简介:Thelayer-by-layercomplexationtechniqueofpolymerandmetalionwassuccessfullyutilizedtofabricatetheuhrathinmuhilayerfilmofpoly(3-thiopheneaceticacid(PTAA)andTb^3+ionbydippingthesubstratesalternativelyinpolymerandTb^3+ionaqueoussolutions.UV-vismeasurementrevealedthattheabsorbancehaslinearitywiththebilayernumberfromlayertolayerandtheX-rayphotoelectronspectrum(XPS)confirmedtheexistenceofTb^3+ion.ThepHofboththepolymerandTbCl3solutionsinfluencethethicknessdramaticallywhiletheconcentrationofthesolutionsisnotsosensitive.TheluminescentspectrumofthecomplexfilmshowsthecharacteristicemissionofTb^3+ionaswellastheligandindicatingtheformationofthecomplex.
简介:Eu2+andDy3+codoped(Ca,Sr)7(SiO3)6Cl2yellowphosphorsweresuccessfullysynthesizedbyself-fluxmethod.Thestructure,morphologyandphotoluminescencepropertieswereinvestigatedbyX-raydiffraction(XRD),scanningelectronmicroscopy(SEM)andphotoluminescencespectra.Theas-preparedphosphorshowedabroademissionspectrumcenteredat550nmforEu2+single-dopedphosphor,whilelocatedat548–544nmfortheEu2+,Dy3+codopedsamplesunderexcitationat380nmlight.TheemissionintensitywasgreatlyimprovedwhenDy3+wasdopedintothe(Ca,Sr)7(SiO3)6Cl2:Eu2+system.Thecomposition-optimizedsamplewith3mol.%ofDy3+andconstant10mol.%ofEu2+exhibiteda220%PLenhancementcomparedtothephosphorwith10mol.%Eu2+single-doped.Meanwhile,itwasfoundthatthequantumefficiencyofphosphornamely(Ca,Sr)7(SiO3)6Cl2:3mol.%Dy3+,10mol.%Eu2+couldgetupto24.6%.Thesynthesizedyellow-emitting(Ca,Sr)7(SiO3)6Cl2:Dy3+,Eu2+isapromisingcandidateashigh-efficiencyyellowphosphorforNUV-excitedwhiteLEDs.
简介:ThesurfaceofacommercialY3Al5O12:Ce3+phosphorwasmodifiedby99%NH4F+CH3COOHsolutioninasupersonicbathwithwatertemperatureof80oCfor4h.Thescanningelectronmicroscopy(SEM)resultsshowedthattheedgeangleswerenotassharpastheunmodifiedparticlesandtheflatsurfacesturnedroughwithmanymicro-structurescovered.Positronlifetimemeasurementsquantitativelyshowedthatsurfacedefectswereremovedawaybymorethan50%.Asaresult,thephotoluminescencedeterminationsshowedthatthebackscatterlosswasreducedby4.2%andtheemissionpowerwasenhancedby5.6%afterthesurfacemodification.Theconversionefficiencywasgreatlyimprovedfrom47.3%to51.1%,aspresentedbythefluorescenceimages.Therefore,itwouldbegreatlyhelpfulfortheimprovementofefficiency,transparencyandstabilityofpc-LED.Moreover,thismethodwassignificantlysuitableformassproductionduetoitseasyoperationandlowcost.
简介:AdetailedstudyofthefluorescenceemissionpropertiesandenergytransfermechanisminEr3+/Tm3+co-dopedleadsilicateglasseswasreported.Enhancednearinfrared1.8μmandvisibleup-conversionemissionswereinvestigatedunder808and980nmexcitations,respectively.TheenergytransfermechanismbetweenEr3+andTm3+wasanalyzedaccordingtotheabsorptionspectra,theemissionspectraandthelevelstructuresofEr3+andTm3+.TheenergytransferefficiencybetweenEr3+andTm3+reached68.1%intheEr3+/Tm3+co-dopedleadsilicateglasseswhenpumpedby808nmlaserdiode.Basedontheabsorptionspectra,theJudd-Ofeltparameters,spontaneousemissionprobability,absorptionandemissioncrosssections,gaincoefficientswerecalculatedandanalyzed.Itwasfoundthatthecalculatedemissioncrosssectionandthemaximumgaincoefficientaround1.8μmwere4.9×10–21cm2and1.12cm–1,respectively.TheseresultsindicatedthattheEr3+/Tm3+co-dopedlead-silicateglasseshadpotentialapplicationinnearinfraredlasers.
简介:结合实例,分析数控车削加工中的基本工艺、机床坐标系和工件坐标系的建立问题;针对FANUC0i系统数控车床的对刀法,阐述了多把刀具的对刀步骤;并对零件进行了手动程序编制.
简介:Thesinglecrystalofthecomplex[Sc(NO3)3(H2O)2]·(15C5)hasbeenpreparedinacetonitrile.Thenewcomplexhasbeencharacterizedbyelementalanalysis,IRspectra,solubilityandmolarconductancemeasurements.ThestructureofthecomplexisdeterminedbysinglecrystalX-raydiffractionanalysis.
简介:(Ba0.66Sr0.33)Mg0.8Al11.47O19:Tm0.013+(BSMA:Tm3+)phosphorwassynthesizedbysolid-statereactions.ThesamplewascharacterizedbyX-raydiffraction(XRD),scanningelectronicmicroscope(SEM),vacuumultraviolet(VUV)spectra,ultraviolet(UV)spectraandFT-IRspectrum.XRDpatternrevealsthatBSMA:Tm3+hasthesamestructureasBaAl12O19phase.SEMimageillustratesthatthephosphorhasthehexagonalshapeanddeepslicestructure.VUVandUVemissionspectraat20,50and100Kshowthatthelowtemperatureluminescenceintensitiesbecomeweakgraduallywiththeincreasingofthetemperatureunder147and254nmexcitation.Thestrongbroadbandpeaksataround357and397nmandthepeakat516nmunder147nmexcitationallcorrespondtothecharacteristictransitionsofTm3+ions.However,underUV(254nm)excitation,themainpeakbecomes530nmwhichhasveryhighlineintensity,andthepeaksatabout362and403nmareveryweak.Theexcitationspectrumat20Kshowsthattherearethreeabsorptionpeaksataround153,186and193nmwhen516nmemissionismonitored.Theabsorptionpeaksof[AlO4],[AlO6]andAl-OcanbeobservedinFT-IRspectrum.
简介:SphericalYAG:Ce3+phosphorparticleswithnarrowsizedistributionwerepreparedbyspraypyrolysis.Theeffectsoftheconcentrationofsolution,theflowrateofcarriergasandtheannealingtemperatureonthephosphormorphologywerestudied.Theproductivityofprecursorparticlesshowsatrendofdropafterrisingwiththeincreaseofconcentration.Raisingtheflowrateofnitrogencanimprovetheproductivityoftheprecursorparticles.Phosphorpreparedbyspraypyrolysishasobviouslyhigheremissionintensitythanthatsynthesizedbysolidstatereaction,spraypyrolysismakesCe3+ionswelldistributedinthecrystallatticeastheluminescentcenters,andphosphorparticleshaveregularsphericityandnarrowsizedistribution.