简介:WeuseamodifiedBecke-JohnsonexchangeplusalocaldensityapproximationcorrelationpotentialwithinthedensityfunctionaltheorytoinvestigatetheelectronicstructuresofHg1-xCdxTeandIn1-xGaxAswithxbeing0,0.25,0.5,0.75,and1.Forbothofthetwoseries,ourcalculatedenergygapsanddielectricfunctions(realpartε1andimaginarypartε2)areinagreementwiththecorrespondingexperimentalresultswithxbeingbetween0and1.Thecalculatedzero-frequencyrefractiveindexvariesgreatlywithxforHg1-xCdxTe,butchangeslittlewithxforIn1-xGaxAs,whichisconsistentwiththerealpartsoftheirdielectricfunctions.Therefore,thisnewapproachissatisfactorytodescribetheelectronicstructuresandtheopticalpropertiesofthesemiconductors.
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简介:New[1+1]and62-membered[2+2]Schiffbasemacrocyclescontaininga2,6-diamidopyridinesubunithavebeensynthesizedbycondensationreactionoftheprecursorspyridine-2,6-dicarboxamideand1,10-bis(20-formylphenyloxy)decaneinthepresenceofphosphoricacidviaaone-potprocess.Thecyclocondensedproductswereeffectivelyisolatedbygelcolumnchromatographyandcharacterizedby~1HNMR,FTIR,massspectrometryandX-rayanalysis.Thetwomacrocycleshaveatwistedstructure,andnotanopen‘circular’conformationinthesolidstate.
简介:The1,1'-binaphtholbasedoligomers3and7with3,3'-acetylene-phenylene-acetylenespacerwerepreparedfromBINOL1.ThehighopticalrotationvalueandCDspectrademonstratedthemainchainchiralityoftheoligomermolecule.TheUV-VISandfluorescentspectraevidencethecharacteristicsofconjugatedstructure.Incomparisonwitholigomer2bearing3,3'-acetylenespacer,theoligomers3and7havelongerefficientconjugationsegment,andtheirfluorescentquantumyields(φ)increased(0.60-0.65versus0.14).Extendingtheeffectiveconjugationsegmentwouldimprovethephotophysicalpropertiesofchiralconjugatedpolymers.``
简介:AnovelSr2CuInO3Soxysulfidep-typesemiconductorphotocatalysthasbeenpreparedbysolidstatereactionmethodanditexhibitsintriguingvisiblelightabsorptionpropertieswithabandgapof2.3eV.Thep-typesemiconductorcharacterofthesynthesizedSr2CuInO3SwasconfirmedbyHallefficientmeasurementandMott-Schottkyplotanalysis.First-principlesdensityfunctionaltheorycalculations(DFT)andelectrochemicalmeasurementswereperformedtoelucidatetheelectronicstructureandtheenergybandlocations.Itwasfoundthattheas-synthesizedSr2CuInO3Sphotocatalysthasappreciateconductionandvalencebandpositionsforhydrogenandoxygenevolution,respectively.Photocatalytichydrogenproductionexperimentsunderavisiblelightirradiation(λ>420nm)werecarriedoutbyloadingdifferentmetalandmetal-likecocatalystsonSr2CuInO3SandRhwasfoundtobethebestoneamongthetestedones.
简介:S^p(1≤p≤∞)空间为导数属于Hardy空间H^p的复平面单位圆盘D上所有解析函数组成的空间.令函数φ和φ是D上的解析函数且φ(D)D,则将算子W(φ,φ):f→φfoφ称为加权复合算子.文章给出了当1≤q≤p≤∞,φ∈S^∞时,加权复合算子W(φ,φ)从空间S^p到S^q上的有界性的充要条件.然后通过推广经典的Fejer-Riesz不等式证明了当1〈p≤∞时,S^p到圆盘代数A上的嵌入映射是紧的.
