学科分类
/ 3
59 个结果
  • 简介:Thenucleationoforderedphasewassimulatedbasedonmicroscopicdiffusionequationandtheassumptionsoftheclassicalnucleationtheorywereexamined.Thequantitativecalculationsofinterfacethicknessevolutionwereaccomplishedforthefirsttime.Itwasfoundthattheinterfacesbetweenorderedphaseanddisorderedmatrixwerediffuse.Theinterfacethicknessdecreasedwithtime,fromtheinitial1.2nmtoanequilibriumvalue0.6nm.Theratiosoftheradiusoforderedparticlesandtheinterfacethicknessmonotonouslyincreased,buttheywereofthesameorderofmagnitudeallthetime.Thesharpinterfaceassumptionshouldnotbeadoptedinthisstage.FortheAl-10%Li(atomfraction)alloyagedat192℃,theassumptionsoftheclassicalnucleationtheorydisagreedwiththefacts.Thephasetransformationfollowedthenon-classicalnucleationmechanismandtheapplicablescopeoftheclassicalnucleationshouldbeconfined.

  • 标签: 计算机模拟 铝锂合金 晶核形成理论 界面扩散 相变
  • 简介:X-raydiffraction(XRD)anddifferentialscanningcalorimetry(DSC)wereusedtoinvestigatethecrystallizationprocessofamorphousAl90TMxCe10-x(atomfractionin%;TM=FeorNi;x=3,5)alloys.AgingeffectswereexaminedbyX-raydiffraction.ThestructurecorrespondingtotheprepeakfortheamorphousAl90Fe5Ce5alloyismorestablethantheamorphousmatrix,butitisnotstableforamorphousAl90Ni5Ce5alloyduringthefirstcrystallizationstageandevendecomposesatroomtemperature.AlthoughbothAl-NiandAl-Fehavestrongchemicalbonding,thecrystallizationonsettemperatureofamorphousAl-Fe-CealloysismuchhigherthanthatofamorphousAl-Ni-Cealloys,whichislikelycausedbythedifferentstabilityofthestructurecorrespondingtotheprepeak.ThecrystallizationonsettemperatureincreasesasCe/NiratioincreasesinamorphousAl90NixCe10-xalloys,whereasitdecreasesasCe/FeratioincreasesinamorphousAl90FexCe10-xalloys.AbetteratomicpackingproducesasCecontentincreasesbecauseofthesizemismatchinAlNi-CesystemsandasFecontentincreasesbecauseoftheincreasingFecentralstructuralunits.

  • 标签: 非晶形合金 Al90TMxCe10-x合金 稳定性
  • 简介:在二种铝锂alloys2090和2090+Ce的脱臼的微观结构借助于TEM技术被观察。到力量的8''和T_1precipitates的贡献被使用量的金属组织学的结果和微变丑的行为的分析独立计算;三角洲的共同加强的效果“andT_1猛抛被学习。结果证明三角洲共同加强的增加的关系“并且T_1根据1.4以近的山峰条件形成的q=,即,三角洲tau_p~(1.4)=三角洲字形物_(三角洲“)~(1.4)+三角洲字形物_(T_1)~(1.4);但是增加的关系是近似一种线性关系(q=1)以未成年的条件并且成为抛物线形式什么时候over-aged(q=2)。共同加强的增加的关系三角洲的贡献“并且显然依赖于老化时间的T_1is。

  • 标签: 金属原料 铝锂合金 深沉 加固
  • 简介:TheelectrochemicalbehaviorofCu-Zn-Alshapememoryalloy(SMA)withandwithoutelectrolessplatedNi-PwasinvestigatedbyelectrochemicalmethodsinartificialTyrode'ssolution.TheresultsshowedthatCu-Zn-AlSMAengendereddezincificationcorrosioninTyrode'ssolution.TheanodicactivecurrentdensitiesaswellaselectrochemicaldissolutionsensitivityoftheelectrolessplatedNi-PCu-Zn-AlSMAincreasedwithNaClconcentrationrising,pHofsolutiondecreasingandenvironmentaltemperatureuprising.X-raydiffractionanalysisindicatedthataftersurfacemodificationbyelectrolessplatedNi-P,anamorphousplatedfilmformedonthesurfaceofCu-Zn-AlSMA.ThisfilmcaneffectivelyisolatematrixmetalfromcorrosionmediaandsignificantlyimprovetheelectrochemicalpropertyofCu-Zn-AlSMAinartificialTyrode'ssolution.

