简介：K2Ti2O5andLixK2-xTi2O5sampleswithvaryingKcontents(x=0.125,0.15,0.3),targetedonremovaloftwomainenvironmentalpollutants:PMandNOx,weresynthesizedbythesolidstatemethodusingTiO2,KNO3andLiOH·H2OasstartingmaterialsandwerecharacterizedbyX-raydiffractometry,scanningelectronmicroscopy,andBET.ThecatalyticactivityoftitanatecatalystsonPMoxidationwasevaluatedusingthetemperatureprogrammedoxidation(TPO)method.ThetestresultsshowedthattheperovskitestructureofK2Ti2O5wasstillretainedafterdopingasmallamountofLi,andthecatalyticperformanceofLixK2-xTi2O5hadbeenimprovedsignificantlycomparedwiththatofK2Ti2O5.Li0.15K1.85Ti2O5catalysthadthehighestcatalyticactivitywithanignitiontemperatureof210℃andapeaktemperatureof290℃.ThecatalyticactivityofbothK2Ti2O5andLixK2-xTi2O5underintimatecontactwashigherthanthatunderloosecontact.Whentheexhaustgasflowratewasaround100mL/min,thecatalystsamplesshowedahighestactivity.TheLidopedK2Ti2O5couldbeanexcellentcandidateforPMoxidationduetoitshighoxidationactivity,waterstability,resistancetosulfurpoisoningandeconomicaladvantages.

简介：对我国环境大气中PM2．5的污染状况以及石化行业对大气中PM2．5来源的贡献等进行了综述，对国家新颁布的《环境空气质量标准》（GB3095-2012）中对PM2．5的管理内容进行了解读。分析了在国家日益严格的大气细颗粒物防控形势下，石化行业所面临的环保工作任务进一步加重，环保资金和技术投入进一步增加的压力，提出了石化行业的应对措施：对PM2．5排放情况进行摸底调查，开展固定污染源排气中PM2．5的减排工作，加快油品质量升级步伐，推进挥发性有机物控制等应对措施。

简介：Inthispaper,2-isopropylnaphthalenehasbeensynthesizedbythereactionofnaphthaleneandisopropylbromide,usingtriethylaminehydrochloride-aluminumchlorideionicliquidasthecatalyst.Theeffectofthecatalystcomposition,thereactiontime,thereactiontemperature,theionicliquiddosage,aswellasthemolarratioofthereagentsonthe2-isopropylnaphthaleneyieldwassystematicallyinvestigated.Theoptimalreactionconditionscover:anAlCl3toEt3NHClratioof2.0,areactiontimeof3h,areactiontemperatureof15.0℃,avolumefractionofionicliquidtothemixture(isopropylbromide,n-dodecaneandn-hexane)of9%,andanaphthalene/isopropylbromidemolarratioof4.0.Undertheoptimalreactionconditions,theconversionofisopropylbromidereached98%andtheselectivityof2-isopropylnaphthalenewasequalto80%.ThetestresultsverifiedgoodcatalyticactivityuponusingEt3NHCl-AlCl3ionicliquidasthecatalystforalkylationofnaphthalenewithisopropylbromide.Theactivityoftheionicliquidremainsunchangedafterithasbeenrecycledfor4times.

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简介：以2,6-二甲基苯酚、氧气为原料,氨水与乙酸铜为催化剂,合成得到了3,3′,5,5′-四甲基-4,4′-联苯二醌,得到反应的最佳条件为:2,6-二甲基苯酚的浓度为0.1g/mL,氨水与乙酸铜的摩尔比为0.43,温度为75℃,反应时间为6h,产率达到60%.

