学科分类
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393 个结果
  • 简介:CdSe/CdS半导体量点共同敏化TiO2nanorod数组在透明的传导性的做氟的符号的听氧化物(FTO)上被制作使用热水、连续的离子的层吸附和反应(SILAR)过程的底层。样品的结构、词法的性质被X光检查描绘衍射(XRD),地排放扫描电子显微镜学(FESEM),和传播电子显微镜学(TEM)。结果显示CdSe/CdSQD在TiO2nanorods的表面上是一致地涂的。轻吸收边的移动被拿紫外可见的吸收系列监视。与TiO2nanorod数组的吸收系列相比,CdSe/CdSQD的免职转移吸收边到更高的波长。当在量点的co-sensitizers敏化太阳能电池(QDSSC),在CdSe/CdS/TiO2nanorod数组的可见光的区域的提高的轻吸收显示CdSe/CdS层能行动。由优化CdSe层免职周期,5.78mA/cm2的光电流,0.469V的开的电路photovoltage和变换,1.34%的效率在100mw/cm2的照明下面被获得。

  • 标签: 半导体量子点 太阳能电池 二氧化钛 纳米棒 硒化镉 共敏化
  • 简介:ThethermodynamicphasestabilityareadiagramsofBCl3-NH3-SiCl4-H2-ArsystemwereplottedviaFactsagesoftwaretopredictthekineticexperimentalresults.Theeffectsofparameters(ie,partialpressureofreactants,depositiontemperatureandtotalpressure)onthedistributionregionsofsolidphaseproductswereanalyzedbasedonthediagrams.Theresultsshowthat:(a)Solidphaseproductsaremainlyaffectedbydepositiontemperature.TheareaofBN+Si3N4phaseincreaseswiththetemperaturerisingfrom650to900℃,anddecreaseswiththetemperaturerisingfrom900to1200℃;(b)Whentemperatureandtotalpressureareconstants,BN+Si3N4phaseexistsatahighpartialpressureofNH3;(c)Theeffectoftotalsystempressureiscorrelatedtodepositiontemperature.Thetemperaturerangingfrom700to900℃underlowtotalpressureistheoptimumconditionforthedeposition.(d)Appropriatekineticparameterscanbedeterminedbasedontheresultsofthermodynamiccalculation.Si–B–Ncoatingisobtainedvialowpressurechemicalvapordeposition.TheanalysisbyX-rayphotoelectronspectroscopyindicatesthatB–NandSi–Narethemainchemicalbondsofthecoating.

  • 标签: boron trichloride-ammonia-silicon tetrachloride-hydrogen-argon SYSTEM thermodynamic phase
  • 简介:综述了近年来共掺杂TiO2光催化剂的研究进展,介绍了众多学者在双金属共掺杂、双非金属共掺杂、金属与非金属共掺杂以及2种以上元素共掺杂方面的最新研究成果。同时阐述了共掺杂TiO2的协同作用机制,并对共掺杂TiO2光催化剂以后的研究方向提出了建议。

  • 标签: 共掺杂 纳米TIO2 光催化剂 协同作用
  • 简介:采用电化学阳极氧化法在HF水溶液体系中对钛金属进行表面处理,得到高度规整的TiO2纳米管阵列。主要研究了电解液pH值大小对TiO2纳米管阵列形貌(管径及管长)的影响;用扫描电子显微镜(SEM)对其表面形貌进行表征。结果表明:酸性条件下能形成TiO2纳米管;强碱性环境不利于TiO2纳米管的制备;在可制备TiO2纳米管的pH值范围内,管径和管长随pH值升高而减小。采用微孔模型对pH值的影响机理进行了阐述。

  • 标签: 二氧化钛 纳米管 阳极氧化 PH值
  • 简介:通过溶胶凝胶-熔盐法以NaCl为熔盐制备了掺杂Co^2+的Cd1-xCoxFe2O4(x=0~0.5)尖晶石铁氧体。利用XRD、SEM和VSM等手段对样品进行了结构、形貌和磁性表征,并详细讨论了Co^2+对Co1-xCdxFe2O4(x=0-0.5)铁氧体结构和磁性的影响。结果表明:在研究范围内掺杂后仍然能得到单相尖晶石结构铁氧体;样品均为正八面体;比饱和磁化强度随x的增大而增加。

