简介:TheextractionofCe(Ⅳ)inH2SO4/H3PO4systemwasinvestigatedsystematicallyusingbifunctionalionicliquidextractants(Bif-ILES)[A336][P507],[A336][P204]and[A336][C272]inn-heptane.TheeffectsofH2SO4concentration,extractantconcentrationandsalting-outagentconcentrationwereobservedindetail.TheextractionmechanismofCe(Ⅳ)inH2SO4/H3PO4systemwasobtained.ThecomparisonwithotherextractantssuchasCyanex923,TBPwasalsostudied.Thermodynamicfunctionsoftheextractionreactionwerecalculated,showingthattheextractionwasanexothermicprocess.TheseparationofCe(Ⅳ)fromRE(Ⅲ)andTh(Ⅳ)wasalsoinvestigated.TheresultindicatedthatCe(Ⅳ)couldbeselectivelyextractedinthissystem.CePO4nanoparticleswereobtainedintheprocessofstrippingusingH2O2inH2SO4/H3PO4system.X-raydiffraction(XRD),scanningelectronmicroscopy(SEM)andspectroscopywereadoptedforthecharacterizationofthesample.
简介:ThisstudyresearchestheeffectsoftherefiningtreatmentonthemicrostructureandthemechanicalpropertiesofH13mandrelsteelandcomparestheseeffectswiththoseoftheconventionaltreatment.Theresultsindicatethatbothcarbideparticlesandgrainswererefined,carbideparticleswereuniformlydistributedbytherefiningtreatment,andtherefore,thestrengthandtoughnessofH13mandrelsteelwereimproved.Rapidcoolingafterthesolutiontreatmentmayinhibitintra-granularprecipitationofcarbideparticles,whichisfavorabletoenhancingtoughness.Consequently,high-performanceH13mandrelsteelcanbeproducedbyproperrefiningtreatment.
简介:本文介绍了多功能电能表遵循的DL/T645—1997通讯协议与各指令,利用VB6.0的MSComm控件进行串行通讯并把采集到的数据导入数据库并进行查询数据库程序的设计。该通讯程序能采集到所有遵循国家标准(DL/T645—1997)的多功能电度表数据。