简介:ToseparatethecadmiumandnickelresourcesinwasteNi-Cdbatteries,aself-designedvacuumdistillationrecyclingsystemwasstudiedunderlaboratoryconditions.Theeffectsofsystemtemperature,operatingpressure,andtimeontheseparationofNiandCdwerestudiedrespectively.Themechanismofvacuumthermalrecyclingwasalsodiscussed.ResultsshowthatvacuumdistillationisaveryeffectiveseparationmethodforwasteNi-Cdbatteries.AtaConstantpressure,theincreaseoftemperaturecanimprovetheseparatingefficiencyofCd.Whenthetemperatureis1173K,Cadmiumcanevaporatecompletelyfromthesamplesduring3hat10Pa,ThereductionofpressureinacertainrangeiseffectivetotheseparatingofCdfromNi-Cdbatteriesbyvacuumdistillation.
简介:AZ31镁合金的团结的微观结构上的一个搏动的磁场的效果被调查。当搏动的磁场被用于AZ31合金的团结时,试验性的结果证明显著微结构精炼被完成。AZ31合金的当演员组微观结构的平均谷物尺寸被精制到107m。由熄灭AZ31合金,不同主要-Mg微观结构在团结的功课期间被保存。微观结构进化表明主要-Mg与搏动的磁场在球状的形状产生并且成长,有没有搏动的磁场的树枝状的形状的对比。搏动的磁场原因在团结期间融化传送对流,它做全部的温度融化一致,并且在液体/固体接口前面生产一个undercooling地区,它使成核率增加并且禁止的大树突。另外,在melt导致的朱尔热效果也加强谷物精炼效果和树突手臂的spheroidization。
简介:Automaticgastungstenarc(GTA)weldinghasbeenutilizedtoconnectAZ31magnesiumalloybuttedplateswithAZ61andAZ61-1.0Sbfillerwire.ContrastedtoAZ61fillerwire,theAZ61-1.0Sbfillerwireholdsacomponentof1wt%antimony(Sb).Inthepresentwork,properweldingtechnologyparaneterswereexplored.AndthemicrostructureandperformanceofweldedjointswereanalyzedtoresearchtheinfluenceofSbonmagnesiumalloyweldedjoint.Observedfromthemicrostructureofweldedjoint,additionofSbhasrefinedcrystalgrainsandchangedthepatternofeutecticinbeadandheataffectedzone(HAZ)adjacenttobeadfromdiscontinuousreticulartograininessstructure,whichstrengthentheweaknessofjoint.Inaddition,becauseoftheanchoringactionofMg3Sb2phasesaswellashamperingactiontocrystalboundaryslip,theperformanceofjointweldedbyAZ61-1.0Sbfillerwirehasbeenimproved.
简介:Africtionstirringweldingtojoint5mmrolledAZ31magnesiumhadbeendeveloped.Themicrostructuresinvariousregionsincludingtheweldnugget,thermo-mechanicallyaffectedzone(TMAZ)andheataffectedzone(HAZ)wereinvestigatedandcomparedwithunaffectedparentmetalusingopticalmicroscopy.Theresultsshowedthattheheatandmechanicalprocesshadgreateffectonthemicrostructureevolution.Inweldnugget,theheatwasenoughtoproducesufficientsuperplasticmaterialflowandthemechanicaleffectwasgreatest,andthedynamicrecrystallizationwascompletedthoroughly.InTMAZ,themechanicaleffectwasindirectlyaffectedbytheweldingtoolandonlysomegrainshadundergonedynamicrecrystallization.Thevariousregionswerestudiedindetailtobetterunderstandthemicrostructuralevolutionduringfrictionstirringwelding(FSW).Thecrosssectionnearthe'keyhole'showedclearonionringsbecausethematerialwasstirredonlybytherotationoftheprobeandmaterialsrotatedwiththeprobeanddidnotmovealongweldingdirectionandinverticaldirection,therewasnomaterialflowandtheflowmovementcanberegardedastwodimensionallayerflow.
简介:AmorphousNi–PcoatingwasplatedonAZ31magnesiumalloyviatheelectrolessplatingtechnique,andtheplatedalloywassubsequentlyannealed.X-raydiffraction(XRD),scanningelectronmicroscopy(SEM),energydispersivespectroscopy(EDS),anddifferentialscanningcalorimetry(DSC)wereusedtocharacterizethecoating.Theresultsshowthatthehardnessofthecoatingismuchhigherthanthatofbaremagnesiumalloy,whichfurtherincreasesaftercrystallization.Theelectrochemicalpolarizationandsaltspraytestsshowthatthecoatingexhibitsamuchhighercorrosionresistancethanthatofthebaremagnesiumalloy.Moreover,thecrystallizedcoatingstillexhibitsamuchstrongercorrosionresistancethanthatofthebaremagnesiumalloy,althoughitscorrosionresistanceislowerthanthatoftheas-platedone.
