简介:Theclosed-jarincubationmethodiswidelyusedtoestimatethemineralizationofsoilorganicC.TherearetwoCpools(i.e.,organicandinorganicC)incalcareoussoil.ToevaluatetheeffectofadditionalcarbonatesonCO2emissionfromcalcareoussoilduringclosed-jarincubation,threeincubationexperimentswereconductedbyaddingdifferenttypes(CaCO3andMgCO3)andamountsofcarbonatetothesoil.TheadditionofcarbonatessignificantlyincreasedCO2emissionfromthesoil;theincreaserangedfrom12.0%intheCaCO3amendedsoilto460%intheMgCO3amendedsoilduringa100-dincubation.CumulativeCO2productionattheendoftheincubationwasthreetimesgreaterintheMgCO3amendedsoilcomparedtotheCaCO3amendedone.TheCO2emissionincreasedwiththeamountofCaCO3addedtothesoil.Incontrast,CO2emissiondecreasedastheamountofMgCO3addedtothesoilincreased.Ourresultsconfirmedthattheclosed-jarincubationmethodcouldleadtoanoverestimateoforganicCmineralizationincalcareoussoils.BecauseofitseffectonsoilpHandthedissolutionofcarbonates,HgCl2shouldnotbeusedtosterilizecalcareoussoiliftheexperimentincludesthemeasurementofsoilCO2production.
简介:Theannualseriesofδ13CweremeasuredintreeringsofthreeCryptomeriafortuneidisks(CF-1,CF-2,andCF-3)collectedfromWestTianmuMountain,ZhejiangProvince,China,accordingtocross-datingtreeringages.Therewasnoobviousdecreasingtrendoftheδ13CannualtimeseriesofCF-2before1835.However,from1835to1982thethreetreeringδ13Cannualseriesexhibitedsimilardecreasingtrendsthatweresignificantly(P≤0.001)correlated.Thedistributioncharacteristicsofascatterdiagrambetweenestimatedδ13CseriesofCF-2frommodelingandtheatmosphericCO2concentrationextractedfromtheLawDomeicecorefrom1840to1978wereanalyzedandacurvilinearregressionequationforreconstructingatmosphericCO2concentrationwasestablishedwithR2=0.98.Also,atestofindependentsamplesindicatedthatbetween1685and1839thereconstructedatmosphericCO2concentrationusingtheδ13CseriesofCF-2hadacloserelationshipwiththeLawDomeandSipleicecores,withastandarddeviationof1.98.ThegeneralincreasingtrendofthereconstructedatmosphericCO2concentrationcloselyreflectedthelong-termvariationofatmosphericCO2concentrationrecordedbothbeforeandaftertheIndustrialRevolution.Between1685and1840theevaluatedatmosphericCO2concentrationwasstable,butafter1840itexhibitedarapidincrease.Givenalongerδ13Cannualtimeseriesoftreerings,itwasfeasibletorebuildarepresentativetimeseriestodescribetheatmosphericCO2concentrationforanearlierperiodandforyearsthatwerenotintheicecorerecord.