简介:Thehybridstructuresofpolystyrene-b-poly(ethyleneoxide)(PS-b-PEO)blockcopolymerandinorganicnanoparticleswithgoodstabilityandbiocompatibilityhavepotentialapplicationsindrugdeliveryandbioimaging.Sphericalco-assembliesofPS120-b-PEO318andoleylamine-cappedCdSquantumdots(QDs)areproducedsuccessfullyinthisworkbyaddingwatertoamixedcommonsolvent,suchasN,N-dimethylmethanamide(DMF)/chloroform,DMF/tetrahydrofuran(THF),orDMF/toluene.TheenergydispersiveX-ray(EDX)spectrumindicatesthatQDsarelocatedattheinterfacebetweenthecoreandshellofthesphericalco-assemblies.Theco-assemblyprocessduringwateradditionistracedbytransmissionelectronmicroscopy(TEM)andturbiditymeasurement.Sphericalco-assembliesareformedthroughbuddingfrombilayersoftheblockcopolymerandQDs.Themorphologyoftheco-assembliesisrelatedtothemiscibilityoftheQD-dispersingsolventswithwaterandthemorphologychangesfromasphericaltoavesicle-likestructurewithDMF/toluene.IncreasingTHFcontentinthemixedsolventcausesmorphologicaltransitionsfromsphericalco-assembliestomulti-branchedcylindersandmicelleswhereQDsarelocatedinthecentralcore.Increasingchloroformcontentyieldsvesicle-likestructureswithprotrudingrodsonthesurface.Themechanismofthemorphologicaltransitionsisalsodiscussedindetail.
简介:Arealn×nsymmetricmatrixX=(x_(ij))_(n×n)iscalledabisymmetricmatrixifx_(ij)=x_(n+1-j,n+1-i).Basedontheprojectiontheorem,thecanonicalcorrelationde-compositionandthegeneralizedsingularvaluedecomposition,amethodusefulforfindingtheleast-squaressolutionsofthematrixequationA~TXA=Boverbisymmetricmatricesisproposed.Theexpressionoftheleast-squaressolutionsisgiven.Moreover,inthecorrespondingsolutionset,theoptimalapproximatesolutiontoagivenmatrixisalsoderived.Anumericalalgorithmforfindingtheoptimalapproximatesolutionisalsodescribed.
简介:极其细小磨擦非结晶的合金催化剂被化学减小与KBH4准备。在在气压的cinnamaldehyde的液体阶段加氢期间,Ru-B催化剂准备了展出优秀选择到cinnamyl酒精。当加氢与超声的照耀被执行时,当到cinnamyl酒精的选择仍然保持几乎未改变时,反应率能极大地被提高。加氢率随超声的频率或照耀时间的增加被增加。根据各种各样的描述,例如XRD,XPS,TEM,赌注和ICP,结构、电子的特征上的超声的照耀的效果磨擦催化剂简短被学习。同时,催化表演上的ultrasonication的提升效果也基于cinnamaldehyde的选择加氢被讨论到cinnamyl酒精。
简介:ThispaperreportsastudyofcomplexfocussingacousticfieldsofaconvexphasedarrayprobewidelyusedinultrasonicdiagnosticB-scanner.Thetimedelaynecessaryforelectronicfocussingandforgeometricfocussingofcomplexfocussingisgiven.BymeansofHelmholtz‘sintegralformula,theexpressionsofacousticfieldswereobtainedfortheelectronicfocussingandcomplexfocussing.Withsimpson‘snumericalintegral,agreatdealofcomputationswascarriedoutwithan86/330computer.Bymeansofusingdifferentparameters,anoptimumfocalrangeandbeamwidthofa4sequenceselectronicandcomplexfocussingacousticsystemwasselected.WithanEUB-40ultrasounddiagnosticB-scannerproducedbytheHitachicompany,thelateralfocussingacousticfieldandlateralresolutioninanechoictankwerephotographedbylatticingmethodandtheexperimentalresultiscon-sistentwiththetheory.
