学科分类
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195 个结果
  • 简介:Thelayer-by-layercomplexationtechniqueofpolymerandmetalionwassuccessfullyutilizedtofabricatetheuhrathinmuhilayerfilmofpoly(3-thiopheneaceticacid(PTAA)andTb^3+ionbydippingthesubstratesalternativelyinpolymerandTb^3+ionaqueoussolutions.UV-vismeasurementrevealedthattheabsorbancehaslinearitywiththebilayernumberfromlayertolayerandtheX-rayphotoelectronspectrum(XPS)confirmedtheexistenceofTb^3+ion.ThepHofboththepolymerandTbCl3solutionsinfluencethethicknessdramaticallywhiletheconcentrationofthesolutionsisnotsosensitive.TheluminescentspectrumofthecomplexfilmshowsthecharacteristicemissionofTb^3+ionaswellastheligandindicatingtheformationofthecomplex.

  • 标签: 光致发光 稀土 自组装薄膜 多层膜 UV-VIS
  • 简介:Eu2+andDy3+codoped(Ca,Sr)7(SiO3)6Cl2yellowphosphorsweresuccessfullysynthesizedbyself-fluxmethod.Thestructure,morphologyandphotoluminescencepropertieswereinvestigatedbyX-raydiffraction(XRD),scanningelectronmicroscopy(SEM)andphotoluminescencespectra.Theas-preparedphosphorshowedabroademissionspectrumcenteredat550nmforEu2+single-dopedphosphor,whilelocatedat548–544nmfortheEu2+,Dy3+codopedsamplesunderexcitationat380nmlight.TheemissionintensitywasgreatlyimprovedwhenDy3+wasdopedintothe(Ca,Sr)7(SiO3)6Cl2:Eu2+system.Thecomposition-optimizedsamplewith3mol.%ofDy3+andconstant10mol.%ofEu2+exhibiteda220%PLenhancementcomparedtothephosphorwith10mol.%Eu2+single-doped.Meanwhile,itwasfoundthatthequantumefficiencyofphosphornamely(Ca,Sr)7(SiO3)6Cl2:3mol.%Dy3+,10mol.%Eu2+couldgetupto24.6%.Thesynthesizedyellow-emitting(Ca,Sr)7(SiO3)6Cl2:Dy3+,Eu2+isapromisingcandidateashigh-efficiencyyellowphosphorforNUV-excitedwhiteLEDs.

  • 标签: 镝掺杂 荧光粉 黄色 扫描电子显微镜
  • 简介:通过加强进厂原燃料管理、强化炉前出铁管理、实施大富氧率喷吹技术和优化高炉基本操作制度,太钢4350m^3高炉的燃料比降到500kg/t以下,利用系数达到了2.4t/m^3·以上,实现了高炉稳定、均衡和高效生产。

  • 标签: 高炉 燃料比 操作制度 高效化
  • 简介:太钢1350m3高炉在炉体破损严重的情况下,对高炉进行了大检修,并采取一系列强化冶炼的措施,收到良好效果.

  • 标签: 高炉 强化冶炼 炼铁
  • 简介:丹麦议会于6月27日投票通过了该圉的新能源协议,决定到2030年再新建三座海上风电场,总容最至少为240万千瓦。协议还提出了丹麦新的能源发展目标,要求到2030年,可再生能源占能源消耗总量的55%。

  • 标签: 海上风电场 丹麦 可再生能源 能源消耗 新能源 协议
  • 简介:分析了3S技术的特点,考虑矿区的具体情况和要求,探讨了3S技术应用于矿区工程的可行性和应用目标.

  • 标签: 3S技术 矿山 应用目标
  • 简介:ThesurfaceofacommercialY3Al5O12:Ce3+phosphorwasmodifiedby99%NH4F+CH3COOHsolutioninasupersonicbathwithwatertemperatureof80oCfor4h.Thescanningelectronmicroscopy(SEM)resultsshowedthattheedgeangleswerenotassharpastheunmodifiedparticlesandtheflatsurfacesturnedroughwithmanymicro-structurescovered.Positronlifetimemeasurementsquantitativelyshowedthatsurfacedefectswereremovedawaybymorethan50%.Asaresult,thephotoluminescencedeterminationsshowedthatthebackscatterlosswasreducedby4.2%andtheemissionpowerwasenhancedby5.6%afterthesurfacemodification.Theconversionefficiencywasgreatlyimprovedfrom47.3%to51.1%,aspresentedbythefluorescenceimages.Therefore,itwouldbegreatlyhelpfulfortheimprovementofefficiency,transparencyandstabilityofpc-LED.Moreover,thismethodwassignificantlysuitableformassproductionduetoitseasyoperationandlowcost.

  • 标签: 表面特征 表面缺陷 溶胶-凝胶法 荧光粉 选择性腐蚀 CE
  • 简介:AdetailedstudyofthefluorescenceemissionpropertiesandenergytransfermechanisminEr3+/Tm3+co-dopedleadsilicateglasseswasreported.Enhancednearinfrared1.8μmandvisibleup-conversionemissionswereinvestigatedunder808and980nmexcitations,respectively.TheenergytransfermechanismbetweenEr3+andTm3+wasanalyzedaccordingtotheabsorptionspectra,theemissionspectraandthelevelstructuresofEr3+andTm3+.TheenergytransferefficiencybetweenEr3+andTm3+reached68.1%intheEr3+/Tm3+co-dopedleadsilicateglasseswhenpumpedby808nmlaserdiode.Basedontheabsorptionspectra,theJudd-Ofeltparameters,spontaneousemissionprobability,absorptionandemissioncrosssections,gaincoefficientswerecalculatedandanalyzed.Itwasfoundthatthecalculatedemissioncrosssectionandthemaximumgaincoefficientaround1.8μmwere4.9×10–21cm2and1.12cm–1,respectively.TheseresultsindicatedthattheEr3+/Tm3+co-dopedlead-silicateglasseshadpotentialapplicationinnearinfraredlasers.

