简介:TheMoS2catalystswerepreparedfromvariousmolybdateprecursorsincludinginorganicandorganicmolybdatecompounds.ThesulfidationdegreeandmorphologyofactivephasesofMoS2activatedbyvariousmolybdateprecursorsinH2S/H2streamatdifferenttemperatureswerestudiedbyX-rayphotoelectronspectroscopy(XPS)andhigh-resolutiontransmissionelectronmicroscopy(HRTEM).TheorganicmolybdateprecursorsleadtoMoS2catalystswithhighersulfidationdegreeandsmalleractivephasestodemonstratehighercatalyticactivityduringhydrodesulfurizaiton(HDS)of4,6-DMDBT.
简介:通过大量岩心和测井资料分析,结合部分地震资料,依据高分辨率层序地层学原理,将辽东湾盆地古近系划分为2个超长期、6个长期、18个中期和数10个短期旋回层序。在综合长期层序界面和结构特征的基础上,选择长期旋回的上升和下降相域为等时地层单元编制层序、岩相古地理图,得出了长期旋回的古地理演化规律为:在LSC2和LSC3时期,以发育浅湖和湖底扇沉积体系为主,LSC4时期以发育三角洲和湖底扇沉积体系为主,到LSC5和LSC6时期以发育三角洲和湖泊沉积体系为主,自下而上形成浅湖→湖底扇→三角洲沉积演化过程和砂体展布规律。从而为有利储集砂体的预测提供了依据。
简介:鄂尔多斯盆地中东部山西组可划分为3个沉积层序,其中SQ8(山2段)可划分为低位、湖侵及高位体系域,主要砂体发育于低位体系域。SQ8—LST可细分为3个进积型准层序组,其砂体呈进积式向湖盆推进,自下而上分为L1,L2和L3准层序组,砂体厚度由薄变厚,分布面积由小变大。L1准层序组仅在研究区西北部发育一支近南北向展布的主砂带,砂岩厚2~10m,砂带宽10~15km,延伸约100km;L2,L3准层序组的砂体分布格局相似,砂岩厚度为4~20m,发育5~6支近南北向、北东向展布的砂带,砂带宽10~25km,延伸200~230km。L1准层序组为大规模海退之后的初始充填沉积,其砂岩成分复杂、分选差,储层物性相对较差,而向上至L2,L3准层序组,储层物性明显变好。有利的储集砂体为发育于低位体系域中上部准层序组的三角洲平原分流河道、前缘水下分流河道及河口坝砂体。三角洲前缘砂体物性略优于三角洲平原砂体,边滩砂体物性较差。
简介:以2,3-二氯萘醌与氨气为原料,甲醇作溶剂,制备了2-氨基-3-氯-1,4-茶醌。考察了反应条件对产品收率的影响,得到最件工艺条件:在二氯萘醌用量为0.1mol,氨与二氯萘醌的物质的量比为6,氨甲醇溶液含量15%~17%,反应温度20~25℃,反应时间4h,产品收率可达96%。
简介:SZorbadsorptivedesulfurizationtechnologyisofgreatsignificanceontheproductionofcleangasolineinChina,buttheformationofZn2SiO4duringtheoperationinsorbentswouldbringforthnegativeimpactsonthedesulfurizationperformanceandthestabilityoftheprocessingunit.Byusingthein-situTPO,XRD,andIRtechniquestostudythemechanismofZn2SiO4formationunderoperatingconditions,itwasfoundthatthecoexistenceofacidandhydrothermalconditionscouldacceleratetheformationofZn2SiO4.Moreover,thestudyofZn2SiO4inhibitionmethodindicatedthatthedecreaseofoxygenconcentrationinregenerationgaswouldinhibittherateofZn2SiO4formation,andtheregenerationofZnSwouldtakeplaceinamildregenerationcondition.
简介:Inthispaper,2-isopropylnaphthalenehasbeensynthesizedbythereactionofnaphthaleneandisopropylbromide,usingtriethylaminehydrochloride-aluminumchlorideionicliquidasthecatalyst.Theeffectofthecatalystcomposition,thereactiontime,thereactiontemperature,theionicliquiddosage,aswellasthemolarratioofthereagentsonthe2-isopropylnaphthaleneyieldwassystematicallyinvestigated.Theoptimalreactionconditionscover:anAlCl3toEt3NHClratioof2.0,areactiontimeof3h,areactiontemperatureof15.0℃,avolumefractionofionicliquidtothemixture(isopropylbromide,n-dodecaneandn-hexane)of9%,andanaphthalene/isopropylbromidemolarratioof4.0.Undertheoptimalreactionconditions,theconversionofisopropylbromidereached98%andtheselectivityof2-isopropylnaphthalenewasequalto80%.ThetestresultsverifiedgoodcatalyticactivityuponusingEt3NHCl-AlCl3ionicliquidasthecatalystforalkylationofnaphthalenewithisopropylbromide.Theactivityoftheionicliquidremainsunchangedafterithasbeenrecycledfor4times.