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435 个结果
  • 简介:Thisperspectivepaperintroducestheconceptthatnanocarbonsandrelatedmaterialssuchascarbondotsareaninterestingintrinsicphotocatalyticsemiconductingmaterial,andnotonlyamodifieroftheexisting(semiconducting)materialstopreparehybridmaterials.Thesemiconductingpropertiesofthenanocarbons,andthepossibilitytohavethebandgapwithinthevisible-lightregionthroughdefectbandengineering,introductionoflightheteroatomsandcontrol/manipulationofthecurvatureorsurfacefunctionalizationarediscussed.Thesematerialsareconceptuallydifferentfromthe'classical'semiconductingphotocatalysts,becausesemiconductordomainswithtuneablecharacteristicsareembeddedinaconductivecarbonmatrix,withthepresenceofvariousfunctionalgroups(asC=Ogroups)enhancingchargeseparationbytrappingelectrons.Thesenanocarbonsopenarangeofnewpossibilitiesforphotocatalysisbothforenergeticandenvironmentalapplications.Theuseofnanocarbonsasquantumdotsandphotoluminescentmaterialswasalsoanalysed.

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  • 简介:Assumingthatthelithiationreactionoccursrandomlyinindividualsmallparticlesinthevicinityofthereactionfront,asimplemodelofdiffusioninduceddislocationswasdeveloped.Thediffusion-induceddislocationsarecontrolledbythemisfitstraincreatedbythediffusionofsoluteatomsorthephasetransformationinthevicinityofthereactionfront.Thedislocationdensityisproportionaltothetotalsurfaceareaofthe"lithiatedparticle"andinverselyproportionaltotheparticlevolume.Thediffusion-induceddislocationsrelievethediffusion-inducedstresses.

  • 标签: 锂化反应 简单模型 扩散 晶体材料 位错密度 小颗粒
  • 简介:AccordingtothepreliminarystatisticsofthemagneticmaterialsbranchofAssociationofChinarareearthindustry,therareearthpermanentmagneticmaterialsindustrymaintainedagoodmomentumofdevelopmentfromJanuarytoOctober2018,benefitingfromtherapiddevelopmentofnewenergyvehicles,energy-savinghouseholdappliances,industrialrobotsetc.Theoutputofpermanentmagneticmaterialsgrewsteadilyandtheproportionofhigh-endproductsaccountedfornearly60%.Amongthem,productionofsinteredNdFeBwas129,500tons,ayear-on-yeargrowthof5%.TheoutputsofbondedNdFeBandSmComagnetswere5,500tonsand2,100tonsrespectively,unchangedthanthesameperiodlastyear.

  • 标签: According NDFEB
  • 简介:ThecomplexcoatingontheMgO-CaOclinkerwaspreparedbydippingmethodandaddingthesecondmineraltorestraintheformationandexpansionofthecracks.Meanwhile,thericrostructureandthemorphologyofthecoatingandhydrationresistanceoftheMgO-CaOclinkerwerealsoinvestigated.TheresultshowsthatthecoatingconsistsmainlyofCa2P2O7,MgOandCaCO3,itsthicknessrangesfrom5μmto20μm,andthecoatingisdenseandeven,nomicro-cracksareobserved.Also,thecoatingadherescloselytothematrix.ThehydrationresistanceoftheMgO-CaOclinkeraftertreatmentisimprovedgreatly,andthecastablespreparedwiththetreatedMgO-CaOclinkerhavebetterphysicalpropertiesthanMgOcastable.

  • 标签: 氧化钙 氧化镁 浸渍方法 MgO CAO 水合作用
  • 简介:Oneoffundamentalbutdifficultproblemsindamagemechanicsistheformulationoftheef-fectiveconstitutiverelationofmicrocrack-weakenedbrittleorquasi-brittlematerialsundercomplexloading,especiallywhenmicrocrackinteractionistakenintoaccount.Thecombinationofphenomenologicalandmi-cromechanicaldamagemechanicsisapromisingapproachtoconstructinganapplicabledamagemodelwithafirmphysicalfoundation.Inthispaper,aquasi-micromechanicalmodelispresetedforsimulatingthecon-stitutiveresponseofmicrocrack-weakenedmaterialsundercomplexloading.Themicrocrackingdamageischaracterizedintermsoftheorientationdomainofmicrocrackgrowth(DMG)aswellasascalarmicrocrackdensityparameter.TheDMGdescribesthecomplexdamageanditsevolutionassociatedwithmicrocrackgrowth,whilethescalarmicrocrackdensityfactordefiningtheisotropicmagnitudeofdamageyieldsaneasycalculationoftheeffectsofmicrocrackinteractiononeffectiveelasticmoduli.

