Cyclicsixmembereda-aminonitrilehaveprovedtobeveryversatilesyntheticintermediatesandhavebeenwidelyusedintheconstructionofalargenumberofindolealkaloids.Inordertoobtainsomeinformationaboutthemechanisnofelectrochemicalsynthesisofaaminonitrile.ElectrochemistrybehaviorsthatincludecyclicvoltammetryandlinearsweepvoltammetryofcyclictertiaryamineswhichincludingN-benzylpiperidine(NBP),1-(l-Methoxycarbonylethyl)piperidine(MCEP),N-methylcarbonylppiperidine(NMCP),Nethylpiperidine(NEP)wasstudied.