Effect of rare earths on viscosity and thermal expansion of soda-lime-silicate glass

(整期优先)网络出版时间:2010-06-07
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Viscosityofsoda-lime-silicateglassdopedwithrareearthoxides(Pr6O11,Eu2O3,Yb2O3)wasinvestigatedbytherotatingcrucibleviscometer,themeltingtemperatureandactivationenergyforviscousflowofthestudiedmeltwerederivedonthebasisoftheArrheniusEquation,thecoefficientofthermalexpansion,glasstransitiontemperatureanddilatometricsofteningtemperaturewerealsodeterminedwithdilatometry,inordertorevealtheeffectsofrareearthelementsonthebehaviorofsoda-lime-silicateglass.Theresultsshowedthatintroductionofrareearthoxidesdecreasedtheviscosityofsoda-lime-silicateglassandmeltingtemperatureofcorrespondingmelt,increasedcoefficientofthermalexpansionofsoda-lime-silicateglass.Theglasstransitiontemperature,dilatometricsofteningtemperature,andmeltingtemperatureofsoda-lime-silicateglassdopedwithrareearthoxidesincreasedwithincreasingcationicfieldstrengthofcorrespondingrareearthions.