  • 标签: 电化学行为 CU-ZN-AL 形状记忆合金 无电镀Ni-P
  • 简介:基于AB_5的氢存储薄电影(LaNi_(4.25)Al_(0.75)),由dc磁控管劈啪作响的扔的onCu底层在这研究被调查。X光检查衍射(XRD)表明层的微观结构在晶形。SEM和AFM分析证明这部电影看起来与近似在nmdiameter的15-40的众多的随机大小的毛孔相当不平。这部电影的结构的稳定性被DSC,XRD,andS他们,它显示这部电影在500K左右下面维持了它的结构的稳定性,和网络结构的联合分析检验在为30min在700K被加热以后在这部电影上被观察。这些电影的Electrochemicalhydrogen存储性质被模仿的电池测试调查。单人赛分层的LaNi_(4.25)Al_(0.75)大批拍摄类似于典型AB_5合金的展出电气化学的氢存储性质,这被发现,并且这部电影的最大的分泌物能力关于220mAh/g。在20个控告/解除周期以后,小塑造针的铝氧化物在电影表面的一些部分上被形成。

  • 标签: 储氢薄膜 磁控溅射 结构稳定性 电气化学性质 LaNi4.25Al0.75
  • 简介:ThevacuuminductionbrazingofSiCparticulatereinforcedLY12alloymatrixcompositeusingAl-28Cu-5Si-2Mgfillermetalhasbeencarriedout.Themicrographofthejointinterfacewasobservedbyscanningelectronmicroscopy.Thejointstrengthwasdeterminedbysheartests.Theresultsshowthatbrazingtemperature,holdingtime,SiCparticlevolumepercentageandpostheattreatmentinfluencejointstrength.SiCparticleshappeninthebrazingseamandthedistributionofSiCparticlesinthejointisnotuniform.Particle-poorzonesinthejointexistnearthebasemetal,andparticleconcentratezonesexistinthecenterofthebrazingseam.Inaddition,thefailureofthecompositeispredominantlyinitiatedbytherootingofSiCparticleinthebrazingseamandthemicro-crackexpandedalongthebrazingseamwithlowenergy.

  • 标签: 真空铜焊接 焊缝强度 矩阵 微观结构
  • 简介:环氧基PCB对无铅安装的兼容性作者通过PCB在经过无铅再流焊峰温260℃5~6次循环的完好比进行分析后比较了DICY和PN固化环氧基板材料对无铅安装的兼容性,试验结果显示DICY固化环氧基板材料不能经受多次无铅焊料的热应力冲击,同时,板材的设计和再流焊的热梯度也影响最终的安装性能。

  • 标签: 文献摘录 覆铜板 国内外 无铅焊料 基板材料 安装性能
  • 简介:ToinvestigatethedegradationofcorrosionresistanceofZircaloy-4inLiOHaqueoussolution,SIMS(secondaryionmassspectrometry)analysiswasperformedtoexaminetheprofilesofLi+,K+,andOH-inoxidelayersformedinthesameconcentration(0.1mol/L)LiOHandKOHsolutions.Eventhoughtheoxidelayershaveanequalthickness,thepenetrationdepthofK+isshallowerthanthatofLi+,andthepenetrationdepthofOH-corrodedinKOHsolutionisalsoshallowerthanthatcorrodedinLiOHsolution.ItshowsthatthediffusionofOH-intooxidelayerisaccompaniedbythecorrespondingcation.ThedifferenceofdegradationeffectofLiOHandKOHsolutionsonthecorrosionresistanceofZircaloy-4wasdiscussed.

