简介:这调查被承担预言钴的集体获得(MG)无电的免职(编辑)在上陶器原文如此粒子。反应表面方法论(RSM)基于有三个编辑参数和30跑的一个完整的因素的图案被用来进行实验并且借助于设计专家软件建立一个数学模型。考虑的三个编辑参数是pH,洗澡温度和陶器的粒子形态学。变化的分析被使用验证预言的模型。由扫描电子显微镜学(SEM)的证实分析的结果证明发达模型是相当精确的。pH是为MG的最有效的参数。另外,最高集体的获得为最低pH被获得,最高的洗澡温度并且对待热原文如此粒子。另外,发达模型证明得到集体获得的最大的价值的最佳的参数是pH,洗澡温度和8的陶器的粒子状态,70?????????迄?迄?X
简介:Poroussiliconpillararray(PSPA)sampleswhichareidealsubstantialmaterialswithdominantelectronicandluminescencepropertieswerepreparedbysurfaceetchingmethod.ZnOnanorodswithorwithoutMndopinggrownuniformlyandalignedontoPSPAregardlessoflatticematchingshowvariousphotoluminescence(PL)properties.ThedopedMnionsinZnOnanorodsweredirectlyobservedbyX-rayphotoelectronspectroscopy(XPS),andZnOstructuresweredetectedbyX-raydiffraction(XRD).Asthedopingconcentrationincreases,XRDpeaksofZnOnanorodsshifttolowangle.TheinfluencesofdopingMnionsonluminescencepropertiesofZnOnanorodswereinvestigated.Exceptfortheultraviolet(UV)PLband,thebroadPLbandisobservedatvisibleregion.Thebandcouldbedividedintothreeseparatebands(orange,greenandred)byLorentziandeconvolution.TheintensityoforangePLbandfirstlyincreasesthendecreases,andthengetsthemaximumatthedopingMn-to-Znmolarratioof2.0:100.0whichisthemosteffectivedopingconcentration.ThegreenPLbandisattributedtozincvacancyofZnO,theorangePLbandtoMnionsrecombinationofitself,andtheredPLbandtooxygenvacancyofZnO,respectively.AstheMn-dopedZnOnanorodscouldemityellowgreenluminescenceexcitedbyUVradiation,anddopedMnionscouldimprovethecolorrenderingindexoftheluminescence,thenanorodscouldbeusedaspromisingwhite-lightemittersinthefuture.
简介:Auniformtransienttemperaturefieldmodelofelectricalcontactsoperationwasfoundbyanalyzingtheprocessofclosingarc→constrictionresistanceJouleheat→breakingarc.EssentialparametersofAg/La2NiO4electricalcontactmaterialfortransienttemperaturefieldcalculationwereobtainedthroughtestsofelectricalcontactexperimentalinstrumentunder18VDCindifferentcurrents,othercorrelationexperiments,andcalculationanalysis.Thefiniteelementmethodwasappliedtosolvethetransienttemperaturefield,andthefeaturesanddistributionofthetransienttemperaturefieldwereobtained.Theconditionofmaterialerosionandmasstransfercanbeforecastedbythosecalculationresults.ItisbeneficialtoresearchaboutthelifetimeofAg/La2NiO4electricalmaterial.
简介:ThermodynamicmodelsofcalculatingmassactionconcentrationsforstructuralunitsorioncouplesinRbCl-H2ObinaryandRbCl-RbNO3-H2Oternarystrongelectrolyteaqueoussolutionsweredevelopedbasedontheionandmoleculecoexistencetheoryat298.15K.Atransformationcoefficientisneededtocomparethecalculatedmassactionconcentrationandthereportedactivitybecausetheyareobtainedatdifferentstandardstatesandconcentrationunits.TheresultsshowthatthetransformationcoefficientsbetweenthecalculatedmassactionconcentrationsandthereportedactivitiesofthesamestructuralunitsorioncouplesinRbCl-H2ObinaryandRbCl-RbNO3-H2Oternarystrongelectrolyteaqueoussolutionschangeinaverynarrowrange.ThetransformedmassactionconcentrationsofstructuralunitsorioncouplesinRbCl-H2Obinarysystemareingoodagreementwiththereportedactivities.ThetransformedmassactionconcentrationsofRbClandRbNO3inRbCl-RbNO3-H2Oternarysolutionarealsoingoodagreementwiththereportedactivities,aRbCland3RbNOa,withdifferenttotalionicstrengthsas0.01,0.05,0.1,0.5,1.0,1.5,2.0,3.0and3.5mol/kg,respectively.AllthoseresultsmeanthedevelopedthermodynamicmodelofstrongelectrolyteaqueoussolutionscanreflectstructuralcharacteristicsofRbCl-H2ObinaryandRbCl-RbNO3-H2Oternarystrongelectrolyteaqueoussolutionsandthemassactionconcentrationalsostrictlyfollowsthemassactionlaw.