  • 标签: CONSTITUTIVE RELATION quasi-mieromechanical model BRITTLE material
  • 简介:Theproblemofananti-planeGriffithcrackmovingalongtheinterfaceofdissimilarpiezoelectricmaterialsissolvedbyusingtheintegraltransformtechnique.Itisshownfromtheresultthattheintensityfactorsofanti-planestressandelectricdisplacementaroundthecracktiparedepen-dentonthespeedoftheGriffithcrackaswellasthematerialcoefficients.Whenthetwopiezoelectricmaterialsareidentical,thepresentresultwillbereducedtotheresultfortheproblemofananti-planemovingGriffithcrackinhomogeneouspiezoelectricmaterials.

  • 标签: INTERFACE GRIFFITH CRACK PIEZOELECTRIC material ANTI-PLANE
  • 简介:ONTHEFUNDAMENTALPROBLEMFORANINFINITEELASTICPLANEBONDEDBYDIFFERENTANISOTROPICMATERIALSWITHCRACKSZHENGKE(DepartmentofMathematic...

  • 标签: Cracks ANISOTROPIC PLANE ELASTICITY complex variable
  • 简介:垫子是在木排和地面之间的小粒的材料的层。在垫子和木排之间的接口的shear行为可以影响上层建筑的地震表演。为了确定,这影响,水平砍在在monotonic并且周期的装载下面的不同垫子材料和具体木排之间的接口上的测试被执行。垂直压力Pv,材料类型和垫子厚度hc作为变量被拿。结论包括:1)在装载的monotonic下面,Pv是最重要的因素;shear抵抗Phmax作为Pv增加,而是抵抗n有一个相反的趋势;2)因为材料在这研究使用了,n从0.40~0.70变化,接口磨擦角度s从20变化

  • 标签: 材料类型 接口 垫子 行为 试验性 学习
  • 简介:我们与强壮的纺纱轨道的couplings在三维、二维的材料处于悦耳的拓扑的量状态考察我们的理论进展。在三维的系统,我们建议新悦耳的拓扑的绝缘体,拓扑的绝缘在说的基于铋的skutterudites能被外部种类导致。涉及拓扑的乐队倒置过程的orbitals是d-orbitals,和p轨道,不同于象双性人那样的典型拓扑的绝缘体<潜水艇class=“a-plus-plus”>2Se<潜水艇class=“a-plus-plus”>3和BiTeI,在仅仅p轨道涉及乐队倒置的地方,处理。由于大d电子的状态的存在,在我们的建议拓扑的绝缘体的电子相互作用在另外的常规拓扑的绝缘体是比那强壮得多的。在二维的系统,我们调查了3d-transition-metal-dopedsilicene。用一个分析模型和第一原则的Wannier插值,我们表明与象钒那样的金属能支撑的某些3d转变装饰的那silicene稳定的量异常霍尔效果。我们也预言量山谷霍尔效果和电子上悦耳的拓扑的状态能在精力乐队倒置发生的某些transition-metal-dopedsilicenes被认识到。这些调查结果提供拓扑的状态能任意地在被控制的现实主义的材料。

  • 标签: 二维材料 量子态 拓扑 可调 自旋轨道耦合 反常霍尔效应
  • 简介:Amolecularnetworkconstitutivemodelisproposedinthisstudy.Basedontheconceptofmolecularnetworkdecomposition,themolecularnetworkwasdecomposedintoaJames-Guth3-chainnetworkmodelandanArruda-Boyce8-chainnetworkmodel.Consideringthatthesinglemolecularchainofrubberisconstrainedbythesurroundingmolecularnetworks,the3-chainmodelandthe8-chainmodelwereconsequentlymodifiedusingthetubetheory.Theproposedmodelcontainsfourmaterialparametersthatweredeterminedbyfittingtheuniaxialtensiletestdatafromrubber-likematerials,andthevaluesoftheseparameterswereutilizedtodeterminethepureshearandthebiaxialextension.Theproposedmodelagreeswellwiththeexperimentaldataandcanpredictthetestresultsofexperimentsperformedundertheconditionsofpureshearandequi-biaxialdeformationwithacceptableaccuracy.

