简介:EffectofCe-Mg-Si(lightRE)andY-Mg-Si(heavyRE)nodulizersonthemicrostructuresandmechanicalpropertiesofheavysectionductileironwasinvestigatedtodevelopthematerialofspent-nuclear-fuelcontainers.Twoas-castsweretreatedbythesamequalitypercentageoflightREandheavyRE,respectively.Fourpositionswerechosentostandfordifferentsolidificationcoolingratesofspecimens.Thetensilestrength,elongationandimpacttoughnessofspecimenstreatedbyheavyREwereallhigherthanthoseofthespecimenstreatedbylightRE.Withthedecreaseofcoolingrate,themechanicalpropertiesoftwospecimensdecreased,andthefracturemorphologychangedfromductilefracturetobrittlefracture.TheimprovingeffectofmechanicalpropertiesbetweenheavyREandlightREwasobviousduetothebetteranti-degradationpropertyofheavyRE.Whilethesolidificationprocesslastedformorethan250min,theimprovingeffectwasnotobviousduetoseriousspheroidalizationdecaying.
简介:
简介:ToevaluatethepossibilityofusingGd-Si-Gealloysinmagneticrefrigerators,samplesofGd-Si-GealloysweremadeofdomesticGd.Themagnetocaloriceffectofsampleswasestimatedbymagneticentropychange(-ΔSm)calculatedfromM-HcurvesaccordingtoMaxwellrelation.ThefirstorderphasetransformationwasdestroyedduetotheimpuritiesinthecommercialGd,sothatnogiantmagnetocaloriceffectwasfound.ThesamplesmadeofpurifiedGdexhibitfirstorderphasetransformation,andthe-ΔSmisbasicallyconsistentwiththepublisheddataofAmeslaboratory,USA.ThisworkprovesthatGd-Si-GealloysmadeofdomesticGdcanbeutilizedinmagneticrefrigerators.
简介:MossbauerEffectofRapidlyQuenchedAl-Fe-V-Si-MmAlloysWangJianqiang(王建强),ChaoYuesheng(晁月盛),ZengMeiguang(曾梅光),ZhangBaojin(张宝金),Ch...
简介:Differentrareearth(RE=La,Ce,Pr,Nd,Sm,Y)andCumodifiednickelcatalystsforhydrogenproductionfrommethanedecompositionweresynthesizedbyasol-gelprocessandmethod.ThecatalystswerecharacterizedoranalyzedthroughBrumauer-Emmett-Teller(BET),X-raydiffraction(XRD),scanningelectronmicroscopy(SEM),transmissionelectronmicroscopy(TEM)techniques.Andthehydrogenproductionperformancewasalsoevaluatedbyafixed-bedandmicro-reactiontechniquewithCH4→C+H2asaprobereaction.Theresultsshowedthatrareearthmodificationhadplayedagreatrolefornickelcatalysts,forexample,smallernickelparticles,goodthermalstability,highactivity,etc.Lawasthebestadditiveamongrareearthmodification.TheSEMofrareearthmodifiedcatalystsshowedorderedflower-likestructureandrareearthmodificationmadethenickelparticlesmovetothesurfaceofcatalysts.Inaddition,theSEMofnano-carbonswasalsochangedbyrareearthmodificationwithlong,narrownano-carbonfibersortubesobtained.Solidcarbonformationwaspreventedbyrareearthmodification.
简介:
简介:Thephasesandmagnetocaloriceffectinthealloys(Gd1-xErx)5Si1.8Ge2.2withx=0,0.1,0.2and0.3wereinvestigatedbyX-raydiffractionanalysisandmagnetizationmeasurement.ThesamplesweresinglephasewiththemonoclinicGd5Si2Ge2-typestructure.WiththeincreaseofErcontent,theCurietemperature(Tc)decreasedobviouslyfrom253Kofthealloywithx=0to114Kwithx=0.3.Themaximummagneticentropychangedinthesamplesof(Gd1-xErx)5Si1.8Ge2.2withx=0.0,0.1,0.2and0.3were6.88,8.32,9.59and10.24J·kg-1·K-1respectivelyintheappliedfieldchangeof0~2.0T.