简介:Ti-dopedW03filmswerepreparedbythemid-frequencydual-targetmagnetronsputteringmethod.ThestructureandelectrochromicpropertiesoftheTi-dopedWO3filmswereanalysedbyX-Raydiffraction(XRD),Ramanspectroscopy,spectrophotometer,cyclicchronoam-perometryandatomicforcemicroscopy(AFM).Theresultsindicatethatthecrystallinitydecreaseafterthedopingoftitanium,thechannelsforioninjectionandextractionincrease,therespondingspeedwith5.1%titaniumdopedbecomesfaster,anditscirclelifeincreasesmorethanfourtimescomparedwiththeundopedWOafilm.Inthecolouredstate,theW-O-Wbondsdecrease,buttheW=Obondsincrease.SincetheW-O-WbondsbreakdownforLi~+ions'injectionandmoreW=Obondsform,itismoreconvenienttoinjectLi~+ionsintotheTi-dopedfilmthanundopedfilmbecausemoreW-O-Wbondsbreakdowninthecolouredstate.
简介:MoleculardynamicssimulationsareperformedtoinvestigateCF3continuouslybom-bardingtheamorphoussiliconsurfacewithenergiesof10eV,50eV,100eVand150eVatnormalincidenceandroomtemperature.TheimprovedTersoff-Brennerpotentialswereused.Thesimu-lationresultsshowthatthesteady-stateetchingratesareabout0.019,0.085and0.1701for50eV,100eVand150eV,respectively.Withincreasingincidentenergy,atransitionfromC-richsurfacetoF-richsurfaceisobserved.IntheregionmodifiedbyCF3,SiFandCFspeciesaredominant.
简介:ThemagneticfusionreactorusingtheadvancedD-3Hefuelshastheadvantageofmuchless-neutronproductionssothattheconsequentdamagestothefirstwallarelessserious.Iftheestablishmentofthiskindofreactorbecomesrealistic,theexplorationof3Heonthemoonwillbelargelymotivated.Basedonrecentprogressesinthesphericaltorus(ST)research,wehavephysicallydesignedaD-3HefusionreactorusingtheextrapolatedresultsfromtheSTexperimentsandalsothepresent-daytokamakscaling.Itisfoundthatthereactorsizesignificantlydependsonthewallreflectioncoefficientofthesynchrotronradiationandoftheimpuritycontaminations.ThesecondaryreactionbetweenD-DthatpromptlyleadstotheD-Treactionproducing14MeVneutronsisalsoestimated.ComparisonofthisD-3HeSTreactorwiththeD-Treactorismade.
简介:采用XAFS方法研究浸渍法制备并于低温焙烧的CuO/γ-A12O3催化剂的局域结构。对于CuO负载量小于单层分散阈值的CuO/γ-A12O3(0.4mmol/100m2),结果表明CuO物种是以层状分散的孤立原子簇存在于γ-Al2O3载体表面,其第一近邻Cu-O配位环境的结构与晶态CuO的相似,键长和配位数分别为0.195nm和4。对于CuO负载量等于单层分散阈值的CuO/γ-A12O3(0.8mmol/100m。),已有少量的CuO纳米颗粒生成。对于CuO负载量大于单层分散阀值的CuO/γ-A12O3(1.2mmol/100m2),其结构与多晶CuO的相近。基于CuO在γ-A12O33载体上的三种不同分散状态的结构特点,我们提出了CuO/γ-A12O3催化剂的结构模型。
简介:Theγ-Fe2O3nanoparticlescoatedwithDBSandCTABwerepreparedbythemicroemulsionmethod.Thecoatedsamplesshowenhancednonlinearopticalpropertiescomparedwiththeirbulkcouterpart.The.Moessbauerspectraatroomtemperatureweremeasuredforthecoatedferricoxides.Themonolayersoftheorganicmoleculearefoundtohaveastrongchemicalbondwiththesurfaceatomsandthushaveasignificantinfluenceontheelectronstructureofparticlesurface.@1999ActaMetallurgicaInc.
简介:TheNi-AlalloycontainingCr,FeadditiveswerepreparedasRaneyNiCatalystbyhighenergymilling.ThesizeandsurfacestateofNi-Alalloypowderwerestudiedbyparticlesizeanalyzerandsanningelectronmicroscopy.theStructurewasanalyzedbyXRDandMoessbauermethods.Theresultsshowedthatafterahigh-energymilling(HEM).theNi-Alalloytransformstoanano-scaleNiAlstructurewithrichAl.Byannealingthealloy,ametastableNi2Al3phasecanbeobtained.