  • 标签: HYPERELASTIC NETWORK DECOMPOSITION Rubber-like materials CONSTITUTIVE
  • 简介:Newcarbonbondedfilterswith'activeandreactivecoatings'forhigherfiltrationefficiencyofaluminabasedinclusionsaswellasnano-engineeredfilterswithnano-scaledadditivesareexploredwiththeaidofimpingementtestsandareevaluatedaccordingtotheircoldcrushingstrengthsatroomtemperature.ThecombinationofcarbonnanotubesandaluminananosheetsadditivesleadstoinsituformationofAl3CON.Boththenanoscaledadditivesaswellastheextraalumina'active'coatingleadtoimprovedmechanicalperformanceofthecarbonbondedfiltersandopenthehorizonforfiltermacrostructureswithhigherfiltrationcapacitiesinmeansofbiggerdimensions.InafurtherstepMWCNT(multiwalledcarbonnanotubes)incombinationwithasyntheticpitchhavebeenusedasafunctionalcoatingonthesurfaceofaluminacarbonbondedfilters.Thesefiltershavethenbeenevaluatedalsowithuncoatedfiltersinaspecialcastingsimulatorandtheinteractionsbetweensteelandfilteringmaterialhavebeeninvestigated.

  • 标签: 过滤材料 相互作用 洁净钢 多壁碳纳米管 纳米氧化铝 纳米过滤器
  • 简介:Montmorillonite(MMT)wasdirectlymodifiedwithhexadecyltrimethylammoniumbromide.Theinterlayerspacingoftheorganophilicmontmorillonite(organo-MMT)correspondingtothed(001)planepeakwas2.21nm.Theinfluencesofthecontentoforgano-MMTandmixingconditionsincludingmixingtemperatureandmixingtimeontheintercalationandexfoliationstructuresofMMT/epoxyresincompositeswereinvestigatedbywideX-raydiffraction(WXRD).TheX-raypatternsrevealthatorgano-MMTwasintercalatedbytheepoxyresinduringmixingprocess.Onlyundercertainmixingconditions,couldtheexfoliationnanocompositesbeformed.Themechanicalandthermalpropertiesofthecompositesweremeasured.TheresultsindicatethatthecompositeshavebettermechanicalpropertiesandhigherTgthanthoseofthepristineepoxyresin.

  • 标签: 环氧树脂复合材料 有机蒙脱土 混合时间 热性能 玻璃化转变温度 十六烷基三甲基铵
  • 简介:Todaysteelisproducedbytwosteelmakingprocesses,thebasicoxygenfurnaceandtheelectricarcfurnace.Threetypesofironinputmaterialsforbothprocessesareliquidhotmetalorinsolidifiedformaspigiron,directreducediron(DRI)andhotbriquettediron(HBI)aswellassteelscrap.Hotmetal,pigiron,DRIandHBIarevirginironmaterials,whichhavetobeproducedfromironorebytheso-calledironmakingtechnologies.Newironmakingprocessesbasedonfluidizedbedtechnologyhavebeendevelopedinthelasttwodecades.Themainadvantageofthesetechnologiesisthatfineorecanbedirectlyusedintheprocessesandpriortreatmentsuchassinteringorpelletizingcanbeavoidedwhichisrequiredfortheestablishedprocesses.Theoreticalaspectsforreductionoffineironoxidesinafluidizedbedreactorsystemwillbeexplained.Thefluidizedbedreducingtechnologiesutilizedinthemostadvancednewironmakingprocessesfordirectuseoffineore,FINMET,Circored,FINEXandHIsmeltwillbecompared.