  • 标签: 锆合金 氢氧化锂水溶液 耐腐蚀性 二次离子质谱
  • 简介:研究结果表明,1Cr18Ni9Ti不锈钢在pH=1的酸性NaCl溶液介质中浸泡最初期,噪声电流曲线无噪声峰,噪声电阻大,电化学阻抗谱为一容抗弧,阻抗模值大,电极表面处于稳定状态。浸泡24h噪声电流曲线出现尖峰波动,但波动峰值只有几个微安,噪声电阻直线下降,阻抗谱高频部分为一容抗弧,低频下出现感抗特征,阻抗模值大幅度下降表面处于点蚀诱导期的亚稳状态。浸泡48h后,噪声电流波动峰值突然增大至100μA,噪声峰也增多,噪声电阻基本稳定,阻抗谱低频下的感抗成分消失,点蚀进入稳定发展阶段。动电位极化曲线与电化学噪声测试结果表明,1Cr18Ni9Ti不锈钢在pH=1的酸性NaCl溶液介质中的耐点蚀性能随浸泡时问延长而降低。

  • 标签: 1Cr18Ni9Ti不锈钢 点腐蚀 电化学噪声 电化学阻抗谱
  • 简介:本套VCD详细介绍了热固性及其增强塑料的工艺特性和主要成型方法。主要内容包括:热固塑料注射戍型、压缩成型、压注成型工艺及模具设计。着重讲述了模具结构设计中应引起注意的事项和设计要点,并对部分成型零部件的设计方法、技巧进行了详细讲解。

  • 标签: 塑料成型工艺 模具设计 热固性 VCD 模具结构设计 成型方法
  • 简介:DD6alloywasbondedbytransientliquidphase(TLP)diffusionbonding.Themaincompositionsoftheinterlayeralloyemployedweresimilartothoseofthebasemetal,DD6,andacertainamountofelementBwasaddedasthemeltingpointdepressant.Theresultsshowthatitisdifficulttoobtainthejointswiththemicrostructurescompletelyhomogeneous.ForthejointTLPdiffusionbondedat1290℃for12h,abouthalfareasofthebeampossessedαγ+γ′microstructure,nearlyidenticalwiththatofthebasemetal,andtheotherlocalareasconsistedofT-solution,borides,etc.Prolongingthebondingtimeto24h,theinhomogeneousareasinthejointreduced,andthejointpropertyimproved.Thejointstress-rupturestrengthat980℃and1100℃reached90%-100%and70%-80%ofthoseofthebasemetalrespectively.

  • 标签: 简单晶体 超合金 液态相变换 结合扩散 接缝应力-破裂性质
  • 简介:InordertoimprovetheelectrochemicalcyclestabilityofLa-Mg-Nisystem(PuNi3-type)hydrogenstoragealloy,NiinthealloyswaspartiallysubstitutedbyM(M=Cu,Al,Mn).AnewLa-Mg-NisystemelectrodealloysLa0.7Mg0.3Ni2.55-xCo0.45Mx(M=Cu,Al,Mn;x=0,0.1)werepreparedbycastingandrapidquenching.Theeffectsofelementsubstitutionandrapidquenchingonthemicrostructuresandelectrochemicalperformancesofthealloyswereinvestigated.TheresultsbyXRD,SEMandTEMshowthatthealloyshaveamultiphasestructure,includingthe(La,Mg)Ni3phase,theLaNi5phaseandtheLaNi2phase.Therapidquenchingandelementsubstitutionhaveanimperceptibleinfluenceonthephasecompositionsofthealloys,butbothchangethephaseabundanceofthealloys.Therapidquenchingsignificantlyimprovesthecompositionhomogeneityofthealloysandmarkedlydecreasesthegrainsizeofthealloys.TheCusubstitutionpromotestheformationofanamorphousphaseintheas-quenchedalloy,andareversalresultbytheAlsubstitution.Theelectrochemicalmeasurementindicatesthattheelementsubstitutiondecreasesthedischargecapacityofthealloys,whereasitobviouslyimprovesthecyclestabilityofthealloys.ThepositiveinfluenceofelementsubstitutiononthecyclelifeofthealloysisinsequenceAl>Cu>Mn,andnegativeinfluenceonthedischargecapacityisinsequenceAl>Mn>Cu.Therapidquenchingsignificantlyenhancesthecyclestabilityofthealloys,butitleadstoadifferentextentdecreaseofthedischargecapacityofthealloys.

