学科分类
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396 个结果
  • 简介:COandformaldehyde(HCHO)oxidationreactionswereinvestigatedovermesoporousAg/Co3O4catalystspreparedbyone-pot(OP)andimpregnation(IM)methods.Itwasfoundthattheone-potmethodwassuperiortotheimpregnationmethodforsynthesizingAg/Co3O4catalystswithhighactivityforbothreactions.ItwasalsofoundthatthecatalyticbehaviorofmesoporousCo3O4andAg/Co3O4catalystsforthebothreactionswasdifferent.AndtheadditionofsilveronmesoporousCo3O4didnotalwaysenhancethecatalyticactivityoffinalcatalystforCOoxidationatroomtemperature(20C),butcouldsignificantlyimprovethecatalyticactivityoffinalcatalystforHCHOoxidationatlowtemperature(90C).Thehighsurfacearea,uniformporestructureandtheprettygooddispersiondegreeofthesilverparticleshouldberesponsiblefortheexcellentlow-temperatureCOoxidationactivity.However,forHCHOoxidation,theadditionofsilverplayedanimportantroleintheactivityenhancement.AndthesilverparticlesizeandthereducibilityofCo3O4shouldbeindispensableforthehighactivityofHCHOoxidationatlowtemperature.

  • 标签: MESOPOROUS materials Co3O4 AG CO OXIDATION
  • 简介:采用溶胶-凝胶法制备了Mn离子摩尔掺杂比.32别为0,2%,4%,6%,8%的Ba(Ti1-xMnx)O3铁电薄膜。研究发现:当x为6%时,漏电流和矫顽场均达到最小,与未掺杂时相比,漏电流降低了约3个量级,矫顽场电场强度降低了约60%,P—E回线的矩形度增加。实验结果表明:通过适量掺杂Mn离子,可以改善BaTiO3铁电薄膜电学性能,提高铁电薄膜的极化,降低薄膜的漏电流。

  • 标签: 铁电薄膜 Ba(Ti1-xMnx)O3 掺杂 漏电流 电滞回线
  • 简介:Nanosheet(S)andnanoplate(P)γ-Al2O3weresynthesizedbysimplehydrothermalmethodsandemployedassupportsforNicatalystsinCO2methanation.BothofthenanostructuredNi/Al2O3catalystsdisplayedgoodactivity.Incomparison,theNi/Al2O3-ScatalystshowedhigherCO2conversionthantheNi/Al2O3-Pcounterpartatthereactiontemperaturerangingfrom250to400°C.ThephysicalandchemicalpropertiesofthecatalystsweresystematicallycharacterizedbyN2sorption,X-raydiffraction(XRD),highresolution-transmissionelectronmicroscopy(HR-TEM),hydrogentemperature-programmedreduction(H2-TPR)andCO2temperature-programmeddesorption(CO2-TPD)techniques.Higherspecificsurfaceareaandstrongermetal-supportinteractionswereconfirmedontheNi/Al2O3-Scatalyst,whichmayleadtosmallerparticlesizeofNinanoparticles.Moreover,theNi/Al2O3-Scatalystpossessedmoreabundantweakandmediumbasicsites,whichwouldbenefittheactivationofCO2.ThesmallerNisizeandmoresuitablebasicsitesmayrationalizethesuperioractivityoftheNi/Al2O3-Scatalyst.Besides,theNi/Al2O3-Scatalystexhibitedexcellentstabilityat325°Cfor40h.

  • 标签: ALUMINA Nickel Size Nano Interaction METHANATION
  • 简介:Thispaperdescribesanewmethodwhichhasbeendevelopedforthesolutionofdirectandinverseproblemsof3-Dcompressibleflowsinturbomachinery.Twotypesofstreamfunctionsarepropsedinthepaperandtheatreamfunction-coordinatesystemisappliedinnumericalcomputations,Thealgorithmisappliedtostatorbladesandtheresultsarecomparedwithexperimentaldata.Itisthownthatthecomparisonsareverysatisfactory.

  • 标签: 透平机 空气动力设计程序 空气热力学
  • 简介:Duringthepastyear,biophysicsgroupatInstituteofModernPhysics(IMP)obtainedlotsofachievementsintheresearchofheavy-ionmutationbreedingandproductionchainofsweetsorghum.Infundamentalresearchfield,amutantpopulationofArabidopsisthalianainducedbycarbonionbeamradiationwasestablishedinM2generation.Thetotalmutationratewas4.77%.Amutantmarked197#,whichhadfrostbite-like,palegreen,wrinkledandunevenleavesanddisplayedloosebractsandlatematuration,wasobtainedandreportedforthefirsttime.Generoughmappingresultsdemonstratedthatthereweretwomutationsitesinthe1stand4thchromosomeof197#mutant,indicatingheavyionradiationmightinducemorecomplicatedmutationsbeyondourcurrentrecognition.Thewholegenomeresequencingofthismutantisstillinprogress.Inaddition,high-yieldstrainsofmicrobeswhichhavepotentialvalueforcommercialapplication,suchasCorynebacteriumglutamicumandLacbobacillusthermophiles,werescreenedusingheavy-ionmutationtechnique.