简介：Alkylationoftoluenewith2-chloro-2-methylpropane(t-Bu-Cl)tosynthesizepara-tert-butyltoluene(PTBT)wascarriedoutinthepresenceoftriethylaminehydrochloride-aluminumchlorideionicliquidsusedasthecatalyst.TheionicliquidswerepreparedwithdifferentmolarratiosofEt3NHCltoAlCl3,andtheeffectofthemolarratiobetweenAlCl3andEt3NHCl,thereactiontime,thereactiontemperature,theionicliquiddosage,aswellasthemolarratiooftoluenetochloro-2-methylpropaneonthealkylationreactionoftoluenewithchloro-2-methyl-propanewasinvestigated.ThetestresultsshowedthattheacidicionicliquidspreparedwithEt3NHClandAlCl3hadgoodactivityandselectivityforthealkylationreactionoftoluenewithalkylchloridetoproducePTBT.TheoptimalreactionconditionswerespecifiedatanAlCl3toEt3NHClratioof1.6,areactiontemperatureof20℃,amassfractionoftoluenetoionicliquidof10%,andachloro-2-methylpropanetotoluenemolarratioof0.5.Underthesuitablereactionconditions,a98%conversionofchloro-2-methylpropaneandan82.5%selectivityofPTBTwereobtained.Ionicliquidscouldbereused5timeswithitscatalyticactivityunchanged,andtheregeneratedionicliquidscanberecycled.

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简介：ThepolycrystallinephaseWO3/g-C3N4wassynthesizedunderstirringusingtungstenicacid(H2WO4)andgraphiticcarbonnitride(g-C3N4)asrawmaterials.ThecatalystwascharacterizedbyX-raydiffraction(XRD),scanningelectronmicroscopy(SEM),energydispersivespectroscopy(EDS),theFouriertransforminfraredspectroscopy(FT-IR),andtheBrunauer-Emmett-Telleranalysis(BET).ThepolycrystallinephaseWO3/g-C3N4wasdeterminedbyXRDtechnique.TheoxidativedesulfurizationprocesswasinvestigatedusingWO3/g-C3N4asthecatalyst,30%hydrogenperoxide(H202)astheoxidant,and1-butyl-3-methylimidazoliumtetrafluoroborate([bmim]BF4)ionicliquids(ILs)astheextractant.Theoperatingconditions,includingH2WO4amount,ILdose,H2O2volume,temperature,catalystdosage,andtypesofsulfurcompounds,weresystematicallyresearched.Thedesulfurizationratecouldreach98.46%forremovingdibenzothiophene(DBT)fromthemodeloilunderoptimalreactionconditions.Inaddition,thecatalyticactivitywasslightlydecreasedafterfiverecyclesofcatalysts.Thereactionkineticsanalysisshowsthattheoxidativedesulfurizationsystemwasinaccordwiththefirst-orderreactionkineticsequation.Themechanismofoxidativedesulfurizationwasproposed.

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简介：3月份，在全球股市上扬、美联储意外购入长期美国公债等利好消息的带动下，国际油价强劲反弹。WTI、英国布伦特原油以及亚洲迪拜原油的现货价格平均为每桶48．00美元、46．54美元和45．59美元，较2月份分别上升了8．84美元、3．47美元和250美元，环比分别增长28％、8％和6％。

简介：根据3号FCC装置运行情况，从物料平衡、产品分布、能耗物耗等方面进行分析，发现装置在运行过程中存在的问题，寻找对策，以便装置在更优化状态下运行。

简介：针对3号苯酚丙酮装置生产中的丙酮褪色问题，分析生产中影响褪色的物质及原设计对褪色指标的工艺控制，通过实验研究，提出用降低丙酮产品中的丙醛含量来解决褪色问题的方法，并找出了丙醛含量波动的直接原因，为实施生产过程控制提出了有效的措施。

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简介：根据中国石化股份有限公司的发展规划，高桥分公司将建设成为股份公司两个汽油出口基地之一，年出口汽油为720kt，其中出口到欧洲的汽油产品要符合欧Ⅲ汽油标准EN228-1999，出口到美国西海岸加洲地区要符合美国加洲汽油标准CapLimitsCaRFG2；而且国内环保质量要求的日益严格也必将要求更加环保的汽油。

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