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简介：利用水热法制备了Cr3＋-Yb3＋-Er3＋共掺杂的NaYF4微管。在980nm的红外激光激发下，微管产生了强的可见上转换荧光。相比于Yb3＋-Er3＋共掺NaYF4微棒，微管的绿光和红光强度分别提高30倍及20倍。上转换荧光增强的原因被归结为Cr3＋掺入引起稀土离子周围晶体场对称性的减弱。对微管的生长过程及上转换发光机制进行了分析。

简介：摘要目的对上转换纳米颗粒进行表面修饰，以利于生物应用。方法利用热分解法合成NaYF4: Yb, Er粒子，然后采用微乳液法在粒子表面包覆一薄层SiO2，并在其表面修饰环氧基团，采用透射电子显微镜、荧光光谱仪和傅里叶红外光谱分析仪分别对颗粒形貌、发光特性和表面性能进行表征。结果采用热分解法合成了大小均一，六方相的NaYF4: Yb, Er颗粒，二氧化硅包覆纳米粒子后仍具有较强的发光特性，并进一步成功修饰上了环氧基团。结论上转换纳米粒子经过表面修饰后具有较强的发光特性和稳定性，可作为生物荧光标记物应用于生物医学领域。

简介：摘 要：本文采用水热法在高温高压条件下合成了β-NaYF4:3%Nd3+微米晶体，并通过改变反应物KF·2H2O的组分实现了对其形貌的调控。此外利用SEM、XRD及光谱测试等表征方法对不同形貌的β-NaYF4:3%Nd3+微晶的结构及发光特性进行了详细的研究。本实验研究对制备出形貌规则、发光强度高的稀土微纳米发光材料具有重要指导意义。

简介：具有上转换功能的纯相Yb3＋／Er3＋共掺杂β-NaYF4上转换微米管通过水热法在180％下反应24小时得到。为更好地利用太阳能并提高降解有机物的光催化效率，尝试将Ti02与NaYF4进行复合，形成Ti02／NaYF4复合材料来对Ti02纳米颗粒进行改性。我们研究了三种不同的复合方法，并对其在太阳光下进行光催化降解罗丹明水溶液的效率进行测试分析。结果表明，Ti02纳米颗粒紧密复合在NaYF微米管表面的复合材料具有相对其他两种合成方法更佳的催化活性，并且比无复合的纯Ti02纳米颗粒的催化效率提高了两倍。催化效率的提高可能是由于在两相进行复合时，在复合界面形成了异质结，该异质结有利于太阳光的吸收和催化效率的提高。

简介：Tobreakthroughthebottle-neckofquantumyieldinupconversion(UC)core-shellsystem,weelucidatedthattheenergytransferefficiencyincore-shellsystemhadanevidentcontributionfromthechargetransferofinterfacewithrelatedtotwofactors:(1)bandoffsetsand(2)bindingenergyareadensity.Thesetwovariablesweredeterminedbymaterialintrinsicpropertiesandcore-shellthicknessratio.Wefurtherunraveledthemechanismofnon-radiativeenergytransferbychargetransferinduceddipoleattheinterface,basedonaquasi-classicalderivationfromF?rstertyperesonantenergytransfer(FRET)model.Withstablebondingacrosstheinterface,thecontributionsonenergytransferinbothradiativeandnon-radiativeenergytransfershouldalsobeaccountedtogetherinAuzel'senergytransfer(ETU)modelincore-shellsystem.Basedonthediscussionaboutinterfacebonding,bandoffsets,andformationenergies,wefiguredoutthesignificanceofinterfacebondinginducedgapstates(IBIGS)thatplayedasignificantroleforinfluencingthechargetransferandradiativetypeenergytransfer.Theinterfacebandoffsetswereakeyfactorindominatingthenon-radiativeenergytransfer,whichwasalsocorrelatedtocore-shellthicknessratio.Wefoundthattheenergyareadensitywithrelatedtocore/shellthicknessratiofollowedthetrendofBoltzmansigmoidalgrowthfunction.Bythephysicaltrend,thisworkcontributedareferencehowthemulti-layeredcore-shellstructurewasformedstartingfromtheverybeginningwithinminimumsize.Aroutewaspavedtowardsasystematicstudyoftheinterfacetounveiltheenergytransfermechanismincore-shellsystems.

