Kinetics Analysis for the Parallel Reaction of Binary Rare Earth with Tribromoarsenazo

(整期优先)网络出版时间:1991-03-13
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TheoverallreactionwasdeterminedonthebasisofthedissociationconstantofTBAandtheratiooftheligandtotherareearthioninthecomplex.Theratelaw,rateconstantsandacitivitionenergiesforthereactionofLa3+,Gd3+andHo3+withTBAwerestudied.ItisshowninthestudythatprerequisitesforperformingdifferentialrateanalysisforbinaryrareearthswithTBAarethatthepseudo-first-orderparallelreactionmechanismshouldbeconformedwith,nomultinuclearcomplexwouldbeformedandtheco-colorationeffectscouldbeneglected.