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87 个结果
  • 简介:TheS-RHTtechnologyisdevelopedbyFRIPPforresiduehydrotreatinginthefixedbedinordertoprocessthehighsulfurcrudeandincreasetheyieldoflightdistillates.Thetechnologycanbeusedfortreatingvariouskindsofatmosphericresidues(AR)orvacuumresidues(VR)withatotalmetalcontentlessthan150ppmundertheoperatingconditionsofatemperaturerangingfrom360-410℃,ahydrogenpartialpressureof14-15MPa,aLHSVof0.20-0.30h-1andahydrogentooilratioof700-1000.AcertainamountoflightproductscanbeobtainedandthehydrotreatedatmosphericresiduecanfullymeettheneedsforthefeedstocktoRFCCorablendingfeedstocktoFCC.BasedontheS-RHTtechnology,a2Mt/aresiduehydrotreatingunithasbeenconstructedandsuccessfullystartedupatMaomingPetrochemicalCompanybytheendof1999.

  • 标签: RESIDUE HYDROTREATING combined CATALYST system rate
  • 简介:本发明涉及一种以无规共聚聚丙烯(PP-R)为基体材料,通过与改性的纳米晶须复合来提高PP-R管用树脂的耐热性能。同时提高树脂的断裂伸长率、抗弯强度的制备方法,其特点是将长度为2-100μm、直径为10-400hm的纳米晶须,经偶联剂改性后,与普通PP-R树脂复合,纳米晶须在基体中有较好的分散性,而且在基体中形成空间的网络结构,从而大大改善了PP-R树脂的热学性能和力学性能;加入的无机抗老化剂不仅可以使树脂具有较好的抗老化性能,同时具有抑菌、抗菌性。

  • 标签: PP-R管 纳米晶须 制备方法 树脂 改性 无规共聚聚丙烯
  • 简介:OnOctober18—19,2018,threeR&DachievementsforrealizingtheChinesecontentofcoalchemicalindustry,includingtheDCSsystemforSinopec’slargecoaldeepprocessingproject,themethanolsyngascompressortrain,andthelargewater-cooledandgas-cooledmethanolsynthesisreactors,hadpassedtheappraisalinOrdoscityofInnerMongolia.ItislearnedthatthesethreeprojectsarebeingappliedforthefirsttimeinChina’scoalchemicalindustrytosymbolizenewbreakthroughsintheChinesecontentofmajorequipmentownedbytheSinopecCorp.,whichboastsarangeofindependentintellectualpropertyrightstopushforwardthetechnicaladvancementofnationalindustry.

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  • 简介:本发明涉及一种以无规共聚聚丙烯(PP-R)为基体材料,通过与层状云母、改性的纳米晶须以及无机纳米粒子的复合来提高PP-R管专用树脂的耐热性能,同时提高树脂的断裂伸长率、抗弯强度等力学性能的制备方法,其特点是通过层状云母二维薄片状结构的插层复合,纳米晶须材料在基体中形成空间的网络结构,零维纳米颗粒在基体中的纳米尺度的分散性,以及层状云母具有的较强隔热性能的联合作用,大大改善了PP-R树脂的热学性能和力学性能。

  • 标签: PP-R管 专用树脂 制备方法 高耐热性 无机纳米粒子 无规共聚聚丙烯
  • 简介:Inthispaper,2-isopropylnaphthalenehasbeensynthesizedbythereactionofnaphthaleneandisopropylbromide,usingtriethylaminehydrochloride-aluminumchlorideionicliquidasthecatalyst.Theeffectofthecatalystcomposition,thereactiontime,thereactiontemperature,theionicliquiddosage,aswellasthemolarratioofthereagentsonthe2-isopropylnaphthaleneyieldwassystematicallyinvestigated.Theoptimalreactionconditionscover:anAlCl3toEt3NHClratioof2.0,areactiontimeof3h,areactiontemperatureof15.0℃,avolumefractionofionicliquidtothemixture(isopropylbromide,n-dodecaneandn-hexane)of9%,andanaphthalene/isopropylbromidemolarratioof4.0.Undertheoptimalreactionconditions,theconversionofisopropylbromidereached98%andtheselectivityof2-isopropylnaphthalenewasequalto80%.ThetestresultsverifiedgoodcatalyticactivityuponusingEt3NHCl-AlCl3ionicliquidasthecatalystforalkylationofnaphthalenewithisopropylbromide.Theactivityoftheionicliquidremainsunchangedafterithasbeenrecycledfor4times.