简介:用增益开关掺铥光纤激光器作种子源,搭建了一个掺铥光纤主振荡放大系统。该系统增益开关种子源最大输出功率约为250mW,斜效率为28.5%;脉冲宽度为56.5ns,脉冲峰值功率为221.2W,对应的峰值功率密度约为0.35GW·cm^-2,输出光谱的3dB线宽仅0.09nm,中心波长在1942nm处。经一级放大后,激光器输出功率提高到1.33W,一级放大器斜效率达48.6%。同时,峰值功率提高到1.2kW,对应的峰值功率密度达1.86GW·cm^-2。此时,受光谱仪分辨率的限制,测得的激光3dB线宽仅为0.06nm。在二级放大器中观察到了超连续谱输出。超连续谱覆盖2~2.6μm的光谱范围,3dB带宽约490nm。
简介:Inthispaper,basedontheimplicitRunge-Kutta(IRK)methods,wederiveaclassofparallelschemethatcanbeimplementedontheparallelcomputerswithNs(Nisapositiveevennumber)processorsefficiently,anddiscusstheiterativelyB-convergenceoftheNewtoniterativeprocessforsolvingthealgebraicequationsofthescheme,secondlywepresentastrategyprovidinginitialvaluesparallellyfortheiterativeprocess.Finally,somenumericalresultsshowthatourparallelschemeishigherefficientasNisnotsolarge.
简介:指向nano探查基于的一个可被细菌破坏的肿瘤poly(?-caprolactone)-b-poly(ethylene乙二醇)有磁性的回声成像(MRI)的块共聚物(PCL-b-PEG)micellefunctionalized对比代理人diethylenetriaminepentaacetic酸金轧(DTPA-Gd3+)在壳上并且一在红外线附近(NIR)在为磁性的回声和光双形式的成像的核心的染料是准备。纵的relaxivity(r1)PCL-b-PEGDTPA-Gd3+,micelle是13.4(mmol/L)?1s?1,DTPA-Gd3+的三褶层,并且比有类似的结构的许多聚合对比代理人的高。在里面忍受xenografted胸肿瘤的一只裸体老鼠的光成像显示出的vivo双形式的micelle优先地经由folic在肿瘤积累了由提高的渗透和保留(EPR)效果的调停酸的活跃指向和被动累积。结果显示dualmodalitymicelle是为癌症察觉和诊断的有希望的nano探查。
简介:Anewapproachtodeterminealltheelectro-elasticconstantsofthepiezoelectriccrystalsinclass4mmhasbeenputforward.Asanexample,alltheconstantsofLithiumTetraborate(Li2B4O7)crystalhavebeenmeasuredbymeansoftheapproach.Theoutstandingadvantageoftheapproachisthatiton-lyneedstoemployinmeasurementthreecrystalplatesdifferentlyoriented.
简介:在laminar的非线性的传送对流的效果三维的Oldroyd-B液体流动被探讨。热转移现象被考虑非线性的热放射和热产生/吸收探索。边界层假设被考虑管理流动分析的数学模型。一些合适的类似变量被介绍把部分微分方程转变成平常的微分系统。有射击方法的Runge-Kutta-Fehlberg第四顺序、第五顺序的技术被用来获得无尺寸的速度和温度的答案。液体速度和温度上的各种各样的物理参数的效果被阴谋并且检验。比较与准确并且homotopy不安答案被做为粘滞液体大小写,和一根优秀火柴被注意。墙的数字价值砍在墙的压力和热转移率被公布并且调查。在德卜拉数字的价值的改进在液体速度上显示出反向的行为。当非线性的传送对流参数增加时,结果证明温度和热边界层被减少。Nusselt数字的价值比处于线性放射状况的那些处于非线性的放射状况是更高的。
简介:Thermoelectricityisatherrnorelatedpropertythatisofgreatimportanceinsingle-moleculejunctions.Theelectricalconductance(σ),electron-derivedthermalconductance(kel)andSeebeckcoefficient(S)ofBgo-basedsingle-moleculejunctionsareinvestigatedbyusingdensityfunctionaltheoryincombinationwithnon-equilibriumGreen'sfunction.Whenthedistancebetweentheleft/rightelectrodesis11.4A,therelationshipbetweenσandkelobeystheWiedemann-FranzlawverywellbecauseofthestronghybridizationbetweenB80molecularorbitalsandthesurfacestatesofAuelectrodes.Furthermore,thecalculatedLorenznumberisclosetothefamousvalueinmetalordegeneratesemiconductors.Inaddition,Sisonly—19.09μV/Kat300K,thusleadingtothesmallerelectron'sthermoelectriefigureofmerit(ZeiT=S^2σT/Kel).Interestingly,thestrainandchemicalpotentialcanmodulateB80-basedsingle-moleculejunctionsfromn-typetop-typewhenthecompressivestrainreaches—0.6Aorthechemicalpotentialshiftsto—0.16eV.ThismightbeattributedthatSreflectstheasymmetryintheelectricalconductancewithrespecttothechemicalpotentialandisproportionaltotheslopesofthetransmissionspectrum.