  • 标签: 硅酸铅玻璃 近红外激光 发射特性 激发条件 共掺杂 TM
  • 简介:结合实例,分析数控车削加工中的基本工艺、机床坐标系和工件坐标系的建立问题;针对FANUC0i系统数控车床的对刀法,阐述了多把刀具的对刀步骤;并对零件进行了手动程序编制.

  • 标签: FANUC0i数控系统 试切法 对刀 手动编程
  • 简介:Thesinglecrystalofthecomplex[Sc(NO33(H2O)2]·(15C5)hasbeenpreparedinacetonitrile.Thenewcomplexhasbeencharacterizedbyelementalanalysis,IRspectra,solubilityandmolarconductancemeasurements.ThestructureofthecomplexisdeterminedbysinglecrystalX-raydiffractionanalysis.

  • 标签: solubility acetonitrile Crown molar H2O NO3
  • 简介:(Ba0.66Sr0.33)Mg0.8Al11.47O19:Tm0.013+(BSMA:Tm3+)phosphorwassynthesizedbysolid-statereactions.ThesamplewascharacterizedbyX-raydiffraction(XRD),scanningelectronicmicroscope(SEM),vacuumultraviolet(VUV)spectra,ultraviolet(UV)spectraandFT-IRspectrum.XRDpatternrevealsthatBSMA:Tm3+hasthesamestructureasBaAl12O19phase.SEMimageillustratesthatthephosphorhasthehexagonalshapeanddeepslicestructure.VUVandUVemissionspectraat20,50and100Kshowthatthelowtemperatureluminescenceintensitiesbecomeweakgraduallywiththeincreasingofthetemperatureunder147and254nmexcitation.Thestrongbroadbandpeaksataround357and397nmandthepeakat516nmunder147nmexcitationallcorrespondtothecharacteristictransitionsofTm3+ions.However,underUV(254nm)excitation,themainpeakbecomes530nmwhichhasveryhighlineintensity,andthepeaksatabout362and403nmareveryweak.Theexcitationspectrumat20Kshowsthattherearethreeabsorptionpeaksataround153,186and193nmwhen516nmemissionismonitored.Theabsorptionpeaksof[AlO4],[AlO6]andAl-OcanbeobservedinFT-IRspectrum.

  • 标签: VACUUM ULTRAVIOLET low temperature LUMINESCENCE Tm3+
  • 简介:近日德意志央行官网新闻通稿称从2013年底起,截止2016年末,其从美国纽约和法国巴黎将属于德国的583吨黄金运回法兰克福。如此大规模运回黄金储备,使得德国提前完成了原定2020年实现的储备目标。德国人从海外搬回家的这些黄金储备,说起来还有漫长心酸的历史。二战之前,为了防止苏联入侵本土,德国提前把自己的部分黄金储备运往海外储藏。进入冷战时代,东西德分裂,德国98%的黄金储备都存储在英美等远离欧洲前线的地方,确保安全。

  • 标签: 德国人 黄金 法兰克福 法国巴黎 储备 海外
  • 简介:SphericalYAG:Ce3+phosphorparticleswithnarrowsizedistributionwerepreparedbyspraypyrolysis.Theeffectsoftheconcentrationofsolution,theflowrateofcarriergasandtheannealingtemperatureonthephosphormorphologywerestudied.Theproductivityofprecursorparticlesshowsatrendofdropafterrisingwiththeincreaseofconcentration.Raisingtheflowrateofnitrogencanimprovetheproductivityoftheprecursorparticles.Phosphorpreparedbyspraypyrolysishasobviouslyhigheremissionintensitythanthatsynthesizedbysolidstatereaction,spraypyrolysismakesCe3+ionswelldistributedinthecrystallatticeastheluminescentcenters,andphosphorparticleshaveregularsphericityandnarrowsizedistribution.

  • 标签: 钇铝石榴石 稀土 热解 制备 发光二极管 荧光性质
  • 简介:新区3200m3高炉喷煤系统采用中速磨负压制粉,一级高浓度低压脉冲长袋式收粉器收粉。喷吹系统采用双系列双罐并列单管路加分配器浓相输送工艺。喷煤系统按烟煤和无烟煤混喷设计,制粉系统按强爆炸性烟煤设计,最大喷煤比250kg/t,尾气排放煤粉质量浓度≤30mg/m3,喷煤系统投运后,运行正常,烟煤配比达40%,高炉喷吹效果良好。

  • 标签: 高炉 喷煤 制粉 特点
  • 简介:截至2018年,汽运分公司在用6m^3铲运机76台。多年来6m^3铲运机前驱动桥的损坏、维修量一直居高不下,不但加大了修理工的维修工作量,还导致备件费用高,成本压力增大。因此,对6m^3铲运机前驱动桥的损坏进行原因分析,找出症结所在,制定应对措施,就显得尤为重要。

  • 标签: 铲运机 驱动桥 损坏
  • 简介:中铝山西分公司氧化铝3号因转窑窑前鼓风机因轴承失效、机壳移位等原因造成风机振动大,虽更换了轴承恢复了机壳位置,但振动未消除:后采用因素排除的方法,在检修过程中实行过程工序确认制度,最终找出了风机振动大的原因,和对缺陷处理的方法.

  • 标签: 氧化铝 回转窑 鼓风机 振动 动平衡 裂缝