简介:EffectofLa-richrareearthoneutecticmicrostructureinA1-2%Fealloywasstudied.WhentheadditionofREissmall,a-A1phaseisintheformofcellulardendrite.WiththeincreaseoftheadditionofRE,thenucleationandgrowthofa-A1dendritearesuppressed,andeutecticAl3Fephaseisrefined.WhentheadditionofREgetsto0.6%(massfrac-tion),thesizeofeutecticAl3Feincreases.Inaddi-tion,mechanismoftheeffectofmixedREoneutecticmorphologyofA1-2%Fealloyisexplored.
简介:EffectofMnsubstitutionforFeincubicLavesZr0.1Tb0.9(Fe1-xMnx)2andY0.1Tb0.9(Fe1-xMnx)2com-poundsispresented.Similarresultsinbothsystemsareobtained:ThestructureandthemagnetismofTbFe2arebothinfluencedslightlybyasmallamountofYorZrsubstitutionforTb;Withincreasingxvalue,thelatticeconstantincreasesmonotonously;theCurietemperaturedecreaseslinearly;whilesaturationmagnetizationincreaseslinearly.ForthesmallamountofMnsubstitutionforFeinbothsystems,magnetostrictionissignificantlylargerthanthatinthepureironalloys.Thelargestmagnetostrictionof|γ‖-|γ|=2200×10-6atmagneticfieldof2×107/4πA/misobtainedforY0.1Tb0.9(Fe0.95Mn0.052.
简介:1-(2-chlorophenyl)ethanol(CPE)isofhealthandenvironmentalconcernduetoitstoxicityanditsuseasaninter-mediateinpharmaceuticalmanufacturing.ThecurrentworkdealswiththecatalyticreductivedechlorinationanddetoxificationofCPEbyPd/Febimetal.CPEwaseffectivelydechlorinatedto1-phenylethanol(PE)accompaniedbytheequivalentreleaseofchloride.TheextentofCPEdechlorinationincreasedwithtemperature,FedosageandPdloading.AdecreaseinsolutionpHincreasedCPEdechlorination,resultingpresumablyfromanincreaseinhydrogenproduction.Underthespecificconditionsof20g/LPd/Fe,0.10%Pd(w/w)andinitialpH5-6,theCPEdechlorinationwascompletedwithin145min.Thedechlorinationfol-lowedapseudo-first-orderkineticswithanactivationenergyof56.7kJ/mol.TheresultsoftoxicitytestingshowedthatCPEwasverytoxictoChlorella,whereasPEshowedlittletoxicity.Thetoxicityofthereactionsolutiondeclinedgraduallyandthepro-motingeffectsonChlorellaintensifiedconsequentlywiththedechlorinationprocess.Thus,thereductivedechlorinationofCPEtoPEbyPd/Fewasadetoxificationprocess.ItmaybeusedtoeffectivelyreducethetoxicologicaleffectsofCPE-contaminatedwastewater,therebyenhancingtheperformanceofsubsequentbiologicalprocessesinwastewatertreatment.
简介:TheeffectsofheattreatmentsonthephasetransformationbehaviorofTi49Ni49.5Fe1V0.5andTi48Ni48.5Fe1V2.5alloyswereinvestigated.TheresultsindicatethatthealloyssubjectedtodifferentheattreatmentshaveB2structureatroomtemperature.AllthespecimensexhibitatwostageB2→R→B190martensitictransformationoncooling,butaB190→B2one-stagereversemartensitictransformationonheatingexceptagedA1alloy,whichundergoesanabnormaltwo-stagetransformationuponheating.ThephasetransformationtemperaturesareaffectedbyheattreatmentsandVcontent,whichcanbeattributedtothevariationofthesecond-phaseparticlescontentinthematrix.