  • 标签: element SUBSTITUTION rapid QUENCHING La-Mg-Ni system
  • 简介:苏丹1/2/4油田年产原油1000万吨。油田内部集输管线600余km,集输干线100km,连接5个现场处理系统(FPF)和中心处理站(CPF)。优质原油经1500多公里的长输管道到达苏丹港出口。油田设施的设计寿命为25年。较为完善的防腐蚀系统设计覆盖了从井下套管、集输管线、输油干线到采油厂设备的几乎所有设施。本文对油田的防腐蚀系统的全貌进行介绍。

  • 标签: 苏丹 1/2/4油田 防腐措施 评价 腐蚀预测 阴极保护
  • 简介:ThestructureandelectrochemicalpropertiesofanewlowcobalthydrogenstorageelectrodealloysLa1-xLixNi3.2Co0.3Al0.3(0≤x≤0.2)wereinvestigatedwithadifferentadditionsofLiinreplacementofLa.WiththeincreaseofLicontentsthemaximumdischargecapacityincreasesfrom240mAh·g-1(x=0)to328.4mAh·g-1(x=0.1)andthecyclestabilityisimprovedcorrespondingly.ThecapacitydecaycanremaiN28.6%(x=0.2)after230charge/dischargecycles.Thehighratedischarge(HRD)abilityofthealloys(x≤0.1)isimprovedandthebestHRDis34.1%(x=0.1)underthedischargecurrentdensity1200mA·g-1.ItisfoundthatthepreparedalloysarebasicallycomposedofLaNi5asmatrixphaseandLaNi3assecondphase(x≤0.1).ButtheabundanceofLaNi3phasedramaticallydecreaseswithincreasingx.Whenx=0.2,anewphaseAl(NiCo)3isformed.

  • 标签: HYDROGEN storage alloy microstructure high rate
  • 简介:17CrNiM06H钢是德国ZF公司开发的Cr-Ni-Mo系齿轮钢,与美国SAE4320H、SAE9310H钢均属于大于1400MPa的高强度、大模数重载齿轮材料。目前,国内大冶钢厂、长城钢厂以及抚顺钢厂陆续完成了17CrNiM06H的国产化,冶金技术已趋成熟,产品性能较稳定,已用于制造重载汽车、装载机、挖掘机驱动桥齿轮。

  • 标签: 热处理工艺 优化 德国ZF公司 大冶钢厂 重载汽车 齿轮材料
  • 简介:Theeffectsofprocessparametersonthemicrostructuralevolution,includinggrainsizeandvolumefractionoftheαphaseduringhotformingofaTC6alloywereinvestigatedusingcompressiontests.Experimentswereconductedonthematerialwith(α+β)phasesatdeformationtemperaturesof800,860,920,and950°C,strainratesof0.001,0.01,1,and50s-1,andheightdirectionreductionsof30%,40%,and50%.Afterreachingapeakvaluenear920°C,thegrainsizeandvolumefractiondecreasewithfurtherincreaseofdeformationtemperature.ThestrainrateaffectsthemorphologiesandgrainsizeofαphaseoftheTC6titaniumalloy.Atalowerstrainrate,theeffectofthestrainrateonthevolumefractionisgreaterthanthatatahigherstrainrateundertheexperimentalconditions.Theeffectsofthestrainrateonthemicrostructurealsoresultfromdeformationheating.Thegrainsizeoftheαphaseincreaseswithanincreaseinheightdirectionreductionafteranearlydrop.Theeffectofheightdirectionreductiononthevolumefractionissimilartothatofthegrainsize.AlloftheopticalmicrographsandquantitativemetallographyshowthatdeformationprocessparametersaffectthemicrostructureduringhotformingoftheTC6alloy,andacorrelationbetweenthetemperature,strain,andstrainrateappearstobeasignificantfuzzycharacteristic.

  • 标签: 显微结构 钛合金 热压成型 晶粒尺寸 工艺参数