简介:Anewtwo-dimensionalstructuremodulationalongc-andb-axeshasbeendiscoveredinsuperconductingsinglecrystalsofBi2.13Sr1.87CuO6+δ(Bi2201)byx-rayscattering.Suchmodulationstructuredoesnotexistinnon-superconductingBi2201singlecrystals.Butinsteadlatticedistortionsareobservedinthea-b-plane.Thisphenomenonmayindicatethatbothstrainrelaxationandchargemodulationinthea-b-planeareimportanttotheoccurrenceofsuperconductivityinthecopperoxides.
简介:研究了FeMn/Co多层膜界面插入Bi前后微结构的变化。利用磁控溅射法制备了FeMn/Co多层膜,利用X射线小角反射和漫散射技术进行了表征,得到结果如下:插入Bi之前,在FeMn/Co界面处确实存在FeMnCo的成分混合存在,插入Bi之后,FeMnCo的成分中掺入了Bi。而且,在FeMn/Co界面处Fe,Mn,和Co的元素分布不相同。
简介:Wesynthesized(Pb,Cd)Sr2(Y,Ca)Cu2O7+x,phasesuperconductor.AftersubstitutionofPbwithBi,theBiCd1212phaseshowsnosuperconductivity.AlthoughpreviousEXAFSstudyhasshownthelocalstructureenvironmentoftheCuissimilarinbothcompounds,EXAFSresultsofBiandPbheredemonstratethatσ2ofPb-Oin-planeislargerthanthatofBi-Oinplane,whereasσ^2ofPb-OapicalissmallerthanthatofBi-O,wheraseσ^2ofPb-OapicalissmallerthanthatofBi-Oapical.TheSrshellfeaturesarealsodiffernet,itappearedthatsuperconductivityneedssomedisorder.incarrierreservoirlayer,whichisduetothesubstitutionaldefectcausedbydifferentionicradii.
简介:通过原位下的高压同步辐射X光衍射技术,对具有钙钛矿结构的La0.4Bi0.1Ca0.5MnO3中存在的Jahn-Teller畸变,进行了研究。实验表明在压力的作用下,样品中的畸变有所减小,超于理想的立方结构,并且在1.4GPa左右存在一个过渡相。
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