简介:由于人们对锻造镁合金兴趣的增加,所以对锻造镁合金的成形性能进行研究。研究应用了连续铸造再挤压成形的AZ31和AZ80镁合金坯料。由室温下的压缩试验测得所研究坯料的力学性能,还测试了不同热处理的试样。此外,测得了在300~450℃、应变速率ε为1s^-1的条件下单轴平面应变镦粗试验时的真实应力曲线。不同热体积成形条件下试样的真实应力曲线与微观组织的定量分析结果有关。为了确定所应用镁合金的成形性能,采用等温模具进行了体积成形试验。试验用液压锻造压力机的滑块速度为1~40mm/s。所使用的两种镁合金均可生产出形状简单的典型锻件。
简介:镁合金在工业有大量应用;然而,他们的腐蚀电阻,穿电阻,和坚硬是相当差的,它限制他们的应用。Ti离子被金属蒸汽真空弧(MEVVA)植入进AZ31镁合金表面implanter。这金属弧离子来源有一根宽广横梁和高当前的能力。Theimplantation精力在45keV被修理,剂量在9x10~(17)cm~(-2)。通过离子培植,有在厚度的约900nm的Ti离子培植层直接在AZ31镁合金,它的表面性质极大地由改善了的表面上被形成。化学药品一些声明离子培植层的典型元素借助于X-rayphotoelectron光谱学(XPS)被分析,当离子培植层和阶段结构的生气部分形态学借助于扫描电子显微镜学(SEM)和X-raydiffraction(XRD)被观察时。Ti离子的腐蚀电阻的性质植入层被CS300P电气化学腐蚀工作站在3.5%NaCl答案学习。结果证明腐蚀电阻的性质显著地被提高,当腐蚀速度显然被减慢时。
简介:ThefatiguepropertyofAZ31magnesiumalloyanditsTIGweldedjointswereinvestigated.Theultrasonicpeeningtreatment(UPT)wasusedtoimprovethefatiguepropertyoftheTIGweldedjoints,whichwastreatedattheweldtoebytheUPTprocess.ThetestresultsshowthatthefatiguestrengthofthebasemetalofAZ31magnesiumalloysis57.8MPa,andthoseofthefilletjointandthetransversecrossjointarerespectively20.0MPaand17.2MPaat2×106cycles.ThefatiguestrengthsoftwokindsofweldedjointstreatedbytheUPTarerespectively30.3MPaand24.7MPa,whichhavebeenimprovedby51.5%and43.6%,respectively.Thefatiguelifeofthefilletjointspecimensisprolongedbyabout2.74timesandthefatiguelifeofthetransversecrossjointspecimensisprolongedbyabout1.05timeswhenthestressrangeisat40.0MPa.
简介:SolderingofLD31aluminumalloysusingSn-PbsolderpasteafterelectricbrushplatingNiandCucoatingswasnvestigated.ThetechnologyofelectricbrushplatingNiandCuwasstudiedandplatingsolutionwasdeveloped.Themicrostructureofthecoatings,solderedjointandfracturefacewereanalyzedusingopticmicroscopy,SEMandEDX.Theshearstrengthofsolderedjointcouldreachashighas26.83MPa.Theresultsshowedthatreliablesolderedjointcouldbeobtainedat230℃,theadhesionofcoatingsandLD31aluminumalloysubstratewashighenoughtobearthethermalprocessinthesoldering.
简介:通过单向拉伸试验研究镁合金AZ31B的电塑性效应。为了显示脉冲电流的非热效应,在相同温度下开展两类试验:环境箱中的单向拉伸试验和脉冲电流辅助的单向拉伸试验。此外,对脉冲电流在材料变形过程中引起的温度场进行数值模拟。结果表明,沿材料截面方向温度分布均匀。通过对比两类单向拉伸试验的真应力-真应变曲线,证实了脉冲电流非热效应的存在。通过光学显微镜研究脉冲电流对材料微观组织演化的影响,结果表明:脉冲电流引起的动态再结晶对流动应力的下降起重要作用。最后,提出一个考虑电塑性响应的AZ31B流动应力模型,并通过实验进行验证。结果表明:模型预测结果和实验结果吻合较好。
简介:LaserweldingwithfillerwireofAZ31magnesiumalloysisinvestigatedusingaCO2laserexperimentalsystem.Theeffectofthreedifferentfillerwiresonthejointpropertiesisresearched.Theresultsshowthattheweldappearancecanbeeffectivelyimprovedwhenusinglaserweldingwithfillerwire.ThemicrohardnessandtensilestrengthofjointsarealmostthesameasthoseofthebasemetalwhenERAZ31orERAZ61wireisadopted.However,whenthefillerwireofER5356aluminumalloyisused,themechanicalpropertiesofjointsbecomeworse.ForERAZ31andERAZ61fillerwires,themicrostructureofweldzoneshowssmalldendritegrains.Incomparison,forER5356fillerwire,theweldshowsastructureofsnowydendritesandmanyintermetalliccompoundsandeutecticphasesdistributeinthedendrites.Theseintermetallicconstituentswithlowmeltingpointincreasethetendencyofhotcrackandresultinfragilejointproperties.Therefore,ERAZ31andERAZ61wirearemoresuitablefillermaterialthanER5356forCO2laserweldingofAZ31magnesiumalloys.