  • 标签: Cd1-xCoxFe2O4 溶胶凝胶熔盐法 比饱和磁化强度
  • 简介:制备富含Bi2O3的微晶封接玻璃,分别用XRD、膨胀仪、光学显微镜等仪器对样品进行表征。结果表明,富含Bi2O3系统可形成玻璃,经造粒成型、热处理后可微晶化。微晶玻璃的转变温度Tg和软化温度Tf分别为438℃和475℃.在420℃时电阻率达6.4×10^7Ω·m,在30-300℃膨胀系数α达8.82×10^-6/℃,可取代金属封接用的传统含铅封接玻璃,并且满足环保对无铅的要求。

  • 标签: 无铅 膨胀系数 软化温度 电绝缘 金属-金属间封接
  • 简介:以Sn为原料,采用磁控溅射及热蒸发法制得SnO2纳米线,用扫描电镜(SEM)、透射电镜(TEM)、X射线衍射(XRD)、能量弥散X射线谱(EDS)、傅氏转换红外线光谱分析(FTIR)、拉曼光谱分析(Raman)等测试手段对纳米结构进行表征,结果表明,合成的二氧化锡纳米结构具有金红石结构,二氧化锡纳米材料的生长机制遵循气一液一固生长机制,生长过程中的温度和退火时间对二氧化锡纳米结构的形貌起着极其重要的作用,可以通过这些因素对二氧化锡纳米材料实行可控生长。

  • 标签: SnO2纳米线 热蒸发 磁控溅射 生长机制
  • 简介:FenanowirearraywithstrongshapeanisotropywasemployedasthesoftphaseinNd-Fe-Bbasednanocomposites.TheeffectsoftheFenanowiredistributiononmagneticpropertiesofthenanocompositeswereinvestigatedbymicromagneticsimulation.TheresultsindicatethattheshapeanisotropyofFewiresaddedinthesamedirectionastheuniaxialmagnetocrystallineanisotropyofthehardphasecannotincreasethecoercivityofthenanocomposite.Whenthenanowiresaredistributedperpendiculartotheeasyaxisofthehardphase,theshapeanisotropyofsoftphasecanretardthemomentsfromrotatingtothefullreverseddirection,leadingtoenhancedcoercivity.Inaddition,withincreasingthenanowirediameter,thecoercivityofthenanocompositedecreases,butthedipolarinteractionshowsdifferentrolesinmagneticreversalofnanocompositefordifferentdistributionsofnanowires.ThecurrentresultssuggestthatthecoercivityoftheNd2Fe14B/α-Fenanocompositecanbeenhancedbyintroducingthesoftmagneticnanowirearraywiththediameterlessthantheexchangelengthandwiththelongaxisalongthedirectionotherthantheeasyaxisofhardphase.

  • 标签: Nd2Fei4B/α-Fe NANOCOMPOSITE MICROMAGNETIC simulation FE NANOWIRES
  • 简介:Inthepresentpaper,twomodelsbasedonartificialneuralnetworksandgeneticprogrammingforpredictingsplittensilestrengthandpercentageofwaterabsorptionofconcretescontainingZrO2nanoparticleshavebeendevelopedatdifferentagesofcuring.Forbuildingthesemodels,trainingandtestingusingexperimentalresultsfor144specimensproducedwith16differentmixtureproportionswereconducted.Thedatausedinthemultilayerfeedforwardneuralnetworksmodelsandinputvariablesofgeneticprogrammingmodelswerearrangedinaformatofeightinputparametersthatcoverthecementcontent,nanoparticlecontent,aggregatetype,watercontent,theamountofsuperplasticizer,thetypeofcuringmedium,ageofcuringandnumberoftestingtry.Accordingtotheseinputparameters,intheneuralnetworksandgeneticprogrammingmodels,thesplittensilestrengthandpercentageofwaterabsorptionvaluesofconcretescontainingZrO2nanoparticleswerepredicted.ThetrainingandtestingresultsintheneuralnetworkandgeneticprogrammingmodelshaveshownthattwomodelshavestrongpotentialforpredictingthesplittensilestrengthandpercentageofwaterabsorptionvaluesofconcretescontainingZrO2nanoparticles.Ithasbeenfoundthatneuralnetwork(NN)andgeneexpressionprogramming(GEP)modelswillbevalidwithintherangesofvariables.Inneuralnetworksmodel,asthetrainingandtestingendedwhenminimumerrornormofnetworkgained,thebestresultswereobtainedandingeneticprogrammingmodel,when4geneswereselectedtoconstructthemodel,thebestresultswereacquired.Althoughneuralnetworkhavepredictedbetterresults,geneticprogrammingisabletopredictreasonablevalueswithasimplermethodratherthanneuralnetwork.