简介:
简介:【摘要】通过对13-4-1#矿体1#采场1665分段3#联道四支进路和1670分段2#凿平四支进路房柱嗣后充填采矿法的分析,结合矿石运输方向、搬运设备等因素,采用房柱嗣后充填采矿法可以提高矿石回采率,降低采矿成本,控制地压,使主要运输巷道不受下部矿体回采施工的影响,保证施工安全并取得较好的经济效益。
简介:摘要: 随着大红山的快速生产建设,I3、I2矿体资源的大量消耗,为了确保矿山生产持续,当时因经济技术条件影响没有纳入回采规划和相对矿体薄、小、连续性差,品位低、构造发育的I1矿体,已经是大红山的主要开采对象,但是根据现有的地质综合资料,在对I1矿体开采中通过地质编录取样,发现揭露的断层与地质资料上的断层在位置上发生位移、偏差和在地质资料上没有综合的断层,这样使矿体发生了变薄、变贫和尖灭。导致在规划设计和盘区建设过程中,没有起到指导的依据。所以要重新收集地质勘查、生产过程中全部地质资料,把现有综合的断层和揭露新增的断层进行对比和分析,根据断层的性质、产状、延伸方向、破坏作用重新综合研究,最终综合到地质平、剖面图中,提交一套完整地质资料。
简介:TheballmillingofFe-24MnandFe-24Mn-6Simixedpowdershasbeenperformedbythehighenergyballmillingtechnique.ByemployingX-raydiffractionandMoessbauermeasurements.Theccmpositionevolutionduringthemillingprocesshasbeeninvestigated.TheresultsindicatetheformationofparamagneticFe-MnorFe-Mn-Sialloyswithametastablefccphaseasfinalproducts.whichimplythattheFeandMnproceedaco-diffusionmeenanismthroughthesurfaceoffragmentedpowders.Thethermalstabilityandcompositionevolutionoftheas-milledalloyswerediscussedcomparingwiththebulkalloy,.
简介:FenanowirearraywithstrongshapeanisotropywasemployedasthesoftphaseinNd-Fe-Bbasednanocomposites.TheeffectsoftheFenanowiredistributiononmagneticpropertiesofthenanocompositeswereinvestigatedbymicromagneticsimulation.TheresultsindicatethattheshapeanisotropyofFewiresaddedinthesamedirectionastheuniaxialmagnetocrystallineanisotropyofthehardphasecannotincreasethecoercivityofthenanocomposite.Whenthenanowiresaredistributedperpendiculartotheeasyaxisofthehardphase,theshapeanisotropyofsoftphasecanretardthemomentsfromrotatingtothefullreverseddirection,leadingtoenhancedcoercivity.Inaddition,withincreasingthenanowirediameter,thecoercivityofthenanocompositedecreases,butthedipolarinteractionshowsdifferentrolesinmagneticreversalofnanocompositefordifferentdistributionsofnanowires.ThecurrentresultssuggestthatthecoercivityoftheNd2Fe14B/α-Fenanocompositecanbeenhancedbyintroducingthesoftmagneticnanowirearraywiththediameterlessthantheexchangelengthandwiththelongaxisalongthedirectionotherthantheeasyaxisofhardphase.
简介:EllipticPDE-constrainedoptimalcontrolproblemswithL^1-controlcost(L^1-EOCP)areconsidered.TosolveL^1-EOCP,theprimal-dualactiveset(PDAS)method,whichisaspecialsemismoothNewton(SSN)method,usedtobeapriority.However,ingeneralsolvingNewtonequationsisexpensive.Motivatedbythesuccessofalternatingdirectionmethodofmultipliers(ADMM),weconsiderextendingtheADMMtoL^1-EOCP.TodiscretizeL^1-EOCP,thepiecewiselinearfiniteelement(FE)isconsidered.However,differentfromthefinitedimensionalL^1-norm,thediscretizedL^1-normdoesnothaveadecoupledform.Toovercomethisdifficulty,aneffectiveapproachisutilizingnodalquadratureformulastoapproximatelydiscretizetheL^1-normandL^2-norm.Itisprovedthattheseapproximationstepswillnotchangetheorderoferrorestimates.Tosolvethediscretizedproblem,aninexactheterogeneousADMM(ihADMM)isproposed.DifferentfromtheclassicalADMM,theihADMMadoptstwodifferentweightedinnerproductstodefinetheaugmentedLagrangianfunctionintwosubproblems,respectively.Benefitingfromsuchdifferentweightedtechniques,twosubproblemsofihADMMcanbeefficientlyimplemented.Furthermore,theoreticalresultsontheglobalconvergenceaswellastheiterationcomplexityresultso(1/k)forihADMMaregiven.Inordertoobtainmoreaccuratesolution,atwo-phasestrategyisalsopresented,inwhichtheprimal-dualactiveset(PDAS)methodisusedasapostprocessoroftheihADMM.Numericalresultsnotonlyconfirmerrorestimates,butalsoshowthattheihADMMandthetwo-phasestrategyarehighlyefficient.
简介:BulknanocrystallineSmCo6FesinteredmagnetwaspreparedbySparkPlasmaSinteringtechnique(SPS).XRDpatternsshowthatthemagnetexhibitsastableTbCu7structure.TEMobservationindicatesthatthemicrostructureofthemagnetiscomposedofSmCo6Fesinglephasegrainswithanaveragegrainsizeof30nm.Magneticmeasurementshowsthatunder9Tmagneticfield,thecoercivityofthemagnetreaches1.12T;thesaturationmagnetizationandtheremanenceare1.13and0.67T,respectively.Themagnethasa(BH)maxof75.6kJ·cm-3.
简介: