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简介：Temperature-dependentphotoluminescencecharacteristicsoforganic-inorganichalideperovskiteCH3NH3PbI3-xClxfilmspreparedusingatwo-stepmethodonZnO/FTOsubstrateswereinvestigated.Surfacemorphologyandabsorptioncharacteristicsofthefilmswerealsostudied.Scanningelectronmicroscopyrevealedlargecrystalsandsubstratecoverage.Theorthorhombic-to-tetragonalphasetransitiontemperaturewas140K.Thefilms’excitonbindingenergywas77.6±10.9meVandtheenergyofopticalphononswas38.8±2.5meV.TheseresultssuggestthatperovskiteCH3NH3PbI3-xClxfilmshaveexcellentoptoelectroniccharacteristicswhichfurthersuggeststheirpotentialusageinperovskitebasedoptoelectronicdevices.

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简介：Generally,ROSareregardedashostdefensemoleculesthatarereleasedbyneutrophilstodestroyexogenouspathogenssuchasbacteriaandtoactassecondarymessengersinsignaltransduction.However,increasedproductionofROSisalsoinvolvedininducingpathophysiologicalchangessuchasapoptosis,cellcycledisruption,andnecrosis.Forthisreason,inductionofROS-mediateddamageincancercellsbypharmacologicalagentsthateitherpromoteROSgenerationordisablethecellularantioxidantsystemisconsideredapotentialtherapeuticstrategyforpreferentiallykillingcancercells[1].

简介：TheinhomogeneityinacongrunetLiTaO3crystalhasbeenobservedbytransmissionsynchrotrontopography.ManyextraordinaryregionsexistincongruentLiTaO3crystalandtheyoftenshowdiffractionintensitydifferentfromthatofordinaryregionsinsynchrotrontopographs.DifferentialthermalanalysisindiatesthattheCurietemperatureoftheextraordinaryregionislowerthanthatofordinaryregion,andtheextraordinaryregionisreallyahighdefectdensityregion.Thediffractioncontrastoftheextraordinaryregioninsynchrotrontopographsisexplainedqualitativelybyacalculationattheselectedwavelength.2001PublishedbyElsevierScienceB.V.

简介：Pt/WO3/CnanocompositeswithparallelWO3nanorodsweresynthesizedandappliedasthecathodecatalystforprotonexchangemembranefuelcells(PEMFCs).Electrochemicalresultsandsinglecelltestsshowthatanenhancedactivityfortheoxygenreductionreaction(ORR)isobtainedforthePt/WO3/CcatalystcomparedwithPt/C.ThehighercatalyticactivitymightbeascribedtotheimprovedPtdispersionwithsmallerparticlesizes.ThePt/WO3/Ccatalystalsoexhibitsagoodelectrochemicalstabilityunderpotentialcycling.Thus,thePt/WO3/CcatalystcanbeusedasapotentialPEMFCcathodecatalyst.

简介：CaF2:Ho3+/Yb3+nano-particleswithintensegreenup-conversion(UC)luminescencearesuccessfullysynthesizedviaafacilehydrothermalapproachbyusingNH4FasthefluoridesourceandNa2EDTAasachelatingreagent.PowderXraydiffraction(XRD),transmissionelectronmicroscopy(TEM),fieldemissionscanningelectronmicroscopy(FE-SEM),andUCemissionspectraareusedtocharacterizethestructures,shapes,andluminescentpropertiesofthesamples.TheeffectsfromfluoridesourcesandchelatingreagentsontheformationsofCaF2nano-particlesareinvestigated,andtheformationprocessisalsodeduced.Undertheexcitationofa980-nmlaserdiode,thesampleseachshowagreenup-conversionemissioncenteredat540nmcorrespondingtothe5S2/5F4→5I8transitionsofHo3+.Moreover,theUCmechanismsofHo3+/Yb3+co-dopedCaF2nano-particlesarealsodiscussed.