简介:研究p-致凸Banach空间中渐近半压缩映象的修正的Mann迭代过程和修正的Ishikawa迭代过程的强收敛性.本文始终假设X是P-致凸Banach空间.最近,r-渐近半压缩映象的概念被引入,并给出了X中该映象(此时,r=P)的修正的Mann迭代过程和修正的Ishikawa迭代过程的强收敛性定理,文章所得结果改进、推广和统一了近期相关结果.
简介:ThecompressionbehaviourofPd39Ni10Cu30P21bulkmetallicglassisivestigatedatroomtemperatureupto23.5GPausinginsituhighpressureenergydispersivex-raydiffractionwithasynchrotronradiationsource.Pressureinducedstrucuralrelaxationofthebulkmetallicglassisexhibitedwithinthepressurerange.Itisfoundthatbelowabout5GPa,theexistenceofexcessfreevolumecontributestorapidstructuralrelaxation,whichgivesrisetorapidvolumeticchange.Underhigherpressure,furtherrelaxationresultsinstructuralstiffness.
简介:目前,国内没有关于半钢发热剂的国家标准检测方法,只能根据组分范围分别检测各个组分,不仅耗时而且使用的大量化学试剂对环境造成污染。故研究了X-射线荧光光谱法快速测定半钢发热剂中Si,P,S的方法。采用粉末压片制样,研究其制样条件,包括磨样时间、压样时间和压力对测定结果的影响。采用其它方法定值提供的检测样品,作为x-射线荧光光谱法内控标准样品,采用经验系数法进行基体校正,通过解谱拟合建立校准曲线,校准曲线建立后仪器建立漂移校正程序。实验结果精密度好,各元素的相对标准偏差在0.15%-1.3%。准确度满足生产需求,实验方法可用于快速检测半钢发热剂化学组分。
简介:Newmodelcompound1H,1′H-Bis(benz-Δ^4-imidazoline)2,2′-spiro-titaniumdichloridewaspreparedandthestructureofthecompoundwasdeterminedby1R,MSandelementaryanalysis.
简介:WeinvestigateindetailtheeffectsofR-parityleptonnumberviolationonthedecay~↑b1→b~↑x1^0intheR-parityviolatingminimalsupersymmetricstandardmodel(Rp-MSSM)underthepresentexperimentalconstraintsonRpparameters.Inournumericalcalculationsweconsidertwocasesofinputparametersofthesquarkandsleptonsectors,MsquarkMslepton,forcomparison.TheresultsshowthattherelativeR-parityviolatingcorrectionisnotverysensitivetothemassofthelightestneutralino-0↑x1andthedegenerateR-parityviolatingcouplingparameterλ2′,butstronglydependsonMsquark,Mslepton,tanβandthedegenerateR-parityviolatingcouplingparameterλ1′.Therelativecorrectionisabout-4~3%andcanexceed-6%insomeregionofparameterspace.Therefore,preciseexperimentanalysesonthedecay~↑b1→b~↑x1^0mayprovideaprobeoftheR-parityviolation.
简介:SYNTHESISANDANTI-HUMANIMMUNODEFICIENCYVIRUS-1(HIV-1)ACTIVITYOF9-(2-PHOSPHONYLMETHOXYETHYL)ADENINE(1)ANDITSREGIOISOMER3-(2-PHO...
简介:TwopossiblereactionmechanismsofVS~+(~3∑~-,~1Γ)withCOinthegasphasehavebeenstudiedbyusingB3LYP/TZVPandCCSD(T)/6-311+G(3dr,3pd)methods:theO/Sexchangereaction(VS~++CO→VO~++CS)andtheS-transferreaction(VS~++CO→V~++COS).Thetworeactionsproceedviatwo-stepandone-stepmechanism,respectively.ThebarriersofthetripletandsingletPESsare30.6and50.9kcal/mol,respectively,forO/Sexchangereactionand7.3and50.2kcal/mol,respectively,fortheS-transferreaction.Theresultsindicatethatthetripletgroundstatereactionismorefavorable,andtheS-transferreactionismorefavorablethantheO/Sexchangereaction,whichisingoodagreementwiththeexperimentalobservation.