简介：ACe3+tion-dopedα-NaYF4singlecrystalofhighqualityisgrownsuccessfullybyanimprovedfluxBridgmanmethodundertheconditionsoftakingthechemicalrawcompositionofNaF:KF:YF3:CeF3inthemolarratioof30∶18∶48∶4,wheretheKFisshowntobeaneffectiveassistantflux.Thexraydiffraction,absorptionspectra,excitationspectra,andemissionspectraoftheCe3+t-dopedα-NaYF4singlecrystalaremeasuredtoinvestigatethephaseandopticalpropertiesofthesinglecrystals.TheabsorptionspectrumoftheCe3+t:α-NaYF4showsastrongbandthatpeaksatthewavelengthof300nm.TheemissionspectrumoftheCe3+t:α-NaYF4emitsanintenseultraviolet（UV）bandatthewavelengthof332nmundertheexcitationof300nmlight.Twoseparatedluminousbandsof330and350nm,whichcorrespondtothetransitions5d→2F25∕2and5d→F7∕2,canbeobtainedbyGaussfitting.ThestrongemissionintensityattheUVbandandtheexcellentopticaltransmissionintherangeofUVwavelengthsindicatethatCe3+t:α-NaYF4singlecrystalscanbeconsideredasapromisingmaterialforUVlasers.

简介：TheNaYF4:Yb,Ernanocrystalsweresynthesizedviathethermaldecompositionofmetaloleateprecursors.Thenanocrystalsinhexagonalstructurewerehighlyuniformandinsizeof25nm.Thebrightupconversionluminescencewasobservedundertheexcitationof980nmlaserandtheupconversionemissionspectrawereinvestigatedatdifferentpumppowers.Theemissionintensityratioofredlighttogreenlightlinearlyincreasedwithpumppowerincreasing.ThisresultindicatedthatthereexistedalargethresholdpowerofsaturationpumpforthefirstexcitationstateinNaYF4:Yb,Ernanocrystalscomparingtothatinbulkmaterial.

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简介：Dy3＋/Eu3＋共掺杂的立方格子NaYF4单晶在~Φ×1厘米大小为10厘米高质量的改进布里奇曼法用氟化钾（KF）作为助熔剂生长。射线衍射（X射线衍射），吸收光谱，激发光谱和发射光谱测量的晶体的相位和发光性能的晶体。分析了激发波长和Dy3＋和Eu3＋离子浓度对发光特性的影响。NaYF4单晶的掺杂摩尔浓度的1.205%和0.366%的Eu3＋，Dy3＋具有优良的白色发光的色度坐标x=0.321，y=0.332。这表明Dy3＋/Eu3＋共掺的立方格子NaYF4单晶可以潜在的发光材料的紫外（UV）光激发的白光发光二极管（LED）。

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简介：Weexperimentallydemonstratedadiode-pumpedKerr-lensmode-lockedfemtosecondlaserwithaYb:CaYAlO4crystalasthegainmedium.Pulsedurationasshortas33fswasobtaineddirectlyfromtheoscillatoratarepetitionrateof115MHz.Thecentralwavelengthwasat1059nmwithaspectralbandwidthof49nm.Theseare,tothebestofourknowledge,theshortestpulsesgeneratedfromaYb:CaYAlO4oscillator.

