简介:Bydepositingdiamondlikecarbon(DLC)filmwithradiofrequencyplasmachemicalvapordeposition(RFPCVD)method,anewsurfacepassivationtechniqueforphotoluminescenceporoussilicon(PS)hasbeenstudied.ThesurfacemicrostructureandphotoelectricpropertiesofbothporoussiliconandDLCcoatedPShavebeenanalyzedbyusingAFM,FTIRandPLspectrometers.TheresultsshowtheDLCfilmwithdenseandhomogenousnanometergrainscanbedepositedonthePSusedaspassivationcoatingasitcanterminateoxidereactiononthesurfaceofthePS.Furthermore,certainratioofhydrogenexistedintheDLCfilmcanbeimprovedtoformhydridespeciesontheDLC/PSinterfaceasthecentersoftheluminescencesothattheDLCcoatingisofbenefitnotonlytothepassivationofthePSbutalsototheimprovementofitsluminescentintensity.
简介:Rod-likegoldnanoparticlescanbeformedfromHAuCl4aqueoussolutionwithultraviolet(UV)irradiationintheabsenceoftemplates,avoidingpossiblepoisonoussurfactantembeddedintothesurfaceoffunctionalgoldnanoparticlesappliedinbiomedicine.Theaspectratioofnanorodsrangesfrom1.1to4.4withtheconcentrationofHAuCl40.2mM,whichcanbeverifiedbyHRTEMimagesandtheabsorptionspectrum.Itisfoundthatthenanoclusterwithseveralatomsoccurspriortotheformationofnanorods,highlycorrespondingtoitstypicalabsorptionspectrum.TracingtheevolutioninabsorptionspectraofHAuCl4aqueoussolution,itcanbeconcludedthattheformationmechanismofgoldnanoparticlesinthisprocessisdifferentfromthatintheconventionalinductivegrowthmodel,possiblyinagrowthpatternwithimperfectorientedattachment(IOA)relevanttothecolliding-and-growing.