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  • 简介:钢丝绳润滑防锈油是一种具有广阔市场前景的特种润滑油,广泛应用于港口机械、挖掘机、行车、吊桥、货物卷扬机及商务用电梯缆绳等领域,需求量正逐步扩大。中国石化股份有限公司润滑油研发(上海)中心成功开发出具有高渗透性、高黏附力、可抵御潮湿与盐雾侵蚀、黏温性能的长城R5319钢丝绳润滑防锈油,可替代价格昂贵的国外同类产品。

  • 标签: 润滑油 防锈油 钢丝绳 应用 开发 长城
  • 简介:以2,6-二甲基苯酚、氧气为原料,氨水与乙酸铜为催化剂,合成得到了3,3′,5,5′-四甲基-4,4′-联苯二醌,得到反应的最佳条件为:2,6-二甲基苯酚的浓度为0.1g/mL,氨水与乙酸铜的摩尔比为0.43,温度为75℃,反应时间为6h,产率达到60%.

  • 标签: 3 3’ 5 5’-四甲基-4 4’-联苯二醌 合成 2 6-二甲基苯酚 氧气 原料
  • 简介:Alkylationoftoluenewith2-chloro-2-methylpropane(t-Bu-Cl)tosynthesizepara-tert-butyltoluene(PTBT)wascarriedoutinthepresenceoftriethylaminehydrochloride-aluminumchlorideionicliquidsusedasthecatalyst.TheionicliquidswerepreparedwithdifferentmolarratiosofEt3NHCltoAlCl3,andtheeffectofthemolarratiobetweenAlCl3andEt3NHCl,thereactiontime,thereactiontemperature,theionicliquiddosage,aswellasthemolarratiooftoluenetochloro-2-methylpropaneonthealkylationreactionoftoluenewithchloro-2-methyl-propanewasinvestigated.ThetestresultsshowedthattheacidicionicliquidspreparedwithEt3NHClandAlCl3hadgoodactivityandselectivityforthealkylationreactionoftoluenewithalkylchloridetoproducePTBT.TheoptimalreactionconditionswerespecifiedatanAlCl3toEt3NHClratioof1.6,areactiontemperatureof20℃,amassfractionoftoluenetoionicliquidof10%,andachloro-2-methylpropanetotoluenemolarratioof0.5.Underthesuitablereactionconditions,a98%conversionofchloro-2-methylpropaneandan82.5%selectivityofPTBTwereobtained.Ionicliquidscouldbereused5timeswithitscatalyticactivityunchanged,andtheregeneratedionicliquidscanberecycled.

  • 标签: 对叔丁基甲苯 酸性离子液体 烷基化反应 氯化铝 催化剂 三乙胺盐酸盐
  • 简介:ThepolycrystallinephaseWO3/g-C3N4wassynthesizedunderstirringusingtungstenicacid(H2WO4)andgraphiticcarbonnitride(g-C3N4)asrawmaterials.ThecatalystwascharacterizedbyX-raydiffraction(XRD),scanningelectronmicroscopy(SEM),energydispersivespectroscopy(EDS),theFouriertransforminfraredspectroscopy(FT-IR),andtheBrunauer-Emmett-Telleranalysis(BET).ThepolycrystallinephaseWO3/g-C3N4wasdeterminedbyXRDtechnique.TheoxidativedesulfurizationprocesswasinvestigatedusingWO3/g-C3N4asthecatalyst,30%hydrogenperoxide(H202)astheoxidant,and1-butyl-3-methylimidazoliumtetrafluoroborate([bmim]BF4)ionicliquids(ILs)astheextractant.Theoperatingconditions,includingH2WO4amount,ILdose,H2O2volume,temperature,catalystdosage,andtypesofsulfurcompounds,weresystematicallyresearched.Thedesulfurizationratecouldreach98.46%forremovingdibenzothiophene(DBT)fromthemodeloilunderoptimalreactionconditions.Inaddition,thecatalyticactivitywasslightlydecreasedafterfiverecyclesofcatalysts.Thereactionkineticsanalysisshowsthattheoxidativedesulfurizationsystemwasinaccordwiththefirst-orderreactionkineticsequation.Themechanismofoxidativedesulfurizationwasproposed.

  • 标签: oxidative DESULFURIZATION WO3/g-C3N4 heterogeneous CATALYSIS EXTRACTANT
  • 简介:3月份,在全球股市上扬、美联储意外购入长期美国公债等利好消息的带动下,国际油价强劲反弹。WTI、英国布伦特原油以及亚洲迪拜原油的现货价格平均为每桶48.00美元、46.54美元和45.59美元,较2月份分别上升了8.84美元、3.47美元和250美元,环比分别增长28%、8%和6%。

  • 标签: 国际油价 现货价格 美元 WTI 原油 股市
  • 简介:针对3号苯酚丙酮装置生产中的丙酮褪色问题,分析生产中影响褪色的物质及原设计对褪色指标的工艺控制,通过实验研究,提出用降低丙酮产品中的丙醛含量来解决褪色问题的方法,并找出了丙醛含量波动的直接原因,为实施生产过程控制提出了有效的措施。

  • 标签: 工艺 丙酮褪色 工艺控制 丙醛工艺 苯酚丙酮装置