Hydrothermal Synthesis and Structure of a New 3D Lanthanide—Carboxylate Framework,[La（btec）1／2（H2btec）1／2（H2O）]n（H4btec=1,2,4,5

摘要 Thetitlecomplex,[La(baec)1/2(H2btec)1/2(H2O)]n(H4btec=1,2,4,5-benzenetetracarboxylicacid)(1)wassynthesizedbythehydrothermalreactionof1,2,4,5-benzenetetracarboxylicdianhydridewithLa(NO3)3·6H2OinH2O,andcrystallizesinthetriclinicsystem,spacegroupP-1withα=0.64403(3)nm,b=0.94500(4)nm,c=0.96380(5)nm,α=88.535(2)°,β=100.314(2)°,γ=76.6470(10)°,V=1.69968(10)nm^3,Z=2,andfinalR=0.0274,Rw=0.0735.In1,eachLa(Ⅲ）ioniscoordinatedbyeightoxygenatomsfromsixcarboxylategroupsandonecoordinatedwatermolecule.TwodifferentcoordinstionmodesofH4btecwerePresentinthestructure,oneofwhichcontainstwoprotonatedcarboxylategrougpstobalancethecharge.

1何水样;杨锐;武望婷;史启祯;王大奇;安德荣. Crystal Structure and Bioactivity of Complex [Gd（C10H9N2O4）（C10H8N2O4）（H2O）3]2·phen·4H2O.化学,2005-09.
2石恒真;单永奎;何鸣元;刘煜炎;翁林红. Synthesis and Structure of the First Protonated Zincoborophosphate：（ H3O ） Zn（ H2O ） 2BP2O8·H2O.化学,2003-09.
3MAOHong-yan;LIUHong-lei;ZHANGHong-yun;XUChen;WANGEn-bo;HANHua-yun;WUQing-an;ZHUYu. A Novel Layered Complex with Rhomboidal Channels： Hydrothermal Synthesis, Crystal Structure, and Properties of Cu （4,4′-bipy）2（H2PO4）2（H2O）2（bipy=bipyridine）.化学,2004-03.
4李秀玲;童明良;牛德仲;陈久桐. Synthesis and Crystal Structure of a Two-dimensional Silver（Ⅰ）-Iron（Ⅲ） Heteronuclear Coordination Polymer： {[Ag4Fe2（SCN）12（H2O）2] [（inaH）2（H2O）2]}n.化学,2004-01.
5贝姣宏;杨海艳;张岩峰. [Mn3Ⅱ(CH3COO)6(H2O)4·(H2O)2]n的合成、结构与磁性研究.化学,2019-01.
6WeiRongbao LiangYa 等. SYNTHESIS OF 1H，1′H BIS（BENZ—Δ^4—IMIDAZ—OLINE）2,2′—SPIRO—TITANIUM DICHLORIDE.高分子化学,1996-01.
7. SYNTHESIS OF 3-ARYL-1(2H, 4H) ACRIDONES AND THEIR DERIVATIVES.化学,1994-12.
8LI，Bao－Long;XU，Yan;等. Synthesis,Structure and Characterization of Two—dimensional Network Copper Complex [Cu3（nta）2（azpy）2（H2O）2]·6H2O.化学,2002-02.
9胡道道;苏东琴;崔亚丽;房喻;唐宗薰. Studies on the Phase Equilibrium of the System C6H12O6-（NH4）2SO4-C2H5OH-H2O（C2H5OH/H2O=0.90 by wt）at 35℃.药学,1998-04.
10ZHANG Xin;YOU Wan-sheng;ZHU Zai-ming;DANG Li-qin;SUN Zhen-gang;ZHENG Xue-fang. Syntheses, Crystal Structures and Characterization of Two Zeotype Crystals of K4[Cr30（H2O） 3（OOCH） 6] 2[ P2W18O62]· 9.5H2 O and K4[ Cr3O（ H2O）3（ OOCH）6 ]2[ H3 P2 W17Co（H2O） O61]· 20H2O.化学,2007-01.

Hydrothermal Synthesis and Structure of a New 3D Lanthanide—Carboxylate Framework,[La（btec）1／2（H2btec）1／2（H2O）]n（H4btec=1,2,4,5—Benzeneteracarboxylic acid）

来源期刊

相关推荐

同分类资源更多

相关关键词

Hydrothermal Synthesis and Structure of a New 3D Lanthanide—Carboxylate Framework,[La（btec）1／2（H2btec）1／2（H2O）]n（H4btec=1,2,4,5—Benzeneteracarboxylic acid）

来源期刊

相关推荐

同分类资源 更多

相关关键词

同分类资源更多