasitislinearforothervaluesofy.Thelatticeconstantsof(Nd1-xPrx)2Fet14BweredeterminedbyusingX-raydiffraction.Thelatticeexpansionwasmostlyalongthecaxis,whereasthatalongthea-axisremainedpracticallyzeroforthewholeseries.ItissuggestedthatPratomsmayshowsitepreferenceinR2M14Bcompounds(M=FeorCo).DuetothesubstitutionofCoforFe.thetendencyofsitepreferenceofPrbecomeslesspronounced,whichmaybeattributedtothedecreaseofdiffer-enceofcrystalelectricfield(CEF)actingonthetworareearthsiteswiththeintroductionofCoorFe.Incon-trasttothatofthePratoms,thesitepreferenceofCoiu(Nd(1-x)Prx)2Fe(14-y)CoyBcompoundsdoesnotdependonthecompositionoftherareearthsublattice(R=NdorPr).
简介:COandformaldehyde(HCHO)oxidationreactionswereinvestigatedovermesoporousAg/Co3O4catalystspreparedbyone-pot(OP)andimpregnation(IM)methods.Itwasfoundthattheone-potmethodwassuperiortotheimpregnationmethodforsynthesizingAg/Co3O4catalystswithhighactivityforbothreactions.ItwasalsofoundthatthecatalyticbehaviorofmesoporousCo3O4andAg/Co3O4catalystsforthebothreactionswasdifferent.AndtheadditionofsilveronmesoporousCo3O4didnotalwaysenhancethecatalyticactivityoffinalcatalystforCOoxidationatroomtemperature(20C),butcouldsignificantlyimprovethecatalyticactivityoffinalcatalystforHCHOoxidationatlowtemperature(90C).Thehighsurfacearea,uniformporestructureandtheprettygooddispersiondegreeofthesilverparticleshouldberesponsiblefortheexcellentlow-temperatureCOoxidationactivity.However,forHCHOoxidation,theadditionofsilverplayedanimportantroleintheactivityenhancement.AndthesilverparticlesizeandthereducibilityofCo3O4shouldbeindispensableforthehighactivityofHCHOoxidationatlowtemperature.
简介:FormerlyNo.713Factory,HuaxingMetallur-gical&ChemicalCo.underChinaNuclearIndustryGeneralCorporationwasestablishedin1958andputintooperationin1962.ThecorporationislocatedinShangrao,JiangxiProvinceandwasoriginallydesignedtoproducerawmaterialsformillitaryuse.Inkeepingupwiththepaceofthedevelopmentofthenationaleconomy,
简介:Dopantsanddefectsareimportantinsemiconductorandmagneticdevices.Strategiesforcontrollingdopinganddefectshavebeenthefocusofsemiconductorphysicsresearchduringthepastdecadesandremaincriticaleventoday.Co-dopingisapromisingstrategythatcanbeusedforeffectivelytuningthedopantpopulations,electronicproperties,andmagneticproperties.Itcanenhancethesolubilityofdopantsandimprovethestabilityofdesireddefects.Duringthepast20years,significantexperimentalandtheoreticaleffortshavebeendevotedtostudyingthecharacteristicsofco-doping.Inthisarticle,wefirstreviewthehistoricaldevelopmentofco-doping.Then,wereviewavarietyofresearchperformedonco-doping,basedonthecompensatingnatureofco-dopants.Finally,wereviewtheeffectsofcontaminationandsurfactantsthatcanexplainthegeneralmechanismsofco-doping.
简介:摘要:随着绿建工程的不断普及,绿色工程的验收标准也有了新的定义,即:在全寿命期内、节约资源、保护环境、减少污染,为人们提供健康、适用、高效的使用空间,最大限度地实现人与自然和谐共生的高质量建筑。
简介:Amethodbasedupontheweightedtotalcrosssection(WTCS)theoryisproposedtocalculatethephoto-ionisationcrosssectionsandtheradiativerecombinationratecoefficientsbetweenthefundamentallevelofCOandthemainelectronicstatesofitscorrespondingion.Totalphoto-ionisationcrosssectionsandradiativerecombinationratecoefficientsaredeterminedfromthecalculationofelementaryvibrationalphoto-ionisationcrosssections.TransitionsbetweenCO~+(X,AandB)andCO(X)areconsidered.Totalphoto-ionisationcrosssectionsandrecombinationcoefficientsarecomputedinthetemperatureinterval500-15000K.
简介:Byemployingaradiofrequency(RF)feedbackchain,theself-interferencecanbecanceledefficientlyinco-timeco-frequencyfullduplex(CCFD).However,theevitablesignalcrosstalkwhichiscausedbytheimperfectRFfeedbackchainisolationusuallydamagestheself-interferencecancelation(SIC)performance.Todealwiththisproblem,firstly,weanalyzetheimpactofRFfeedbackchainisolationonSICperformance.ThenadigitalpreprocessingschemewithRFfeedbackchainisproposedinthemultiple-antennaCCFDarchitecture.Usingbothanalyticalandexperimentalmethods,wefindthattheproposedschemeachievesabetterperformanceonSIC.
简介:利用methoxysilyl一半的水解作用和冷凝作用,器官无机的混血儿(N-isopropylacrylamide-co-acrylamide-co-3-(trimethoxysilyl)propylmethacrylate)poly,P(NIPAM-co-AM-co-TMSPMA)microgels经由二个不同方法被准备。第一个方法是microgels是从crosslinkable的fabricated以后线性P(NIPAM-co-AM-co-TMSPMA)terpolymer在terpolymer的更低的批评答案温度(LCST)上面的水的答案。为第二个方法,microgels被常规表面活化剂直接综合NIPAM,AM,和TMSPMA的免费乳剂copolymerization。结果的P(NIPAM-co-AM-co-TMSPMA)microgels的水动力学直径和稳定性强烈取决于microgel的pH和温度水的答案。microgels的水动力学直径与增加测量温度减少了。microgels的阶段转变温度被发现在34附近吗??
简介:Dynamicnodecreationandfastlearningalgorithmforahybridfeedforwardneuralnetwork.Flight-pathanglecontrolvianeuro-adaptiveBackstepping.Locallearningframeworkforhandwrittencharacterrecognition.Maximizingmarginsofmultilayerneuralnetworks.ModularnetworkSOMself-orgmlizingmapofasystemsgroupinfunctionspace.