  • 标签: 流化床技术 材料生产 炼钢工艺 生铁 输入 HISMELT
  • 简介:Preparationofhierarchicallyporous,heteroatom-richnanostructuredcarbonsthroughgreenandscalableroutesplaysakeyroleforpracticalenergystorageapplications.Inthiswork,naturallyabundantlignocellulosicagriculturalwastewithhighinitialoxygencontent,hazelnutshells,werehydrothermallycarbonizedandconvertedintonanostructured‘hydrochar’.Environmentallybenignceramic/magnesiumoxide(MgO)templatingwasusedtointroduceporosityintothehydrochar.Electrochemicalperformanceoftheresultingmaterial(HM700)wasinvestigatedinaqueoussolutionsof1MH2SO4,6MKOHand1MNa2SO4,usingathree-electrodecell.HM700achievedahighspecificcapacitanceof323.2F/gin1MH2SO4(at1A/g,-0.3to0.9Vvs.Ag/AgCl)duetothecontributionsofoxygenheteroatoms(13.5wt%)tothetotalcapacitancebypseudo-capacitiveeffect.Moreover,amaximumenergydensityof11.1Wh/kgandamaximumpowerdensityof3686.2W/kgwereattainedforthesymmetricsupercapacitoremployingHM700aselectrodematerial(1MNa2SO4,E=2V),makingthedevicepromisingforgreensupercapacitorapplications.

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  • 简介:MedicalforgedCoCrMoalloywastreatedbyplasmanitridingprocess.Themicrostructureswerecharacterizedby3Dprofiler,SEMandXRD.Thetribologicalpropertieswereinvestigatedunderlubricationof25%bovineserumsolution.Resultsshowthatplasmanitridingisapromisingprocesstoproducethick,hard,andmorewearresistantlayersonthesurfaceofCoCrMoalloy.AllnitridedsamplesshowedanimportantincreaseinthesurfacehardnessduetotheformationofharderCrNandCr2Nphaseswithcompactnano-crystallinestructures.ThetypicalhardnessvaluesofHV0.05increasedalmosttwotimesthanuntreatedone.Underbovineserumlubrication,atlownitridingtemperaturetheCoefficientofFriction(COF)ofnitridedsamplewaslowerthanthatofuntreatedsample,butathighnitridingtemperaturetheCOFwasalmostthesameastheuntreatedone.Comparedwiththeuntreatedsample,thenitridedsamplesshowedlowerwearratesandhigherwearresistanceunderdifferentnitridingtemperatures.TheadhesivewearisthemainmechanismforuntreatedCoCrMoalloyandthewearmechanismsofnitridedonesarethefatiguewearandslightadhesivewear.ItisconcludedthattheimprovementofwearresistanceisascribedtothehardnitrideformationofCrNandCr2Nphasesatthenitridedsurfaces.

  • 标签: COCRMO alloy plasma NITRIDING MICROSTRUCTURE FRICTION
  • 简介:Thispaperpresentsahybridgradedelementmodelforthetransientheatconductionprobleminfunctionallygradedmaterials(FGMs).First,aLaplacetransformapproachisusedtohandlethetimevariable.Then,afundamentalsolutioninLaplacespaceforFGMsisconstructed.Next,ahybridgradedelementisformulatedbasedontheobtainedfundamentalsolutionandaframefield.Asaresult,thegradedpropertiesofFGMsarenaturallyreflectedbyusingthefundamentalsolutiontointerpolatetheintra-elementfield.Further,Stefest'salgorithmisemployedtoconverttheresultsinLaplacespacebackintothetime-spacedomain.Finally,theperformanceoftheproposedmethodisassessedbyseveralbenchmarkexamples.Theresultsdemonstratewelltheefficiencyandaccuracyoftheproposedmethod.

  • 标签: 功能梯度材料 瞬态热传导 元模型 混合 Laplace空间 拉普拉斯变换
  • 简介:当控制媒介的湿度被测试,控制作为基本水泥材料和激活的海泡石包含石膏的材料的一些湿度的吸收/解吸附作用性质搽粉。潮湿吸附/解吸附作用的动力学曲线被拉,在自然环境控制性能的湿度被验证。试验性的结果证明潮湿吸收/解吸附作用率被增加,并且速度也被加速。这些材料,能有效地调整环境湿度,是有控制性能的好湿度的新的。

  • 标签: 湿度控制 水泥材料 解吸性能 石膏基 吸收 制备