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简介：Anewmethodfordeterminingthepartialmeltingdepthofmantle-derivedmagmaandlithosphericthicknessincontinentalregionsisderivedfromREEgeochemistry.ThiseffectivetechniqueusesvariationsintheCe/YbandSm/YbratiosfoundinmainlyvolcanicrocksincontinentalChina.TheratioschangewiththedepthoforiginconsistentwiththecorrelationbetweenlithosphericthicknessandtheCe/YbandSm/Ybratiosfoundinoceanicbasalt.Theseratiosincreaseexponentiallywiththedepthoforigin,thelithosphericthickness,ofawidevarietyofCenozoicvolcanicbasaltandPaleozoickimberliteintheNorthChinaCraton,northeasternChinacontinentandvicinity.Thisfunctionalrelationshipwithdepthisshowninaplotoftheratiosthatformsaconcordiacurve,whichiscloselyexpressedbyformulasusing8-degreepolynomials.Theseprovideamoreaccurategageinmeasuringthelithosphericthicknessthanthetraditionalgeophysicalmethods.Whenappliedtovolcanicrockofdifferentagesitalsorevealshowthethicknesshaschangedovertimeandthus,greatlyaidstheunderstandingofthetectonichistory.RelationsbetweentheCO2content,mineralreactionsandpressureintheupperasthenospherebeneaththebaseofthelithosphereappearstoaffecttheproportionsofREEinpartialmeltsandbringsaboutaclosecorrelationbetweenlithosphericthicknessandtheCe/YbandSm/Ybratiosinmantle-derivedmagmaticrock.Thisthicknessgauge,forbothcontinentalandoceaniclithosphere,providesanewapproachinanalyzingthelithosphericthicknessindifferenttectonicsettingsandgeologictimes.

简介：Er3+-Tm3+-Yb3+tri-dopedBaMoO4phosphorsweresynthesizedbyco-precipitationtechniqueandcharacterizedbyX-raydiffractionanalysis,absorptionstudyandfieldemissionscanningelectronmicroscopyanalysis.Upconversionaswellasdownconversionluminescencestudieswereperformedbyusingnearinfrared（980nm）andultraviolet（380nm）excitations.Energyleveldiagram,pumppowerdependenceandcolourcoordinatestudywereutilizedtodescribethemulticolorupconversionemissionproperties.Undersingle980nmdiodelaserexcitationthedualmodesensingbehaviourisrealizedviaStarksublevelsandthermallycoupledenergylevelsoftheTm3+andEr3+ionsinthepreparedtri-dopedphosphors.AcomparativefluorescenceintensityratioanalysisforintegratedemissionintensitiesarisingfromtheStarksublevels{1G4（a）and1G4（b）}andthermallycoupledenergylevels{2H11/2and4S3/2}oftheTm3+andEr3+ions,respectivelywascarriedoutinthepreparedtri-dopedBaMoO4phosphors.ThemaximumsensitivityforthermallycoupledenergylevelsoftheEr3+andStarksublevelsoftheTm3+ionwasreported.Thedevelopedphosphorscouldbeusefulinthedisplaydevicesandopticalthermometricapplications.

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简介：Inthispaper,Er/Ybco-dopedfiberamplifiers(EYDFAs)withanYb-bandfiberBragggrating(FBG)atthepumpendtoimprovetheperformanceoftheamplifierissystematicallystudied.TheinfluenceofthereflectivityandcenterwavelengthoftheFBGalongwiththegain-fiberlengthontheperformanceofanEYDFAarenumericallyanalyzed.TheresultsshowthatthewavelengthoftheFBGhascriticalinfluenceontheefficiencyoftheEYDFA,whereastherequirementtoitsreflectivityisrelaxed.Itisaneffectiveandpromisingwaytoimprovetheefficiencyofahigh-powerpumpedEYDFAbyintroducingasuitableYb-bandFBGatthepumpend.Basedontheanalysisoftheunderlyingprinciples,suggestionsforthepracticaldesignandpossiblefurtherimprovementstrategiesarealsoproposed.

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