  • 标签: 英文摘要 材料科学 优秀论文 科技学报
  • 简介:Theeffectofthehot-chargingtreatmentontheperformanceofAB2andAB5hydrogenstoragealloyelectrodeswasinvestigated.Theresultshowedthatthetreatmentcanmarkedlyimprovethevoltageplateauratio(VPR),thehighratedischargeability(HRDA),thediffusioncoefficientofhydrogenDHandthedischargecapacityoftheAB2hydrogenstoragealloyelectrode.TheSEManalysisshowedthatthehot-chargingtreatmentbringsaboutaNi-richsurfaceduetothedissolutionofZroxides.ItisalsoveryhelpfulfortheimprovementofthekineticpropertiesofAB2hydrogenstoragealloyelectrodebecausethemicrocrackingo.fthesurfaceresultsinfreshsurface.ThiscanbethebasicmodificationtreatmentforNiMHbatteryusedinelectricvehicles(EVs)inthefuture.ButforAB5typealloys,thetreatmenthasthedisadvantageofimpairingthecomprehensiveelectrochemicalproperties,becausethesurfaceofthealloymaybecorrodedduringthetreatment.Themechanismofthesurfacemodificationoftheelectrodeisalsoproposed.

  • 标签:
  • 简介:以Pickering乳液液滴为模板,通过液滴表面水合作用制备出MgO/Mg(OH)_2复合空心球壳,通过SEM、XRD等手段进行表征,讨论了空心球壳形成机理,并研究了MgO/Mg(OH)_2复合空心球壳对阿维菌素微胶囊的缓释作用,结果表明,MgO/Mg(OH)_2复合空心球壳形貌完整,粒径分布均匀,平均粒径为62μm。水合过程中部分MgO转变成Mg(OH)_2,并优先复合在未反应的MgO粒子上,形成MgO/Mg(OH)_2复合空心球壳。以MgO/Mg(OH)_2复合空心球壳为壁材的阿维菌素微胶囊具有良好的缓释性能。

  • 标签: Pickering乳液 空心球壳 MgO纳米粒子 阿维菌素 微胶囊
  • 简介:以硬脂酸锌为Zn源、硫化钠为S源,首次采用油水界面法制备出单分散于环己烷和甲苯的ZnS纳米材料,探索有机溶剂、锌源和油酸浓度等对紫外吸收影响的同时,以ZnS为基质,掺杂Mn^2+和Eu^3+制得ZnS:Mn^2+,Eu^3+发光纳米材料,采用高分辨率透射电子显微镜(HRTEM)、X射线粉末衍射仪(XRD)、紫外可见(UV-VIS)和荧光分光光度计(PL)对产物进行了表征,紫外和HRTEM测试结果均表明,产物为单分散性,平均粒径为4.3nn;荧光测试表明,产物所发荧光较强,肉眼可观测到明显的橙黄色(585nm)和橙红色(616nm)发光;XRD结果显示,产物结构为立方闪锌矿结构

  • 标签: ZnS:Mn^2+ Eu^3+ 发光纳米材料 油水界面法