简介:Moleculardynamicssimulationswereperformedtostudytheinteractionbetweenatomichydrogenandsiliconcarbide.Inthepresentstudy,wefocusontheeffectofthesurfacetemperatureonHinteractingwithsiliconcarbide.ThesimulationresultsshowthattheretentionofHatomsinthesampledecreaseslinearlywithincreasingsurfacetemperature.ThedepthprofileanalysisshowsthatthesampleismodifiedbyHbombardment,andthedensityofHatomsisgreaterthanthoseofSiandCatomsneartheinterfaceregionbetweentheH-containingregionandthebulk.However,nearthesurfaceregionthedensitiesofH,SiandCatomsarealmostequivalent.Inthemodifiedlayer,thebondsconsistofSi-CandSi-HandC-H.ThefractionofSi-Cbondsisthegreatest.OnlyafewC-Hbondsarepresent.
简介:Geepilayersofdifferentthicknessesaregrownbymolecular-beamepitaxywithSbasasurfactantonSI(100)substrates,X-raydiffractionillustratesthattheseGethinfilmsarepartiallystrained.andthestrainsdecreasegraduallywithincreasingepilayerthickness,RamanspectrarevealadownwardshiftoftheGe-Gemodepeakastheepilayerthicknessincreases.Intheregionsofhighstrain,therelationshipbetweentheRamanshiftofthismodeandthestraininthepartiallyrelaxedsamplesisconsiderablydifferentfromthelinearrelationshipreportedbefore,whichismainlyattributedtothespatialconfinementeffectofphononsinananocrystal.
简介:本文利用XAFS方法研究机械合金化方法制备的Fe100-xCux(x=0,10,20,40,60,70,80,100,x为原子百分比)合金中Fe、Cu原子的局域环境结构随组成的变化。对于Fe100-xCux二元混合物,当x≥40时,Fe原子的近邻配位结构从bcc转变为fcc,但Cu原子的近邻结构保持其fcc不变;与之相反,当x≤20时,Fe原子的近邻配位保持bcc结构而Cu原子的近邻配位结构从fcc转变为bcc结构。XAFS结果还表明fcc结构的Fe100-xCux中Fe的无序因子σ(0.009A)比bcc结构的Fe100-xCux中的σ(0.081A)大得多;并且在同一机械合金化Fe100-xCux(x≥40)样品中Fe原子的σ(0.099A)比Cu原子的σ(0.089A)大。这表明机械合金化的Fe100-xCux样品中Fe和Cu原子可以有相同的局域结构环境但不是均匀的过饱和固溶体,而是fcc或bcc合金相同时存在Fe富集区和Cu富集区。
简介:Alargediamondcrystalupto500μmindiameterwithasmooth(100)facetatitstophasbeensynthesizedonMosubstratethroughmicrowaveplasmachemicalvapordeposition(MPCVD).Itsmorphologyandqualitywerecharacterizedbyscanningelectronmicroscopy(SEM),andthegrowthmechanismwasroughlyillustratedfrombothmacroscopicandmicroscopicviewpoints.Itwasfoundthatmorphologicalinstabilitiesareamajorfactorresultinginsynthesisoflargediamondcrystals,moreover,highmicrowavepowerdensity(MPD),highCH4concentrations,highpressure,highsubstratesurfacetemperatureandtheadditionofasmallamountofO2werealsonecessaryforthesynthesisoflargediamondcrystals.
简介:Neutralbeaminjection(NBI)isrecognizedasoneofthemosteffectivemeansforplasmaheating.A100slongpulseneutralbeamwith30keVbeamenergy,10Abeamcurrentanda100slongpulsemodulatingneutralbeamwith50keVbeamenergy,16AbeamcurrentwereachievedintheEASTneutralbeaminjectoronthetest-stand.ThepreliminaryresultssuggestthatEAST-NBIsysteminitiallypossesstheabilityoflongpulsebeamextraction.
简介:StationarylongpulseplasmaofhighelectrontemperaturewasproducedonEASTforthefirsttimethroughanintegratedcontrolofplasmashape,divertorheatflux,particleexhaust,wallconditioning,impuritymanagement,andthecouplingofmultipleheatingandcurrentdrivepower.Adischargewithalowersinglenulldivertorconfigurationwasmaintainedfor103sataplasmacurrentof0.4MA,q95≈7.0,apeakelectrontemperatureof>4.5keV,andacentraldensityne(0)2.5×1019m-3.Theplasmacurrentwasnearlynon-inductive(Vloop<0.05V,poloidalbeta0.9)drivenbyacombinationof0.6MWlowerhybridwaveat2.45GHz,1.4MWlowerhybridwaveat4.6GHz,0.5MWelectroncyclotronheatingat140GHz,and0.4MWmodulatedneutraldeuteriumbeaminjectedat60kV.Thisprogressdemonstratedstrongsynergyofelectroncyclotronandlowerhybridelectronheating,currentdrive,andenergyconfinementofstationaryplasmaonEAST.Itfurtherintroducedanexampleofintegrated'hybrid'operatingscenarioofinteresttoITERandCFETR.
简介:GaInP/GaAs/Getriple-junctionsolarcellswereirradiatedwith50keVand100keVprotonsatfluencesof5×1010cm-2,1×1011cm-2,1×1012cm-2,and1×1013cm-2.Theirperformancedegradationisanalyzedusingcurrent-voltagecharacteristicsandspectralresponsemeasurements,andthenthechangesinIsc,Voc,Pmaxandthespectralresponseofthecellsareobservedasfunctionsofprotonirradiationfluenceandenergy.Theresultsshowthatthespectralresponseofthetopcelldegradesmoresignificantlythanthatofthemiddlecell,and100keVproton-induceddegradationratesofIsc,VocandPmaxarelargercomparedwith50keVprotonirradiation.
简介:通过原位浸渍法把FeSO4和其它助剂共同浸渍在两种烟煤上,考察了以FeSO4为主要前驱体的催化剂对这两种煤直接液化的活性与选择性,以及其对液化产物-甲苯可溶物分子量的影响作用,并通过EXAFS和SAXS表征揭示了催化剂在煤上的化学态和粒径分布,结果表明:在一定的反应条件下,FeSO4和两种助剂分别共浸渍在两种煤上时,煤的总转化率及沥青烯和轻质产物的产率均比不添加催化剂时的结果提高1倍左右,与铁的硫化物相比,以FeSO4为主要前驱体的催化剂沥青烯和轻质产物具有较高的选择性,生成的重质甲苯可溶物具有较大的分子量;EXAFS和SAXS表明,原位浸渍在煤上的FeSO4表现为纳米相,助剂Na2S和尿素的添加主要改变了Fe原子周围的配位原子种类以及它们的成键方式,而对其颗粒分布影响较小,催化剂在汾西煤上的分布较其在兖州煤上的差一些。
简介:本文测定了在高压条件下两种金属(钙和锌)的8-羟基喹啉络合物的晶体粉末样品的发光行为和原位x-光衍射光说。结果表明,压力对其发光性质产生极大的影响。随着压力的增加,8-羟基喹啉钙的发光强度在3GPa以内时大大增加。随后发光强度快速下降,到7GPa左右时几乎为零。而8-羟基喹啉锌的发光随压力的增加而逐渐降低,到7GPa左右时常压的10%。高压下的原位x-光衍射结果表明8-羟基喹啉钙的晶体在3-4GPa开始发生非晶化相变,在7GPa时该非晶化相变完成,样品的x-光衍射完全消失。而8-羟基喹啉锌在压力的作用下(至16GPa)没有发生明显的相变。