AuseofSulfonateesterasalinkerinsynthesisofω-aminoalkanolswasreported.Diolsweretetheredontopolystyrylsulfonylchlorideresin,yieldingsulfonateresins(2).Aftercleavedbydiethylamine,diisopropylamineandpropylaminerespectively,threeω-aminoalkanolswereobtained.