AmodelhasbeendevelopedtodescribethemicrostructureevolutionintheatomizeddropletsofCu-Fealloyduringcoolingthroughthemetastablemiscibilitygap.CalculationshavebeenperformedforCu85Fe15alloytoinvestigatetheprocessofliquid-liquidphasetransformation.Thenumericalresultsindicatethattheminorityphasedropletsarenucleatedinatemperatureregionaroundthepeakofthesupersaturation.TheaverageradiusoftheFe-richdropletsdecreasesandthenumberdensityoftheminorityphasedropletsincreaseswithdecreasingtheatomizeddropletsize.Thesimulatedresultswerecomparedwiththeexperimentalones.Thekineticprocessoftheliquid-liquidphasetransformationwasdiscussedindetail.