简介:Thecreepmechanismofas-castMg-6Al-6Ndalloywasstudied.Thestressexponentforcreepis5.8undertheappliedstressesof50-70MPaat175°C.Theactivationenergyforcreepis189kJ·mol-1undertheappliedstressof70MPaintherangeof150-200°C.Thetruestressexponentandthresholdstressforcreeparecalculatedas4.96and10.2MPa,respectively.Thetruestressexponentindicatesthatitscreepmechanismbelongstothedislocationclimb-controlledcreep,whichisinagreementwiththemicrostructurechangesbeforeandaftercreep.ThehighvalueforstressexponentisattributedtotheinteractionofAl11Nd3phasewithdislocations.Theactivationenergyismorethantheself-diffusionactivationenergyofMg,whichisattributedtotheloadtransfertakingplacefromthematrixtoAl11Nd3phaseduringcreep.
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简介:macroporous的吸着性质为La3+离子的弱酸树脂(D113)被化学分析和红外系列学习。试验性的结果显示D113树脂在pH=为La3+有一个好吸附能力6.0在HAc-NaAc媒介。静态地浸透的吸附能力是273.3mg/g。La3+/Ce3+,La3+/Gd3+,La3+/Er3+,和La3+/Y3+的分离系数分别地是2.29,3.64,4.27,和0.627。吸附的明显的激活精力,Ea是吸着的18.4kJ/mol,热力学参数H,S,和G是4.53kJ/mol,61.8J/(mol.K),?13.9kJ/mol分别地。为La3+的D113的吸附行为服从Freundlich等温线。在树脂上吸附的La3+能是由2.0mol/LHCl份量上的eluted。
简介:Arheo-diecastingprocess(RDC)wasinvestigatedforsemisolidprocessingofanAZ91Dmagnesiumalloy.TheresultsoftheRDCsamplesinas-caststateindicatethatthemicrostructureofprimaryα-Mgparticleshasafinesize,nearlysphericalmorphology,anduniformdistributionthroughoutthecomponents.Duetotheadvancedmicrostructureandreducedlevelofdefects,theRDCAZ91DMgalloyexhibitsanapparentimprovementinmechanicalproperties.Thequantitativemetallographicinvestigationsrevealthatincreasingtheintensityofforcedconvectionduringtheslurrypreparationresultsinapromotednucleationandreducedvolumefractionoftheprimaryphasesolidifiedintheslurrymaker.
简介:为描述铁粉末的压缩过程的一个新模型基于连续统假设和椭圆的收益标准被建议。模仿densification行为,组成的模型在马克被实现计算机节目。为在负担和排水量之间的关系,不同模型被比较,在组成的方程的参数的影响借助于模拟和实验是坚定的。balancer的密度分发被测量并且模仿。参数采用了的结果表演为负担排水量曲线起一个修正作用,并且与另外的模型相比,现在的模型主要由于不同参数A和B在压缩进程的以后的阶段与试验性的数据更好适合。接触表面上的磨擦在细工品的大变丑下面贡献不同类的密度分发。在模拟和试验性的数据之间的比较显示这个模型能被用来精确并且有效地预言粉末协议过程。