简介:TechnologicalprocessofrareearthsealinganodizedLY12(2024)alloyisintroduced.Corrosionbehaviorofthefilmwasstudiedbypolarizationcurvesandelectrochemicalimpedancespectroscopy(EIS).Theresultsshowedthatthecoatingremainedpassivityatthepotentialrangefromtheopencircuitpotential(-780mV)to-250mVinNaClsolution.Whenthepotentialexceeded-200mV,corrosionreactionhappenedonthecoating.theresultsofElSanalysiswasconsistentwiththeresultsofpolarizationcurves.
简介:Themicrostructuralevolutionsofadvanced9-12%Crferrite/martensiteheat-resistantsteelsusedforpowergenerationplantsarereviewedinthisarticle.Despiteofthesmalldifferencesinchemicalcompositions,thesteelssharethesamemicrostructureoftheas-temperedmartensite.Itisthethermalstabilityoftheinitialmicrostructurethatmattersthecreepbehavioroftheseheat-resistantsteels.Themicrostructuralevolutionsinvolvedin9-12%Crferriteheat-resistantsteelsareelabo-rated,including(1)martensiticlathwidening,(2)disappearanceofprioraustenitegrainboundary,(3)emergenceofsubgrains,(4)coarseningofprecipitates,and(5)formationofnewprecipitates,suchasLaves-phaseandZ-phase.Theformerthreemicrostructuralevolutionscouldberetardedbyproperlydisposingthelattertwo.Namelyimprovingthestabilityofprecipitatesandoptimizingtheirsizedistributioncaneffectivelyexertthebeneficialinfluenceofprecipitatesonmicrostructures.Inthissense,themicrostructuralstabilityofthetemperedmartensiteisinfactthestabilityofprecipitatesduringthecreep.Manyattemptshavebeencarriedouttoimprovethemicrostructuralstabilityof9-12%Crsteelsandseveralpromisingheat-resistantsteelshavebeendeveloped.
简介:在电的运输性质上评估Ni替换的影响,p类型skutteruditesRyFe3NiSb12(R=Ba,Nd和Yb)系统地从2.5K被调查到800K。由小心地修改三fillers,Ba,Nd和Yb的充满的部分,搬运人集中精确被调整,它按比例改变到数统治的原子价计算的名字的价值。活动性和Seebeck系数的搬运人集中依赖表示在原子价乐队的二乐队贡献,和为热电的性能的优化搬运人集中在之间(5–9)×1020厘米−3。样品的热电导率用稀土元素的元素(Nd和Yb)填满的格子作为与相比显著地更低充满Ba,由于更低的反响的频率并且部分充满。与公司替换相比,Ni替换趋于关上乐队差距,它为RyFe3NiSb12。然而由于状态的密度的改进,当搬运人集中是类似的时,RyFe3NiSb12比RyFe2公司2在更低的温度范围的Sb12。0.73的ZT价值为Yb0.77Fe3在600K的NiSb12。
简介:钡铁酸盐micro/nano纤维成功地经由由把dimethylformamide(DMF)用作溶剂的静电的旋转被准备,并且poly乙烯基pyrrolidone(PVP)作为旋转auxiliaries。结构,形态学,和磁性上的锶替换的效果被扫描电子调查显微镜(SEM),X光检查衍射分析(XRD),和颤动取样磁强计(VSM)。样品的XRD模式证实纯钡铁酸盐纤维形式,和Sr替换做主要山峰(110),(107),并且(114)稍微搬到右。另外,FE-SEM图象证明代替的纤维能保留的Sr完成含纤维的形态学。而且,当纤维在800点被锻烧时,VSM结果证明浸透磁化能到达56.7emu/g'
简介:Na5+xYAlxSi4-xO12superionicconductorsarerhombohedralR3cspacegroup.Theirstructuresarecharacterizedby(Alx/4Si1-x/4)O4tetrahedralinkedtoformpuckered(Al3xSi4-x)4O35ringsparalleltothebasalplaneofthehexagonalcell.Theserings,separatedbypartsofsodiumoxygenpolyhedron,arestackedtoformlargerigidcolumsparalleltocaxis.Thecolumnsarelinkedby[YO6]octahedratoformathree-dimensionalFrameworkwithlargechannelsbetweentherings.PartsofNaionslocatedinthecoresofthecolumnsaremovable.Intermsoftheconductionmechanism,theconcentrationofconductingNa+ionswascarriedoutandcomparedwiththeexperimentalresults.Itwasfoundthatthetheoreticalvaluesaccordwiththeexperimentalresults.
简介:Thestudyofthetriplejunctionsofthegrainboundariesinsomefccsolidsolutions,orderedalloysandintermetallicswithL12hasbeencarriedoutusingtheopticalmetallographyandTEMmethods.Two-typesofthetriplejunctionswerefoundinthealloysinvestigated(1),consistingoftheboundariesoftherandom(RT),and(2),consistingoftheRTboundaryandthespecialboundaries(ST).TherelativevaluesoftheRTandSTboundaryenergyweredeterminedonthebasisofthemeasurementsoftheanglesbetweenthegrainboundaryplanes.IthasbeenshownthattheenergyofSTboundariesincreaseswiththeincreaseofthestackingfault(SF)energy.TheenergyoftheRTboundariesdoesnotdependontheSFenergy.
简介:ThecompositenanofibersofSrTiO3/SrFe12O19withamolarratioof1:1anddiameterabout120nmwerepreparedbyelectrospinning.Effectsofcalcinationtemperatureontheformation,crystallitesize,morphologyandmagneticpropertywerestudiedbyinfraredspectroscopy,X-raydiffraction,scanningelectronmicroscopyandvibratingsamplemagnetometer.Thebinaryphaseofstrontiumferriteandtitanatewasformedafterbeingcalcinedat900℃for2handthecompositenanofiberswerefabricatedfromnanograinsofSrTiO3about24nmandSrFe12O19around33nm.ThecrystallitesizesforthenanofibersincreasewithincreasingcalcinationtemperatureandtheadditionofSrTiO3hasanobvioussuppressioneffectonSrFe12O19graingrowth.Thespecificsaturationmagnetizationandremanencetendtoincreasewiththecrystallitesize.Withincreasingcalcinationtemperaturefrom900to1050℃,thecoercivityincreasesinitially,achievingamaximumvalueof520.2kA·m-1at950℃,andthenshowsareductiontendency.