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简介：采用燃烧法合成了La1.6（MoO_4）_3：Eu_0.4^3＋纳米晶末，研究了其声子一掺杂-晶格相互作用和发光性质。x射线粉末衍射（XRD）分析表明，在500～900℃退火后，La1.6（MoO_4）_3：Eu_0.4^3＋样品为单一晶相。对样品进行了光致发光（PL）测量，激发Mo^6＋-O^2-电荷迁移带，观察到Eu^3＋的系列发光，表明Mo^6＋-O^2-带和Eu^3＋间存在能量传递，中心波长分别在λ1=469nm和λ2=426nm处的两个one-phonon边带，相应的声子能量分别为767和1202cm^-1，分别对应于Mo=0和Mo-0-Mo伸缩振动。同时，计算了两个局域模电子一声子耦合强度的黄昆因子分别为S1=0．055和S2=0．037，为揭示其三价离子高传导特性及其负热膨胀物理特性提供了实验基础。

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简介：ThecorrelationbetweenphasestructuresandsurfaceacidityofAl2O3supportscalcinedatdifferenttemperaturesandthecatalyticperformanceofNi/Al2O3catalystsintheproductionofsyntheticnaturalgas(SNG)viaCOmethanationwassystematicallyinvestigated.Aseriesof10wt%NiO/Al2O3catalystswerepreparedbytheconventionalimpregnationmethod,andthephasestructuresandsurfaceacidityofAl2O3supportswereadjustedbycalciningthecommercialγ-Al2O3atdifferenttemperatures(600–1200C).COmethanationreactionwascarriedoutinthetemperaturerangeof300–600Catdifferentweighthourlyspacevelocities(WHSV=30000and120000mL·g-1h-1)andpressures(0.1and3.0MPa).ItwasfoundthathighcalcinationtemperaturenotonlyledtothegrowthinNiparticlesize,butalsoweakenedtheinteractionbetweenNinanoparticlesandAl2O3supportsduetotherapiddecreaseofthespecificsurfaceareaandacidityofAl2O3supports.Interestingly,NicatalystssupportedonAl2O3calcinedat1200C(Ni/Al2O3-1200)exhibitedthebestcatalyticactivityforCOmethanationunderdifferentreactionconditions.LifetimereactiontestsalsoindicatedthatNi/Al2O3-1200wasthemostactiveandstablecatalystcomparedwiththeotherthreecatalysts,whosesupportswerecalcinedatlowertemperatures(600,800and1000C).ThesefindingswouldthereforebehelpfultodevelopNi/Al2O3methanationcatalystforSNGproduction.

简介：A60%Fe/Al2O3catalystwaspreparedbytheco-precipitationmethod.ItwasreducedbyH2toproducemetallicFe,whichwasthensulfidedbyCS2toFe0.96SandFe3S4orphosphidedbytriphenylphosphine(PPh3)inliquidphasestoFe2PandFeP.Itwasfoundthattheironsulfides(Fe0.96SandFe3S4)exhibitedthelowactivityforthehydrodesulfurization(HDS)reactions.TheHDSactivitywasalsolowontheFe(metal)/Al2O3andFe2P/Al2O3catalystssincetheywereconvertedintoFe0.96SandFe3S4duringtheHDSreactions.Incontrast,theFeP/Al2O3wasfoundtobestableandactivefortheHDSreactions.Inparticular,FeP/Al2O3possessedsignificantlysmallerFePparticlesthanFeP/C,leadingtothesignificanthigherHDSactivityofFeP/Al2O3thanFeP/C.

简介：用多光子光电效应理论简要分析了多光子光电效应实验,指出多光子光电效应满足nhν=12mv20+φ(hν0)且nν/ν0=4/3。同时用微扰法及单光子光电效应理论分析了H原子电离问题,结果表明也是当ω/ω0=4/3时电离几率最大

简介：Theshapeofnanostructurehasimportanteffectsontheirproperties,thereforeinthisstudy,wehavepreparedandcharacterizedthreedifferentmorphologiesofWO3nanostructuresi.e.nanorod,nanosphereandnanoplateforsurveyingshapeeffectontheirphotocatalyticpropertiestowarddegradationofRhodamineB(RhB)dye.ObtainedresultsshowthatnanoplateWO3incomparisonwithothershasthebestphotocatalyticactivity.AccordingtoSEM,andphotocatalyticdegradationresults,thereasonforthisbehavioristhesharpedgesandcornersofWO3nanoplates.Becauseoftheirlowcoordinationnumber,atomslocatedintheedgesandcornersoftheWO3nanoplateshavemoreactivity,adsorbmoreRhBandthereforegivemorephotocatalyticactivitytotheWO3nanoplates.UsingofdifferentscavengersshowedthathydroxylradicalsaremainlyresponsibleforphotocatalyticactivityofWO3nanoplatesandnanospheresbutforWO3nanorods,superoxideradicalsarethemainphotocatalyticdegradationagents.

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