  • 标签: PROGRESS MUTATION BREEDING
  • 简介:含FTO的闪光照相系统中,FTO是由一组同心球层组成的静态高密度客体,其动态量程高达4480。后锥的使用会大大降低系统的直散比DSR,并且散射空间分布的不均匀性也很严重。

  • 标签: 闪光照相系统 Monte-Carlo FTO 客体 直散比DSR 不均匀性
  • 简介:聚苯硫醚(PPS)以其高温稳定性、阻燃性、耐化学腐蚀性及良好的机械和电学性能受到关注,但PPS存在脆性大,韧性差的缺点。聚醚醚酮(PEEK)的耐热性是热塑性树脂中最优异的,还具有优异的综合力学性能、电性能等,但由于PEEK熔融温度(Tm=334℃)高,熔融黏度较大,给其成型加工带来困难。

  • 标签: 综合力学性能 聚苯硫醚 聚醚醚酮 共混体系 相容性 耐化学腐蚀性
  • 简介:Duetotheiruniqueadvantagesinphysicsandbiology,heavyionbeams,withhighmutationrateandwidemutationspectrum,havebeenwidelyusedinplantbreedingasanovelandefficientphysicalmutagen.Inthiswork,Arabidopsisthaliana(197#),whichdisplayeddecreasedfertility,wasinducedbycarbonionbeamsacceleratedbytheHeavyIonResearchFacilityinLanzhou(HIRFL).InordertodeterminethediscrepanciesbetweenWTandmutantplants,aseriesofdevelopmentindexeswereanalyzedduringthereproductivegrowthstage.

  • 标签: REPRODUCTIVE Analysis ARABIDOPSIS
  • 简介:Recently,bismuthsulfide(Bi2S3)hasattractedmuchattentioninthethermoelectriccommunityowingtoitsabundance,lowcost,andadvancedproperties.However,itspoorelectricaltransportpropertieshavepreventedBi2S3devicesfromrealizinghighthermoelectricperformance.Inthiswork,ourmotivationistodecreasethelargeelectricalresistivity,whichisrecognizedastheoriginofthelowZTvalueinundopedBi2S3.Wecombinedmeltingandsparkplasmasintering(SPS)inacontinuousfabricationprocesstoproduceBi2S3–xSex(x=0,0.09,0.15,0.21)andBi2S2.85–ySe0.15Cly(y=0.0015,0.0045,0.0075,0.015,0.03)samples.OurresultsshowthatSealloyingatSsitescannarrowthebandgapandactivateintrinsicelectronconduction,leadingtoahighpowerfactorof~2.0μW·cm–1·K–2atroomtemperatureinBi2S2.85S0.15,about100timeshigherthanthatofundopedBi2S3.Moreover,ourfurtherintroductionofClatomsintotheSsitesresultedinasecond-stageoptimizationofcarrierconcentrationandsimultaneouslyreducedthelatticethermalconductivity,whichcontributedtoahighZTvalueof~0.6at723KforBi2S2.835Se0.15Cl0.015.OurresultsindicatethathighthermoelectricperformancecouldberealizedinBi2S3withearth-abundantandlow-costelements.

  • 标签: THERMOELECTRIC BI2S3 CARRIER concentration LATTICE thermal
  • 简介:Rapidgrowthofmannedspaceflightresultsinmoreconcernabouthealthriskandanurgentneedofhealthassessmentinspacetravel.Sincetheimportanceofbrainfunctionstoastronauts,weexploredthelong-termeffectsandpotentialmechanismsof56Feionradiationonmicebrain.

  • 标签: COGNITIVE Function MOUSE BRAIN
  • 简介:Wehavestudiedthetwo-andthree-photonabsorption(2PAand3PA)propertiesofMn-dopedCsPbCl3twodimensionalnanoplatelets(2DNPs)andcubicnanocrystals.Comparedwiththeircubiccounterparts,theMn-doped2DNPsexhibitstrongerquantumconfinementeffectsthatcanmoreefficientlyenhancetheirdopantcarrierexchangeinteractionsandmultiphotonabsorption.Morespecifically,themaximumvolume-normalized2PAand3PAcrosssectionsofthe2DNPswere6.8and7.2timesgreaterthanthoseoftheircubiccounterparts,respectively,reachingupto1237GM∕nm3inthevisiblelightbandand2.24×10-78cm6·s2·photon-2∕nm3inthesecondbiologicalwindow,respectively.

  • 标签: Cl Mn SUPERIOR MULTIPHOTON CsPbCl3two-dimensional NANOPLATELETS
  • 简介:在模拟球面元件曲率半径的仿面形夹具上镀制了AlF3单层薄膜,并对不同口径位置上的薄膜进行了比较,以表征球面元件表面镀制薄膜的光学特性和微观结构。首先,采用紫外可见光分光光度计测量了不同口径位置上薄膜样品的透射和反射光谱,反演得出AlF3的折射率和消光系数。然后,使用原子力显微镜观察了样品的表面形貌和表面粗糙度。最后,使用X射线衍射仪对薄膜的内部结构进行了表征。实验结果表明:在球面不同位置镀制的AlF3单层薄膜样品的光学损耗随着所在位置口径的增大而增大。口径为280mm处的消光系数是中心位置处消光系数的1.8倍,表面粗糙度是中心位置的17.7倍。因此,球面元件需要考虑由蒸汽入射角不同带来的光学损耗的差异。

  • 标签: 热蒸发 AlF3薄膜 球面元件 微观结构特性
  • 简介:以呋咱环为基本结构单元可以构建多系列性能优异的新型呋咱含能衍生物,它们一般具有能量密度高,标准生成焓大,氮含量高以及分子热力学稳定性较好等优点。3-叠氮-4-氨基呋咱(AAF)作为合成三唑联呋咱、多叠氮基呋咱、呋咱醚、腈基呋咱等多类含能化合物的重要中间体,而且本身也是一个高能量密度化合物,因此探讨其合成方法具有一定的意义。3-叠氮-4-氨基呋咱的合成路线如图1所示,合成分为3步:第一步是乙二醛与盐酸羟胺在氢氧化钠溶液中发生加成缩合反应得N-氨基乙二肟(DAG)。该反应具有强放热性,实验操作应小心。

  • 标签: 合成方法 叠氮基 氨基 晶体结构 高能量密度化合物 呋咱含能衍生物